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Abstract

The densification behavior of H13 tool steel powder by dual speed laser scanning strategy have been characterized for selective laser melting process, one of powder bed fusion based metal 3d printing. Under limited given laser power, the laser re-melting increases the relative density and hardness of H13 tool steel with closing pores. The single melt-pool analysis shows that the pores are located on top area of melt pool when the scanning speed is over 400 mm/s while the low scanning speed of 200 mm/s generates pores beneath the melt pool in the form of keyhole mode with the high energy input from the laser. With the second laser scanning, the pores on top area of melt pools are efficiently closed with proper dual combination of scan speed. However pores located beneath the melt pools could not be removed by second laser scanning. When each layer of 3d printing are re-melted, the relative density and hardness are improved for most dual combination of scanning. Among the scan speed combination, the 600 mm/s by 400 mm/s leads to the highest relative density, 99.94 % with hardness of 53.5 HRC. This densification characterization with H13 tool steel laser re-melting can be efficiently applied for tool steel component manufacturing via metal 3d printing.

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Authors and Affiliations

Im Doo Jung
Jungho Choe
Jaecheol Yun
Sangsun Yang
Dong-Yeol Yang
Yong-Jin Kim
Ji-Hun Yu
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Abstract

In the manufacturing sector, the processing of magnesium alloys through the liquid casting route is one of the promising methods to manufacture automotive and aircraft components, for their excellent mechanical properties at the lower weight. Investment casting process has the great cabaility to produce near net shape complex castings for automotive and aircraft applications. The distinct and attractive engineering properties of magnesium alloys have shown to be promising in terms of its potential to replace materials such as cast iron, steel, and aluminum In this regard, the efforts to develop processing technology for these alloys for their wide range of applications in industries have been reported by the scientific and engineering community. For successful production of magnesium alloy castings, it requires specialized foundry techniques because of the particular chemical and physical properties of magnesium; especially the reactive and oxidative nature of these alloys. The industry is young enough, to tap the potential.
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Authors and Affiliations

A.V. Vyas
1
ORCID: ORCID
M.P. Sutaria
1
ORCID: ORCID

  1. Department of Mechanical Engineering, Chandubhai S. Patel Institute of Technology, Charotar University of Science and Technology (CHARUSAT), Changa, Anand-388421, Gujarat, India
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Abstract

This paper presents a comparative study of the preparation and characterisation of Fe 38.5 Co 38.5 Nb 7 P 15Cu 1 alloy produced by mechanical alloying (MA) and rapid quenching (RQ) method. In order to obtain the starting mixture (SS) in the present study, we opted for the replacement of elemental Nb and P powders with ferroalloy powders of niobium and phosphorus. Benzene was used as a control agent of the process (PCA) for wet MA. The samples obtained (powders and ribbons) were characterised by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), X-ray microanalysis (EDX), magnetic measurements M(H) and thermomagnetic measurements M(T). After 40 h of wet MA, the alloy was partially amorphous, and the ribbons obtained by RQ do not show an amorphous state. Also, the magnetic measurements show the influence of the method used on the magnetic properties.
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Authors and Affiliations

A. Cotai
1 2
ORCID: ORCID
S. Miraglia
2
ORCID: ORCID
B.V. Neamţu
1
ORCID: ORCID
T.F. Marinca
1
ORCID: ORCID
H.F. Chicinaș
1 3
ORCID: ORCID
O. Isnard
2
ORCID: ORCID
I. Chicinaş
1
ORCID: ORCID

  1. Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Ave., 400641 Cluj-Napoca, Romania
  2. Institut Néel, CNRS / Université Grenoble Alpes, 25 rue des Martyrs, BP166, 38042 Grenoble, Cédex 9, France
  3. Guhring Romania, Constructurilor Street 30, Apahida 407035, Romania
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Abstract

The article presents research on solid particle erosive wear resistance of ductile cast iron after laser surface melting. This surface treatment technology enables improvement of wear resistance of ductile cast iron surface. For the test ductile cast iron EN GJS-350-22 surface was processed by high power diode laser HPDL Rofin Sinar DL020. For the research single pass and multi pass laser melted surface layers were made. The macrostructure and microstructure of multi pass surface layers were analysed. The Vickers microhardness tests were proceeded for single pass and multi pass surface layers. The solid particle erosive test according to standard ASTM G76 – 04 with 30°, 60° and 90° impact angle was made for each multi pass surface layer. As a reference material in erosive test, base material EN GJS-350-22 was used. After the erosive test, worn surfaces observations were carried out on the Scanning Electron Microscope. Laser surface melting process of tested ductile cast iron resulted in maximum 3.7 times hardness increase caused by microstructure change. This caused the increase of erosive resistance in comparison to the base material.

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Authors and Affiliations

A. Kotarska
D. Janicki
J. Górka
ORCID: ORCID
T. Poloczek
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Abstract

For long time, Sn-Pb solder alloys have been used extensively as the main interconnection materials in the soldering. It is no doubt that Sn-Pb offers many advantages including good electrical conductivity, mechanical properties as well as low melting temperature. However, Pb is very toxic and Pb usage poses risk to human health and environments. Owing to this, the usage of Pb in the electronic industry was banned and restricted by the legislation. These factors accelerate the efforts in finding suitable replacement for solder alloy and thus lead-free solder was introduced. The major problems associated with lead-free solder is the formation of large and brittle intermetallic compound which have given a rise to the reliability issues. Micro alloying with Sb seems to be advantageous in improving the properties of existing lead-free solder alloy. Thus, this paper reviews the influence of Sb addition to the lead-free solder alloy in terms of microstructure formations and thermal properties.
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Authors and Affiliations

Nur Syahirah Mohamad Zaimi
1
Mohd Arif Anuar Mohd Salleh
1
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
1
ORCID: ORCID
Mohd Izrul Izwan Ramli
1

  1. Center of Excellence Geopolymer & Green Technology (CeGeoGTech), Faculty of Chemical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Taman Muhibbah, 02600 Jejawi, Arau, Perlis, Malaysia
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Abstract

The basic objective of the research is to construct a difference model of the melt motion. The existence of a solution to the problem is proven in the paper. It is also proven the convergence of the difference problem solution to the original problem solution of the melt motion. The Rothe method is implemented to study the Navier–Stokes equations, which provides the study of the boundary value problems correctness for a viscous incompressible flow both numerically and analytically.
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Bibliography

[1] R. Lakshminarayana, K. Dadzie, R. Ocone, M. Borg, and J. Reese: Recasting Navier–Stokes equations. Journal of Physics Communications, 3(10), (2019), 13–18, DOI: 10.1088/2399-6528/ab4b86.
[2] S.Sh. Kazhikenova, S.N. Shaltaqov, D. Belomestny, and G.S. Shai- hova: Finite difference method implementation for Numerical integration hydrodynamic equations melts. Eurasian Physical Technical Journal, 17(33), (2020), 50–56.
[3] C. Bardos: A basic example of non linear equations: The Navier– Stokes equations. Mathematics: Concepts and Foundations, III (2002), http://www.eolss.net/sample-chapters/c02/e6-01-06-02.pdf.
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[6] P.M. Gresho: Incompressible fluid dynamics: some fundamental formulation issues. Annual Review of Fluid Mechanics, 23, (1991), 413–453, DOI: 10.1146/annurev.fl.23.010191.002213.
[7] S.E. Rogers, K. Dochan, and K. Cetin: Steady and unsteady solutions of the incompressible Navier–Stokes equations. AIAA Journal, 29(4), (1991), 603–610, DOI: 10.2514/3.10627.
[8] S. Masayoshi, T. Hiroshi, S. Nobuyuki, and N. Hidetoshi: Numerical simulation of three-dimensional viscous flows using the vector potential method. JSME International Journal, 34(2), (1991), 109–114, DOI: 10.1299/jsmeb1988.34.2_109.
[9] E. Sciubba: A variational derivation of the Navier–Stokes equations based on the exergy destruction of the flow. Journal of Mathematical and Physical Sciences, 25(1), (1991), 61–68.
[10] A. Bouziani and R. Mechri: The Rothe’s method to a parabolic integrodifferential equation with a nonclassical boundary conditions. International Journal of Stochastic Analysis, Article ID 519684, (2010), DOI: 10.1155/2010/519684.
[11] N. Merazga and A. Bouziani: Rothe time-discretization method for a nonlocal problem arising in thermoelasticity. Journal of Applied Mathematics and Stochastic Analysis, 2005(1), (2005), 13–28, DOI: 10.1080/00036818908839869.
[12] T.A. Barannyk, A.F. Barannyk, and I.I. Yuryk: Exact solutions of the nonliear equation. Ukrains’kyi Matematychnyi Zhurnal, 69(9), (2017), 1180–1186, http://umj.imath.[K]iev.ua/index.php/umj/article/view/1768.
[13] N.B. Iskakova, A.T. Assanova, and E.A. Bakirova: Numerical method for the solution of linear boundary-value problem for integrodifferential equations based on spline approximations. Ukrains’kyi Matematychnyi Zhurnal, 71(9), (2019), 1176–91, http://umj.imath.[K]iev.ua/index.php/ umj/article/view/1508.
[14] S.L. Skorokhodov and N.P. Kuzmina: Analytical-numerical method for solving an Orr-Sommerfeld type problem for analysis of instability of ocean currents. Zh. Vychisl. Mat. Mat. Fiz., 58(6), (2018), 1022–1039, DOI: 10.7868/S0044466918060133.
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Authors and Affiliations

Saule Sh. Kazhikenova
1
ORCID: ORCID
Sagyndyk N. Shaltakov
1
ORCID: ORCID
Bekbolat R. Nussupbekov
2
ORCID: ORCID

  1. Karaganda Technical University, Kazakhstan
  2. Karaganda University E.A. Buketov, Kazakhstan
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Abstract

The article presents "-approximation of hydrodynamics equations’ stationary model along with the proof of a theorem about existence of a hydrodynamics equations’ strongly generalized solution. It was proved by a theorem on the existence of uniqueness of the hydrodynamics equations’ temperature model’s solution, taking into account energy dissipation. There was implemented the Galerkin method to study the Navier–Stokes equations, which provides the study of the boundary value problems correctness for an incompressible viscous flow both numerically and analytically. Approximations of stationary and non-stationary models of the hydrodynamics equations were constructed by a system of Cauchy–Kovalevsky equations with a small parameter ". There was developed an algorithm for numerical modelling of the Navier– Stokes equations by the finite difference method.
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Bibliography

[1] C. Conca: On the application of the homogenization theory to a class of problems arising in fluid mechanics. J. Math. Purs at Appl., 64(1), (1985), 31–35.
[2] M.R. Malik, T.A. Zang, and M.Y. Hussaini:Aspectral collocation method for the Navier–Stokes equations. J. Comput. Phys., 61(1), (1985), 64–68.
[3] P.M. Gresho: Incompressible fluid dynamics: some fundamental formulation issues. Annu. Rev. Fluid Mech., 23, Palo Alto, Calif., (1991), 413-453.
[4] R. Lakshminarayana, K. Dadzie, R. Ocone, M. Borg, and J. Reese: Recasting Navier–Stokes equations. J. Phys. Commun., 3(10), (2019), 13– 18, DOI: 10.1088/2399-6528/ab4b86.
[5] S.Sh. Kazhikenova, S.N. Shaltakov, D. Belomestny, and G.S. Shai- hova: Finite difference method implementation for numerical integration hydrodynamic equations melts. Eurasian Physical Technical Journal, 17(1), (2020), 50–56.
[6] O.A. Ladijenskaya: Boundary Value Problems of Mathematical Physics. Nauka, Moscow, 1973.
[7] Z.R. Safarova: On a finding the coefficient of one nonlinear wave equation in the mixed problem. Archives of Control Sciences, 30(2), (2020), 199–212, DOI: 10.24425/acs.2020.133497.
[8] A. Abramov and L.F. Yukhno: Solving some problems for systems of linear ordinary differential equations with redundant conditions. Comput. Math. and Math. Phys., 57 (2017), 1285–1293, DOI: 10.7868/ S0044466917080026.
[9] K. Yasumasa and T. Takahico: Finite-element method for three-dimensional incompressible viscous flow using simultaneous relaxation of velocity and Bernoulli function. 1st report flow in a lid-driven cubic cavity at Re = 5000. Trans. Jap. Soc. Mech. Eng., 57(540), (1991), 2640–2647.
[10] H. Itsuro, Î. Hideki, T. Yuji, and N. Tetsuji: Numerical analysis of a flow in a three-dimensional cubic cavity. Trans. Jap. Soc. Mech. Eng., 57(540), (1991), 2627–2631.
[11] X. Yan, L. Wei, Y. Lei, X. Xue, Y.Wang, G. Zhao, J. Li, and X. Qingyan: Numerical simulation of Meso-Micro structure in Ni-based superalloy during liquid metal cooling. Proceedings of the 4th World Congress on Integrated Computational Materials Engineering. The Minerals, Metals & Materials Series. Ð. 249–259, DOI: 10.1007/978-3-319-57864-4_23.
[12] T.A. Barannyk, A.F. Barannyk, and I.I. Yuryk: Exact Solutions of the nonliear equation. Ukrains’kyi Matematychnyi Zhurnal, 69(9), (2017), 1180–1186, http://umj.imath.kiev.ua/index.php/umj/article/view/1768.
[13] S. Tleugabulov, D. Ryzhonkov, N. Aytbayev, G. Koishina, and G. Sul- tamurat: The reduction smelting of metal-containing industrial wastes. News of the Academy of Sciences of the Republic of Kazakhstan, 1(433), (2019), 32–37, DOI: 10.32014/2019.2518-170X.3.
[14] S.L. Skorokhodov and N.P. Kuzmina: Analytical-numerical method for solving an Orr–Sommerfeld-type problem for analysis of instability of ocean currents. Zh. Vychisl. Mat. Mat. Fiz., 58(6), (2018), 1022–1039, DOI: 10.7868/S0044466918060133.
[15] N.B. Iskakova, A.T. Assanova, and E.A. Bakirova: Numerical method for the solution of linear boundary-value problem for integrodifferential equations based on spline approximations. Ukrains’kyi Matematychnyi Zhurnal, 71(9), (2019), 1176–1191, http://umj.imath.kiev.ua/index.php/ umj/article/view/1508.
[16] S.Sh. Kazhikenova, M.I. Ramazanov, and A.A. Khairkulova: epsilon- Approximation of the temperatures model of inhomogeneous melts with allowance for energy dissipation. Bulletin of the Karaganda University- Mathematics, 90(2), (2018), 93–100, DOI: 10.31489/2018M2/93-100.
[17] J.A. Iskenderova and Sh. Smagulov: The Cauchy problem for the equations of a viscous heat-conducting gas with degenerate density. Comput. Maths Math. Phys. Great Britain, 33(8), (1993), 1109–1117.
[18] A.M. Molchanov: Numerical Methods for Solving the Navier–Stokes Equations. Moscow, 2018.
[19] Y. Achdou and J.-L. Guermond: Convergence Analysis of a finite element projection / Lagrange-Galerkin method for the incompressible Navier–Stokes equations. SIAM Journal of Numerical Analysis, 37 (2000), 799–826.
[20] M.P. de Carvalho, V.L. Scalon, and A. Padilha: Analysis of CBS numerical algorithm execution to flow simulation using the finite element method. Ingeniare Revista chilena de Ingeniería, 17(2), (2009), 166–174, DOI: 10.4067/S0718-33052009000200005.
[21] G. Muratova, T. Martynova, E. Andreeva, V. Bavin, and Z-Q. Wang: Numerical solution of the Navier–Stokes equations using multigrid methods with HSS-based and STS-based smoother. Symmetry, 12(2), (2020), DOI: 10.3390/sym12020233.
[22] M. Rosenfeld and M. Israeli: Numerical solution of incompressible flows by a marching multigrid nonlinear method. AIAA 7th Comput. Fluid Dyn. Conf.: Collect. Techn. Pap., New-York, (1985), 108–116.92.


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Authors and Affiliations

Saule Sh. Kazhikenova
1
ORCID: ORCID

  1. Head of the Department of Higher Mathematics, Karaganda Technical University, Kazakhstan
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Abstract

In Poland, the mineral sector generates 110–130 million tons of wastes annually (in the last 20 years), and metal ore mining alone was responsible for 31.2 million tons of wastes in 2017. The slags deposited at the Polkowice were investigated. This waste may be a potential source of many valuable metals (Zn, Pb, Cu, Sb, Sn, Se). The tailings dump in Polkowice contains approximately 80,000 tons of slag. The material contains primary phases formed by pyrometallurgical processes and secondary phases, which are the result of transformation of primary components. The primary phases are represented by sulfides: sphalerite [ZnS]; wurtzite [(Zn,Fe)S]; pyrite [FeS2]; sulfates: beaverite-(Zn) [Pb(Fe3+ 2Zn)(SO4)2(OH)6]; palmierite [(K,Na)2Pb(SO4)2]; oxides and hydroxides: goethite [Fe3+O(OH)]; wüestite [FeO]; hematite [Fe2O3]; magnetite [Fe2+Fe3+ 2O4]; chromian spinel [Fe2+Cr3+ 2O4]; silicates: petedunnite [Ca(Zn,Mn2+,Mg,Fe2+)Si2O6]; quartz [SiO2]; and microcline [KAlSi3O8]. Additionally, SEM -BSE observations revealed that oxidized native metals (Cu, Pb, As) and metal alloys and semi-metals appear. The slag consists mainly of SiO2 (13.70–20.60 wt%), Fe2O3 (24.90–39.62 wt%) and subordinately of CaO (2.71–6.94 wt%) and MgO (1.34–4.68 wt%). High contents are formed by Zn (9.42–17.38 wt%), Pb (5.13–13.74 wt%) and Cu (1.29–2.88 wt%). The slag contains trace elements Mo (487.4–980.1 ppm), Ni (245.3–530.7 ppm), Sn (2380.0–4441.5 ppm), Sb (2462.8–4446.0 ppm), Se (168.0–293.0 ppm). High concentrations are formed by toxic elements, such as e.g. As (13 100–22 600 ppm) and Cd (190.5–893.1 ppm). It is estimated that the tailings dump has accumulated about 80,000 t of slag, which may contain about 10,000 t of Zn, about 6,700 t of Pb, and 1,500 t of Cu.
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Authors and Affiliations

Karol Zglinicki
1
ORCID: ORCID
Krzysztof Szamałek
2
ORCID: ORCID
Anna Czarnecka-Skwarek
2
ORCID: ORCID
Katarzyna Żyłka
2 1

  1. Polish Geological Institute – Polish Research Institute, Warszawa, Poland
  2. University of Warsaw, Warszawa, Poland
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Abstract

Production waste is one of the major sources of aluminium for recycling. Depending on the waste sources, it can be directly melted in furnaces, pre-cleaned and then melted, or due to the small size of the material (powder or dust) left without remelting. The latter form of waste includes chips formed during mechanical cutting (sawing) of aluminium and its alloys. In this study, this type of chips (with the dimensions not exceeding 1 mm) were melted. The obtained results of laboratory tests have indicated that even chips of such small sizes pressed into cylindrical compacts can be remelted. The high recovery yield (up to 94 %) and degree of metal coalescence (up to 100 %) were achieved via thermal removal of impurities under controlled conditions of a gas atmosphere (argon or/and air), followed with consolidation of chips at a pressure of minimum 170 MPa and melting at 750 oC with NaCl-KCl-Na3AlF6 salt flux.

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Authors and Affiliations

P. Palimąka
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Abstract

Recyclability is one of the great features of aluminium and its alloys. However, it has been typically considered that the secondary aluminium quality is low and bad. This is only because aluminium is so sensitive to turbulence. Uncontrolled transfer and handling of the liquid aluminium results in formation of double oxide defects known as bifilms. Bifilms are detrimental defects. They form porosity and deteriorate the properties. The detection and quantification of bifilms in liquid aluminium can be carried out by bifilm index measured in millimetres as an indication of melt cleanliness using Reduced Pressure Test (RPT). In this work, recycling efficiency and quality change of A356 alloy with various Ti additions have been investigated. The charge was recycled three times and change in bifilm index and bifilm number was evaluated. It was found that when high amount of Ti grain refiner was added, the melt quality was increased due to sedimentation of bifilms with Ti. When low amount of Ti is added, the melt quality was degraded.

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Authors and Affiliations

O. Gursoy
E. Erzi
K. Tur
D. Dispinar
ORCID: ORCID
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Abstract

The removal of inclusions is a major challenge prior to the casting process, as they cause a discontinuity in the cast material, thereby lowering its mechanical properties and have a negative impact on the feeding capability and fluidity of the liquid alloys. In order to achieve adequate melt quality for casting, it is important to clean the melts from inclusions, for which there are numerous methods that can be used. In the course of the presented research, the inclusion removal efficiency of rotary degassing coupled with the addition of different fluxes was investigated. The effects of various cleaning fluxes on the inclusion content and the susceptibility to pore formation were compared by the investigation of K-mold samples and the evaluation of Density Index values at different stages of melt preparation. The chemical composition of the applied fluxes was characterized by X-ray powder diffraction, while the melting temperature of the fluxes was evaluated by derivatographic measurements. It was found that only the solute hydrogen content of the liquid metal could be significantly reduced during the melt treatments, however, better inclusion removal efficiency could be achieved with fluxes that have a low melting temperature.

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Authors and Affiliations

M. Máté
M. Tokár
G. Fegyverneki
G. Gyarmati
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Abstract

The naturally pressurized gating system was used for reoxidation suppression during aluminium alloy casting. A naturally pressurized gating system appears to be a suitable solution to reduce reoxidation processes, which was proven by our previous works. The disadvantage of this system is that without inserting deceleration elements, the melt velocity is supercritical. Therefore, the aim of paper is to find a proper way to reduce the melt velocity, which is the main parameter affecting the scale of reoxidation processes. For the purpose of the melt velocity reduction, labyrinth filters, foam filters and flat filters effect on the melt velocity and the number of oxides were investigated by numerical simulation software in the first stage of the experiment. After simulations observation, the effect of filters on the mechanical properties was investigated by experimental casts. The simulations and experimental casts proved that filters had a positive effect on the melt velocity reduction and it was associated with increased mechanical properties of castings. The best results were achieved by the foam filter.
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Bibliography

[1] Campbell, J. (2015). Complete Casting Handbook. (2nd ed.). Oxford: Elsevier Ltd.
[2] Dobosz, St.M., Grabarczyk, A., Major-Gabrys, K. & Jakubski, J. (2015). Influence of quartz sand quality on bending strength and thermal deformation of moulding sands with synthetic binders. Archives of Foundry Engineering. 15(2), 9-12. ISSN (1897-3310)
[3] Lakoma, R., Camek, L., Lichý, P., Kroupová, I., Radkovský, F. & Obzina, T. (2021). Some possibilities of using statistical methods while solving poor quality production. Archives of Foundry Engineering. 21(1), 18-22. DOI: 10.24425/afe.2021.136073
[4] Baghani, A., Kheirabi, A., Bahmani, A. & Khalilpour, H. (2012). Removal of double oxide film defects by ceramic foam filters. Journal of Materials Engineering and Performance. 21(7), 1352-1362. DOI: 10.1007/s11665-011-9991-3
[5] Jezierski, J., Dojka, R. & Janerka, K. (2018). Optimizing the Gating System for Steel Castings. Metals. 8(266), 1-13. DOI: 10.3390/met804026
[6] Pastirčák, R. & Ščury, J. (2016). Effect of technological parameters on microstructure in alloy AlCu4Ti using squeeze casting technology. The application of experimental and numerical methods in fluid mechanics and energy. ISBN 978-0-7354-1402-0.
[7] Gyarmati, G., Fegyverneki, G., Mende, T. & Tokár, M. 2019. Characterization of the double oxide film content of liquid aluminum alloys by computed tomography. Materials Characterization. 157, 109925.
[8] Remišová, A. & Brůna, M. (2019). Analysis of reoxidation processes with aid of computer simulation. Archives of Foundry Engineering. 19(4), 55-60.
[9] Brůna, M., Galčík, M., Sládek, A. & Martinec, D. (2021). Possibilities of bifilm amount reduction in Al castings by gating system design optimization. Archives of Metallurgy and Materials. 66(2), 549-559. ISSN 1733-3490

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Authors and Affiliations

M. Bruna
1
ORCID: ORCID
M. Galčík
1

  1. University of Žilina, Slovakia
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Abstract

The solubility of Fe in aluminium alloys is known to be a problem in the casting of aluminium alloys. Due to the formation of various intermetallic phases, the mechanical properties decrease. Therefore, it is important to determine the formation mechanisms of such intermetallic. In this work, A360 alloy was used, and Fe additions were made. The alloy was cast into the sand and die moulds that consisted of three different thicknesses. In this way, the effect of the cooling rate was investigated. The holding time was selected to be 5 hours and every hour, a sample was collected from the melt for microstructural analysis. Additionally, the melt quality change was also examined by means of using a reduced pressure test where the bifilm index was measured. It was found that the iron content was increased after 2 hours of holding and the melt quality was decreased. There was a correlation between the duration and bifilm index. The size of Al-Si-Mn-Fe phases was increased in parallel with the bifilm content regardless of the iron content.
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Bibliography

[1] Bjurenstedt, A., Ghassemali, E., Seifeddine, S. & Dahle, A.K. (2019). The effect of Fe-rich intermetallics on crack initiation in cast aluminium: An in-situ tensile study. Materials Science and Engineering: A. 756, 502-507. DOI:10.1016/j.msea.2018.07.044
[2] Ferraro, S. & Timelli, G. (2015). Influence of sludge particles on the tensile properties of die-cast secondary aluminum alloys. Metallurgical and Materials Transactions B. 46(2), 1022-1034. DOI:10.1007/s11663-014-0260-3
[3] Ma, Z., Samuel, A., Samuel, F., Doty, H. & Valtierra, S. (2008). A study of tensile properties in Al–Si–Cu and Al–Si–Mg alloys: Effect of β-iron intermetallics and porosity. Materials Science and Engineering: A. 490(1-2), 36-51. https://doi.org/10.1016/j.msea.2008.01.028
[4] Zahedi, H., Emamy, M., Razaghian, A., Mahta, M., Campbell, J. & Tiryakioğlu, M. (2007). The effect of Fe-rich intermetallics on the Weibull distribution of tensile properties in a cast Al-5 pct Si-3 pct Cu-1 pct Fe-0.3 pct Mg alloy. Metallurgical and Materials Transactions A. 38(3), 659-670. DOI: 10.1007/s11661-006-9068-3
[5] Tunçay, T., Özyürek, D., Dişpinar, D. & Tekeli, S. (2020). The effects of Cr and Zr additives on the microstructure and mechanical properties of A356 alloy. Transactions of the Indian Institute of Metals. 73(5), 1273-1285. DOI: 10.1007/s12666-020-01970-4
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Authors and Affiliations

E.N. Bas
1
S. Alper
1
T. Tuncay
2
ORCID: ORCID
D. Dispinar
3
ORCID: ORCID
S. Kirtay
1
ORCID: ORCID

  1. Istanbul University-Cerrahpasa, Turkey
  2. Karabuk University, Turkey
  3. Foseco, Netherlands
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Abstract

The article describes the influence of optimization parameters on the efficiency of aluminium melt refining by using physical modelling. The blowing of refining gas, through a rotating impeller into the ladle is a widely used operating technology to reduce the content of impurities in molten aluminium, e.g. hydrogen. The efficiency of this refining process depends on the creation of fine bubbles with a high interphase surface, wide-spread distribution, the residence time of its effect in the melt, and mostly on the wide-spread dispersion of bubbles in the whole volume of the refining ladle and with the long period of their effect in the melt. For physical modelling, a plexiglass model on a scale of 1:1 is used for the operating ladle. Part of the physical model is a hollow shaft used for gas supply equipped with an impeller and also two baffles. The basis of physical modelling consists in the targeted utilization of the similarities of the processes that take place within the actual device and its model. The degassing process of aluminium melt by blowing inert gas is simulated in physical modelling by a decrease of dissolved oxygen in the model liquid (water).
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Bibliography

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Authors and Affiliations

J. Walek
1
ORCID: ORCID
K. Michalek
1
ORCID: ORCID
M. Tkadlečková
1
ORCID: ORCID

  1. VŠB - Technical University of Ostrava, Faculty of Materials Science and Technology, Department of Metallurgical Technologies
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Abstract

This paper investigates the influence of 1%, 2% and 3% zirconia (ZrO2) nanoparticles to the melting, microstructural and mechanical properties of the Sn58Bi solder. Melting temperatures of 145.11°C, 140.89°C and 143.84°C were attained correspondingly for the 1%, 2% and 3% ZrO2 reinforced Sn58Bi solder. The microstructures especially the spacing between the lamellar structures of the Sn58Bi solder alloy was narrower for 1% ZrO2 added with Sn58Bi solder alloy. The highest and lowest hardness value of 32.28 HV and 27.62 HV was recorded for 1% and 2% ZrO2 additions respectively. Highest shear strength value was noted for the 3% ZrO2 added SnBi/Copper joint with 0.8712 kN, while the lowest value of 0.4380 kN noted for the 1% ZrO2 added SnBi/Copper joint. The presence of small-sized ZrO2 nanoparticles can be seen to be properly dispersed at the solder joint to increase the shear load at maximum joint stress.
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Authors and Affiliations

S. Amares
1 2
R. Durairaj
2
S.H. Kuan
2

  1. Universiti Tunku Abdul Rahman, Lee Kong Chian Faculty of Engineering and Science, Jalan Sungai Long, Bandar Sungai Long, 43000 Kajang, Selangor, Malaysia
  2. Center of Mechanical and Materials Engineering, Faculty of Engineering and Built Environment, SEGi University No. 9, Jalan Teknologi, Taman Sains Selangor, Kota Damansara PJU 5, 47810 Petaling Jaya , Selangor, Malaysia
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Abstract

High pressure die casting technology (HPDC) is a method enabling the production of shape-complex casts with good mechanical properties, with high repeatability of production within narrow tolerance limits. However, the casts show, to some extent, basic porosity, which may reduce their mechanical and qualitative properties. One of the main areas to focus on in order to reduce the porosity of casts is the correct design and structure of the gating and overflow system. Submitted article is devoted to the assessment of the connecting channel cross-section design for connecting the overflows to the cast on selected parameters of the casting process. Five different cross-section designs of connecting channels are considered, enabling the removal of gases and vapors from the volume during the molding. The connecting channels are designed with a constant width g = 10mm and variable height h1 = 1.50 mm, h2 = 1.25 mm, h3 = 1.00 mm, h4 = 0.75 mm and h5 = 0.6 mm. The primary monitored parameter is the gas entrapment in selected points of the cast. The following is an evaluation of the pressure conditions change in the mold cavity at the end of the filling mode and local overheating of the mold material just below the surface of the mold face. With regard to the monitored parameters, based on the performed analyzes, the most suitable design solution of the connecting channel is assessed and recommendations for the design and structure of the overflows and their connection to the cast are derived.
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Bibliography

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Authors and Affiliations

J. Majerník
1
ORCID: ORCID
M. Podařil
1
D. Gojdan
2

  1. Institute of Technology and Business in České Budějovice, Czech Republic
  2. Technical University of Košice, Faculty of Manufacturing Technologies with the Seat in Prešov, Slovak Republic
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Abstract

Aluminum casting alloys are widely used in especially automotive, aerospace, and other industrial applications due to providing desired mechanical characteristics and their high specific strength properties. Along with the increase of application areas, the importance of recycling in aluminum alloys is also increasing. The amount of energy required for producing primary ingots is about ten times the amount of energy required for the production of recycled ingots. The large energy savings achieved by using the recycled ingots results in a significant reduction in the amount of greenhouse gas released to nature compared to primary ingot production. Production can be made by adding a certain amount of recycled ingot to the primary ingot so that the desired mechanical properties remain within the boundary conditions. In this study, by using the A356 alloy and chips with five different quantities (100% primary ingots, 30% recycled ingots + 70% primary ingots, 50% recycled ingots + 50% primary ingots, 70% recycled ingots + 30% primary ingots, 100% recycled ingots), the effect on mechanical properties has been examined and the maximum amount of chips that can be used in production has been determined. T6 heat treatment was applied to the samples obtained by the gravity casting method and the mechanical properties were compared depending on the amount of chips. Besides, microstructural examinations were carried out with optical microscopy techniques. As a result, it has been observed that while producing from primary ingots, adding 30% recycled ingot to the alloy composition improves the mechanical properties of the alloy such as yield strength and tensile strength to a certain extent. However, generally a downward pattern was observed with increasing recycled ingot amount.
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Authors and Affiliations

A.Y. Kaya
1
O. Özaydın
1
T. Yağcı
2
A. Korkmaz
2
E. Armakan
1
O. Çulha
2

  1. Cevher Alloy Wheels Co. / R&D Dept., İzmir, Turkey
  2. Manisa Celal Bayar University, Engineering Faculty, Dept. of Metallurgical and Materials Engineering, Manisa, Turkey
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Abstract

The high pressure die casting technology allows the production of complex casts with good mechanical properties, with high production repeatability within narrow tolerance limits. However, the casts are somewhat porous, which may reduce their mechanical properties. There are several recommendations for reducing the porosity of casts, which are aimed at setting the technological parameters of the casting cycle. One of the primary and important ways to reduce the porosity and air entrapment in the melt is a suitable gating system design. Submitted contribution is devoted to assessing the influence of the runner branching geometry on the air entrapment within the cast volume during the filling phase of the casting cycle. Four variants of the gating system for a particular cast are compared with different design of main runner branching. The initial design is based on a real gating system where the secondary runner is connected to the main runner at an angle of 90 °. The modified designs are provided with a continuous transition of the main runner into the secondary ones, with the change in the branching runner radius r1 = 15 mm, r2 = 25 mm and r3 = 35 mm. The air entrapment in the melt is assessed within the cast volume behind the cores, which have been evaluated as a critical points with respect to further mechanical treatment. When designing the structural modification of geometry it was assumed that by branch changing using the radius value r3 = 35 mm, the melt flows fluently, and thus the value of the entrapped air in the volume of the cast will be the lowest. This assumption was disproved. The lowest values of entrapped air in the melt were found in the casts with runner transition designed with radius r1 = 15 mm. The conclusion of the contribution explains the causes of this phenomenon and from a designing point of view it presents proposal for measures to reduce the entrapment of the air in casts.

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Authors and Affiliations

J. Majerník
ORCID: ORCID
M. Podařil
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Abstract

Refractories are the basic material for the construction of the lining of a melting furnace used, among other things, in the foundry industry. The article describes a comparative study of the influence of the type of moulding on the quality of the finished refractory product. A method for making products from refractory materials was proposed and a test methodology was developed. The results, based on a classic study of the quality of these materials, confirm a strong influence on the quality of the materials obtained in terms of reduced porosity and homogeneity of pore size.
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Authors and Affiliations

Alicja Trela
1
ORCID: ORCID
Alena Pribulová
2
ORCID: ORCID
Peter Futas
2
ORCID: ORCID

  1. AGH University of Krakow, Faculty of Foundry Engineering, Al. Mickiewicza 30, 30-059 Kraków, Poland
  2. Technical University Kosice, Department of Metallurgy, Slovakia
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Abstract

Scientists and medics are still searching for new metallic materials that can be used in medicine, e.g., as material for implants. The following article proposes materials based on titanium with vital elements prepared by combined powder metallurgy and arc melting methods. Four compositions of Ti-28Ta-9Nb, Ti-28Ta-19Nb, Ti-28Ta-9Zr and Ti-28Ta-19Zr (wt.%) have been prepared. The tested material was thoroughly analyzed by X-ray diffraction and scanning electron microscopy. Qualitative phase analysis using X-ray diffraction showed the presence of two phases, α' and β titanium. In addition, a microhardness test was conducted, and the material was characterized in terms of corrosion properties. It was found that the corrosion resistance decreases with an increase of the β phase presence.
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Authors and Affiliations

I. Matuła
1
ORCID: ORCID
G. Dercz
1
ORCID: ORCID
K. Prusik
1
ORCID: ORCID
M. Szklarska
1
ORCID: ORCID
A. Kazek-Kęsik
2
ORCID: ORCID
W. Simka
2
ORCID: ORCID
E. Sudoł
3

  1. University of Silesia in Katowice, Institute of Materials Engineering, 75 Pułku Piechoty Str., 1 A, 41-500 Chorzów, Poland
  2. Silesian University of Technology, Faculty of Chemistry, 6 B. Krzywoustego Str., 44-100 Gliwice, Poland
  3. Graduate, Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Street 1 A, 41-500 Chorzów, Poland
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Abstract

Refractories are the basic material for the construction of the lining of a melting furnace used, among other things, in the foundry industry. The article describes a comparative study of the influence of the type of moulding on the quality of the finished refractory product. A method for making products from refractory materials was proposed and a test methodology was developed. The results, based on a classic study of the quality of these materials, confirm a strong influence on the quality of the materials obtained in terms of reduced porosity and homogeneity of pore size.
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Authors and Affiliations

Alicja Trela
ORCID: ORCID
M. Brzeziński
1
ORCID: ORCID
A. Pribulova
2
ORCID: ORCID
Peter Futas
ORCID: ORCID

  1. AGH University of Krakow, Faculty of Foundry Engineering, Al. Mickiewicza 30, 30-059 Krakow, Poland
  2. Technical University, Department of Metallurgy, Kosice, Slovakia
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Abstract

This work investigated two titanium-based alloys with a constant tantalum content and variable contents of alloy additives – niobium and zirconium. The Ti-30Ta-10Zr-20Nb (wt.%) and Ti-30Ta-20Zr-10Nb (wt.%) alloys were obtained using a combination of powder metallurgy and arc melting methods. The influence of alloying additives on the structure and properties of the Ti-Ta-Nb-Zr system was studied using, among others: X-ray diffraction and scanning electron microscopy. The X-ray diffraction confirmed the single-β-phase structure of both alloys. In addition, the microscopic analysis revealed that a higher amount of zirconium favoured the formation of larger grains. However, the microhardness analysis indicated that the alloy with the higher niobium content had the higher microhardness. Importantly, the in vitro corrosion study revealed that the addition of niobium promoted the better corrosion resistance of the investigated alloy.
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Authors and Affiliations

G. Dercz
1
ORCID: ORCID
I. Matuła
1
ORCID: ORCID
K. Prusik
1
ORCID: ORCID
J. Zając
1
M. Szklarska
1
ORCID: ORCID
A. Kazek-Kęsik
2
ORCID: ORCID
W. Simka
2
ORCID: ORCID

  1. Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Street 1 A, 41-500 Chorzów, Poland
  2. Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice, Poland
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Abstract

Electromagnetic processing of molten copper is provided in a special kind of electrical furnace called an induction furnace with a cold crucible (IFCC), making it possible to successfully remove impurities from the workpiece. In order to analyze the process in a sufficient way not only electromagnetic, thermal and flow but also metallurgical and mass transfer phenomena in the coupled formulation should be taken into consideration. The paper points to an analysis of the kinetic process of lead evaporation from molten copper. It was shown that mass transport in the gas phase determines the rate of the analyzed evaporation process. The possibility of removal of lead from molten copper is analyzed and described.
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Authors and Affiliations

Albert Smalcerz
1
ORCID: ORCID
Leszek Blacha
1
ORCID: ORCID
Jerzy Barglik
1
ORCID: ORCID
Ivo Dolezel
2
ORCID: ORCID
Tadeusz Wieczorek
1
ORCID: ORCID

  1. Silesian University of Technology Krasinskiego 8, 40-019 Katowice, Poland
  2. Faculty of Electrical Engineering, University of West Bohemia Univerzitní 26, 301 00 Pilsen, Czech Republic
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Abstract

Titanium alloys belonging to the group of modern metallic materials used in many industries, including the aerospace industries. Induction crucible vacuum furnaces and induction furnaces with cold crucible are most commonly used for their smelting. When operating these devices, one can deal with an adverse phenomenon of decrease in the content of alloy elements that are characterized by higher equilibrium vapour pressure than the matrix metal or titanium, in the metal bath. In the paper, results of the study on aluminium evaporation from the Ti-Al-Nb, Ti-Al-V and Ti-Al alloys (max 6.2 % wt.) during smelting in a vacuum induction melting (VIM) furnace are presented. The experiments were performed at 10 to 1000 Pa for 1973 K and 2023 K. A significant degree of aluminium loss has been demonstrated during the analysed process. The values of relative aluminium loss for all the alloys ranged from 4 % to 25 %. Lowering the pressure in the melting system from 1000 Pa to 10 Pa resulted in increased values of aluminium evaporation flux from 4.82⋅10-5 to 0.000327 g⋅cm-2⋅s-1 for 1973 K and from 9.28⋅10-5 to 0.000344 g⋅cm-2⋅s-1 for 2023 K. The analysis of the results obtained took into account the value of the actual surface of the liquid metal. In the case of melting metals in an induction furnace, this surface depends on the value of power emitted in the charge. At greater power, we observe a significant increase in the bath surface due to the formation of a meniscus.
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Bibliography

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Authors and Affiliations

Albert Smalcerz
ORCID: ORCID
Leszek Blacha
ORCID: ORCID
J. Łabaj
1
ORCID: ORCID

  1. Silesian University of Technology, Faculty of Materials Engineering and Metallurgy, ul. Krasińskiego 8, 40-019 Katowice, Poland

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