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Number of results: 29
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Abstract

Methane is accompanied by most of the coal deposits. The methane hazard is excessive content of this gas in the mining excavations. This is a source of high risk security and continuity of the mine. The Piast–Ziemowit is the only non-methane mine in the Polish Mining Group. In 2015, 66,4% of the coal mined in Kompania Węglowa S.A. mines comes from methane coal seams. Methane drainage is the most effective but very costly method of combating methane hazard.The costs of prevention and eradication of methane hazard is charged to the costs of coal mining. Therefore, performance of methane drainage in the mines of the Polish Mining Group is adapted to the scale of the methane hazard. The article presents an analysis of the costs of prevention of methane hazard for mines with different absolute methane and its impact on the level of these costs.

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Authors and Affiliations

Halina Potoczek
Piotr Bojarski
Leszek Kloc
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Abstract

Methane explosions are among the greatest hazards in the Polish coal mining industry and unfortunately continue to cause many catastrophes. The constant growth of the depth of coal exploitation in the conditions of the high concentration of mining causes the increase of absolute methane content and methane seam pressure from the mined seams. This situation directly affects the increase in the level of methane hazard in the underground work environment. It is therefore obvious to undertake intensive research that will allow for the development of appropriate solutions that help to exclude the risk of mining catastrophes resulting from the ignition and/or methane explosion. In addition to the development of methane hazard prevention methods, an indispensable element of this approach is a very accurate identification of the mechanisms of the combustion and explosion of this gas. The article presents the method of investigation and examples of results of methane explosions carried out in the 400 m experimental gallery of the Experimental Mine “Barbara” of the Central Mining Institute – the only large scale underground experimental facility in Europe. A n analysis has been performed of the influence of the methane release into mining workings on the distribution of the gas concentration and on the course of its explosion or combustion. The data collected characterizes thermodynamic phenomena that form the basis for determining the level of the explosion hazard. Large scale studies have also allowed to assess the risk of conditions that are sufficient for the development of a coal dust explosion initiated by methane explosions. The large scale of the experiments and the system of continuous recording of the course of the experiments allowed the specific characteristics of the methane explosion and burning in underground mining workings to be identified and isolated. For the first time, the course of experiments was recorded via a camera system deployed along the gallery.

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Authors and Affiliations

Krzysztof Cybulski
Zdzisław Dyduch
Robert Hildebrandt
Henryk Koptoń
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Abstract

This paper presents mathematical models enabling the calculation of the distribution and patterns of methane inflow to the air stream in a longwall seam being exploited and spoil on a longwall conveyor, taking into account the variability of shearer and conveyor operation and simulation results of the mining team using the Ventgraph-Plus software. In the research, an experiment was employed to observe changes in air parameters, in particular air velocity and methane concentration in the Cw-4 longwall area in seam 364/2 at KWK Budryk, during different phases of shearer operation in the area of the mining wall in methane hazard conditions. Presented is the method of data recording during the experiment which included records from the mine’s system for automatic gasometry, records from a wireless system of eight methane sensors installed in the end part of the longwall and additionally from nine methane anemometers located across the longwall on a grid. Synchronous data records obtained from these three independent sources were compared against the recording the operating condition of the shearer and haulage machines at the longwall in various phases of their operation (cleaning, cutting). The results of the multipoint system measurements made it possible to determine the volume of air and methane flow across the longwall working, and, consequently, to calculate the correction coefficients for determining the volume of air and methane from measurements of local air velocity and methane concentration. An attempt was made to determine the methane inflow from a unit of the longwall body area and the unit of spoil length on conveyors depending on the mining rate. The Cw-4 longwall ventilation was simulated using the data measured and calculated from measurements and the simulation results were discussed.

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Authors and Affiliations

Wacław Dziurzyński
ORCID: ORCID
Teresa Palka
Andrzej Krach
ORCID: ORCID
Stanisław Wasilewski
ORCID: ORCID
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Abstract

A mathematical model for the purposes of methane hazard assessment in mines was developed in the Central Mining Institute as part of the statutory activities conducted in 2017 and 2018. The model describes the course of kinetics of methane sorption on coal samples while taking into account the diffusion coefficient. The paper presents the formulas describing the mathematical model of methane emission from coal sidewall to longwall working, taking into account the sorption properties of coal – sorption capacity of coal (related to methane) and the effective diffusion coefficient of methane in coal. In the light of the conducted research, such a methodology for describing this phenomenon enables a more precise determination of the amount of methane released to the longwall from the exploited coal seam, which in turn makes it possible to select appropriate methane prevention measures.

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Authors and Affiliations

Henryk Koptoń
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Abstract

The work concerned the introduction of simplifications in a one-dimensional mathematical model of a chemical reactor. Fecralloy foam with a pore density of 16 PPC (pores per centimetre) was used as catalyst support. The analysed process was the combustion of methane with a typical concentration found in the ventilation air of hard coal mines. The process was carried out using a palladium catalyst.
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Authors and Affiliations

Mateusz Korpyś
1
ORCID: ORCID
Marzena Iwaniszyn
1
ORCID: ORCID
Katarzyna Sindera
1
ORCID: ORCID
Andrzej Kołodziej
1
ORCID: ORCID
Adam Rotkegel
1
ORCID: ORCID
Joanna Profic-Paczkowska
2
ORCID: ORCID
Maciej Sitarz
3
ORCID: ORCID
Anna Gancarczyk
1
ORCID: ORCID

  1. Polish Academy of Sciences, Institute of Chemical Engineering, Bałtycka 5, 44-100 Gliwice, Poland
  2. Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland
  3. AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Mickiewicza 30, 30-059 Kraków, Poland
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Abstract

The article shows the results of research on methane concentration changes along mine galleries. The experiment was conducted in a longwall area mined using a U-type system, and the results were obtained in situ. The main goal was to measure methane concentration by function of gallery length and dividing segments of methane data into segments, which ultimately enabled separate analysis of these methane data. The analysis led to the diagnosis of methane hazard through the detection of exceedance of the assumed tolerance area.
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Authors and Affiliations

Piotr Ostrogórski
1
ORCID: ORCID
Przemysław Skotniczny
1
ORCID: ORCID

  1. Strata Mechanics Research Institute of the Polish Academy of Sciences, 27 Reymonta Str.,30-059 Kraków, Poland
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Abstract

United Nations Framework Convention on Climate Change obliges member countries to make an inventory of greenhouse gases emission and, among others, an inventory of fugitive emission from coal mining system. To comply with this obligation, basing on 1992 data. Poland has evaluated so-called "emission factors" for identified sources of methane emission. According to IPCC/OECD guidelines, the emission factors multiplied by coal output allow simple evaluation of methane emission. Since the time when the emission factors were evaluated in 1994, coal industry in Poland has undergone major organisational and technical changes. At the same time significant development of basic knowledge on geology of methane in coal-bearing strata have occurred. Both these facts make the emission factors evaluated earlier inaccurate. A wide range of research indispensable for accurate evaluation of new emission factors is described in the paper. It is also recommended in the paper that by the time the research results are known, the improved emission factors. which take into account organisational changes of mining industry should be used. Methane emission from coal mining system in 1999 evaluated using those emission factors equals 527,889 Gg.
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Authors and Affiliations

Lidia Gawlik
ORCID: ORCID
Ireneusz Grzybek
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Abstract

The landfill gas (LFG), produced during decomposition of the organic fraction of waste is a major source of air pollutants. It consists mainly of methane and carbon dioxide, but also contains additional gases, such as nitrogen, oxygen, hydrogen, carbon monoxide, hydrogen sulphide, and a large number of trace components. Aliphatic and aromatic hydrocarbons, halogenated hydrocarbons, heterocyclic compounds, alcohols, aldehydes, ketones, terpenes and siloxanes belong to this group. This work presents the results of field studies concerning the concentration of over fifty non-methane organic compounds in municipal solid waste landfill gas. The sites examined were located in the Middle East macroregion of Poland. The landfills were different in the respect to size, morphology, and age of stored waste. The results reveal that the highest concentrations of the majority of the examined compounds were observed in gas released from the largest landfill at which the waste was not pre-treated prior to deposition. Concentrations often exceeded those found in the literature data. Deposition of waste after separation of biofraction and recyclable materials significantly decreased concentrations of the majority of NMOCs in the LFG.
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Authors and Affiliations

Małgorzata Pawłowska
Jacek Czerwiński
Witold Stępniewski
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Abstract

This study investigated the potential of three microalgae taxonomic groups of Chlorophyta, Cyanoprokaryota and Bacillariophyceae for biogas production. Biogas potential was assessed in mesophilic anaerobic digestion batch tests over a period of 20 days. The cumulative biogas yield (CBY) of Chlorophyta and Cyanoprocaryota was respectively 396.21 mL/g Volatile Solids (VS) and 382.45 mL/g VS. Bacillariophyceae digestion showed lower biogas production of 357.07 mL/g VS. The highest cumulative methane yield (CMY) of 241.25 mL CH 4/g VS was recorded for Cyanoprocaryota biomass, which was signifi cantly higher (p<0.05) than the other two types of microalgae. The highest methane content in biogas of 63.08% was observed with Cyanoprokaryota. Chemical composition of biomass as well as biogas productivity are infl uenced by algal taxonomy.
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Authors and Affiliations

Marta Kisielewska
1
Marcin Dębowski
1
Marcin Zieliński
1

  1. Uniwersytet Warmińsko-Mazurski w Olsztynie, Department of Environmental Engineering
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Abstract

Here One important aspect of the process of anaerobic stabilisation of sewage sludge in medium and large sewage treatment plants, in addition to sludge mineralisation, is the acquisition of a valuable source of energy, which is biogas. There are well-known methods of intensifying the process of methane fermentation by subjecting sludge to disintegration using physical factors, i.e. ultrasonic field. Acetate production is the ratelimiting step in the acetate consumption pathway and affects the efficiency of the anaerobic stabilisation process. The product of the first stage of the process is also the substrate for the next stage. Therefore, it is advisable to subject sewage sludge to disintegration, which increases its susceptibility to biodegradation. Sludge modification with the above-mentioned method causes a significant increase in the concentration of organic substances in the supernatant liquid. The reflection of the physical and chemical transformations of sludge in the disintegration processes is the change in their structure expressed by the increase in the degree of particle dispersion. The disintegration of sludge using sonolysis is an effective process solution, both in terms of technology and energy, in terms of obtaining biogas, which is a valuable source of energy.
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Authors and Affiliations

Iwona Zawieja
1
ORCID: ORCID

  1. Faculty of Infrastructure and Environment, Czestochowa University of Technology,Dąbrowskiego 73, 42-201, Czestochowa, Poland, ORCID 0000-0002-4480-8736
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Abstract

Methane explosions are one of the greatest hazards in the coal mining industry and have caused many accidents. On 27 July 2016 at approximately 11:01 a.m., an explosion of methane occurred at the bottom of Zygmunt return shaft at the depth of 411 metres. The explosion resulted in one casualty.
The article presents the results of, and the conclusions from, an in-depth analysis of the changes in the parameters of mine air, especially methane concentration, air flow and the operation of mine fans, recorded by sensors installed in the workings and in Zygmunt ventilation shaft around the time of the accident. The analysis was based on signals recorded by the monitoring system, related to the evolution of methane and fire hazards prior to and after the accident occurred. An attempt was made to identify the cause and the circumstances of the methane explosion at the bottom of the return shaft.
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Authors and Affiliations

Stanisław Wasilewski
1
ORCID: ORCID
Nikodem Szlązak
2
ORCID: ORCID
Paweł Jamróz
1
ORCID: ORCID

  1. Strata Mechanics Research Institute of the Polish Academy of Sciences, 27 Reymonta Str.,30-059 Kraków, Poland
  2. AGH University of Kraków, al. Mickiewicza 30, 30-059 Kraków, Poland
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Abstract

One of the most hazardous places in mines are longwall areas. They emit a considerable amount of methane to the ventilation air. The emission depends on many but mostly known factors. The article presents the research results on changes in the methane concentration along the longwall excavations and longwall. The distributions were obtained based on a measurement experiment at the ZG Brzeszcze mine in Poland. The author’s research aimed to experimentally determine the concentration of methane as a function of the length of excavation for the longwall excavations and longwall. As a result, methane concentration trends along the excavations were obtained. The conclusions show the pros and cons of the method used, and it allows to set the right direction in the development of measurement systems and sensors.
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Bibliography

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Authors and Affiliations

Piotr Ostrogórski
1
ORCID: ORCID
Przemysław Skotniczny
1
ORCID: ORCID
Mieczysław Pucka
2

  1. Strata Mechanics Institute, Polish Academy of Sciences, 27 Reymonta Str., 30-059 Kraków, Poland
  2. Tauron Wydobycie S.A. ZG Brzeszcze, ul. Kościuszki 1, 32-620 Brzeszcze, Poland
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Abstract

In longwall absolute methane emission rate forecasting, the range of the destressing zone is determined empirically and is not considered to be dependent on the geomechanical parameters of the rock strata. This simplification regarding destressing zone determination may result in significant differences between the forecast and the actual methane emission rates. During the extraction of coal seams using a system involving longwalls with caving under the conditions of low rock mass geomechanical parameters, the absolute methane emission rate forecasts are typically underestimated in comparison to the actual methane emission rates.

In order to examine the influence of the destressing zones on the final forecasting result and to assess the influence of the rock mass geomechanical parameters on the increased accuracy of forecast values, destressing zones were determined for three longwalls with lengths ranging from 186 to 250 m, based on numerical modelling using the finite difference method (FDM). The modelling results confirmed the assumptions concerning the upper destressing zone range adopted for absolute methane emission rate forecasting. As for the remaining parameters, the destressing zones yielded great differences, particularly for floor strata. To inspect the accuracy of the FDM calculation result, an absolute methane emission rate forecasting algorithm was supplemented with the obtained zones. The prepared forecasts, both for longwall methane emission rates as well as the inflow of methane to the longwalls from strata within the destressing zone, were verified via underground methane emission tests. A comparative analysis found that including geomechanical parameters in methane emission rate forecasting can significantly reduce the errors in forecast values.

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Authors and Affiliations

Andrzej Walentek
Krystian Wierzbiński
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Abstract

The methane hazard is one of the most dangerous phenomena in hard coal mining. In a certain range of concentrations, methane is flammable and explosive. Therefore, in order to maintain the continuity of the production process and the safety of work for the crew, various measures are taken to prevent these concentration levels from being exceeded. A significant role in this process is played by the forecasting of methane concentrations in mine headings. This very problem has been the focus of the present article. Based on discrete measurements of methane concentration in mine headings and ventilation parameters, the distribution of methane concentration levels in these headings was forecasted. This process was performed on the basis of model-based tests using the Computational Fluid Dynamics (CFD). The methodology adopted was used to develop a structural model of the region under analysis, for which boundary conditions were adopted on the basis of the measurements results in real-world conditions. The analyses conducted helped to specify the distributions of methane concentrations in the region at hand and determine the anticipated future values of these concentrations. The results obtained from model-based tests were compared with the results of the measurements in realworld conditions. The methodology using the CFD and the results of the tests offer extensive possibilities of their application for effective diagnosis and forecasting of the methane hazard in mine headings.

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Authors and Affiliations

Jarosław Brodny
Magdalena Tutak
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Abstract

The paper presents the results of a study of methane adsorption on coal samples with various degrees of metamorphism, coming from the Polish and Czech parts of the Upper Silesian Coal Basin (USCB). The range of coalification of the samples was from bituminous with vitrinite reflectance Ro equal to about 0.5% to para-anthracite coals with Ro equal to over 2%. The methane adsorption capacity was determined at the temperature 303 K for each of the studied coal seams. Methane adsorption isotherms were approximated using the Langmuir model. The relationship between the Langmuir isotherm parameters (am and PL) and the degree of coalification was presented. It was shown that the degree of coalification of the coal substance affects the adsorption ability of coal with respect to methane and determines the value of the Langmuir isotherm parameters. The study was conducted in order to present the distribution of adsorption capacity of Upper Silesian coals in relation to improving work safety in active mines as well as designing technologies that use coal bed methane (CBM) from balance and off-balance resources.
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Bibliography

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Authors and Affiliations

Barbara Dutka
1
ORCID: ORCID
Katarzyna Godyń
1
ORCID: ORCID

  1. Strata Mechanics Research Institute of the Polish Academy of Sciences, 27 Reymonta Str.,30-059 Krakow, Poland
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Abstract

It is commonly known that the cause of serious accidents in underground coal mining is methane. Thus, computational fluid dynamics (CFD) becomes a useful tool to simulate methane dispersion and to evaluate the performance of the ventilation system in order to prevent mine accidents related to methane. In this study, numerical and experimental studies of the methane concentration and air velocity behaviour were carried out. The experiment was conducted in an auxiliary ventilated coal heading in Turkish Hard Coal Enterprises (TTK), which is the most predominant coal producer in Turkey. The simulations were modeled using Fluent-Ansys v.12. Significant correlations were found when experimental values and modeling results were compared with statistical analysis. The CFD modeling of the methane and air velocity in the headings especially uses in auxiliary ventilation systems of places where it is hard to measure or when the measurements made are inadequate.
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Authors and Affiliations

Gülnaz Daloğlu
1
Mustafa Önder
1
Teresa Parra
2

  1. Eskişehir Osmangazi Üniversitesi Müh. Mim. Fak. Maden Mühendi sliği Bölümü, 26480 Eskişehir, Turkey
  2. University of Valladolid, Department of Energy and Fluid Mechanics, Valladolid, Spain
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Abstract

The mining in seams with a high methane content by means of a longwall system, under conditions of high extraction concentration, results in exceeding methane concentrations allowed by the regulations at workings of the longwall environment, with the effect of mining machines’ standstill periods. The paper is a part of a study supporting the development of a system for shearing cutting speed control at the longwall, which should substantially reduce the production standstills due to exceeded limits and switching off the supply of electric equipment. Such a control system may be appropriate for longwalls ventilated using “Y” and “short Y” methods. Efficient Computer simulations of the 3D airflow and methane propagation may assist the design and initial evaluation of the control system performance. First chapters present studies that are necessary for a proper formulation of the properties of the longwall model. Synthetic analysis of production during the period of longwall operation allowed one to choose the input assumptions to carry out ventilation-methane computations in a CFD numerical model of longwall Z-11. This study is followed by a description of the model that is used for a case study, considering three variants of the shearer position. Finally, initial simulation results and directions of further studies are discussed.
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Authors and Affiliations

Tomasz Janoszek
1
ORCID: ORCID
Jerzy Krawczyk
2
ORCID: ORCID

  1. Central Mining Institute (GIG), 1 Gwarków Sq., 40-166 Katowice, Poland
  2. Strata Mechanics Research Institute, Polish Academy of Science, 27 Reymonta Str., 30-059 Kraków, Poland
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Abstract

The closure of deep mines, featuring multi level seam extraction, lasts many years. During this time period, the ventilation system must ensure adequate working conditions, and ensure the safety and stability of fan operation in gas and fire hazards conditions. The analysis of air flows and methane inflows during the progress of mining mine excavations closure, is the primary object of the article. Execution of such analysis requires knowledge of the mining mine excavations’ closure schedule, the structure of the ventilation system under consideration, the values of the parameters describing the air flows delivered to the mine excavations, and the current characteristics of operating fans and predicted methane exhalation. A computer database, currently being updated by a mine ventilation department for the VentGraph-Plus computer software, has been used simulate the various ventilation scenarios experienced, during the final stage of closure, including the shutdown of the main fans and the backfilling of shafts. The results of case study, containing 2 variants of simulated examples, are presented in the form of diagrams of methane concentration changes in time at characteristic places of the mine. The completed simulations of ventilation processes during the closure of mine excavations and transfer of inflowing methane, indicate useful possibilities of the computational tool used.
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Authors and Affiliations

Wacław Dziurzyński
1
ORCID: ORCID
Jerzy Krawczyk
1
ORCID: ORCID
Teresa Pałka
1
ORCID: ORCID
Andrzej Krach
1
ORCID: ORCID
Przemysław Skotniczny
1
ORCID: ORCID

  1. Strata Mechanics Research Institutes of Polish Academy of Science, 27 Reymonta Str., 30-059 Kraków, Poland
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Abstract

The rational management of underground space, especially when used for various purposes, requires a comprehensive approach to the subject. The possibility of using the same geological structures (aquifers, hydrocarbon reservoirs, and salt caverns) for the storage of CH4, H2 and CO2 may result in conflicts of interest, especially in Poland. These conflicts are related to the use of the rock mass, spatial planning, nature protection, and social acceptance.
The experience in the field of natural gas storage can be transferred to other gases. The geological and reservoir conditions are crucial when selecting geological structures for gas storage, as storage safety and the absence of undesirable geochemical and microbiological interactions with reservoir fluids and the rock matrix are essential. Economic aspects, which are associated with the storage efficiency, should also be taken into account.
The lack of regulations setting priorities of rock mass development may result in the use of the same geological structures for the storage of various gases. The introduction of appropriate provisions to the legal regulations concerning spatial development will facilitate the process of granting licenses for underground gas storage. The provisions on area based nature protection should take other methods of developing the rock mass than the exploitation of deposits into account. Failure to do so may hinder the establishment of underground storage facilities in protected areas. Knowledge of the technology and ensuring the safety of underground gas storage should translate into growing social acceptance for CO2 and H2storage.
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Authors and Affiliations

Radosław Tarkowski
1
ORCID: ORCID
Barbara Uliasz-Misiak
2
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute of the Polish Academy of Sciences, Kraków, Poland
  2. AGH University of Science and Technology, Faculty of Drilling, Oil and Gas, Kraków, Poland
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Abstract

Anaerobic digestion (AD) converts organic matter and biomass waste into biogas, making it an environmentally friendly technology to improve energy resources for a wide range of applications. Jerusalem artichoke straw (JAS) has an enriched content of cellulose and exhibits a high potential for methane production. AD-based production of methane can eff ectively utilize waste JAS. This study investigated the AD performance of JAS to explore the enhancement of methane yields by employing a Box-Behnken experimental design (BBD) of response surface methodology (RSM). The overall goal was to identify the optimal levels of pretreatment factors, including HCl concentration, pretreatment time, and pretreatment temperature, for producing optimal biomethane yields from JAS. The highest value of methane production achieved was 256.33 mL g-1VS by using an optimal concentration of HCl as 0.25 M, a pretreatment time of 10 h, and a pretreatment temperature of 25°C. These results inform the future application of JAS in enhanced methane production.
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Authors and Affiliations

Yan Meng
1
Yi Li
1
Laisheng Chen
1
Rui Han
1

  1. Qinghai Key Laboratory of Vegetable Genetics and Physiology, Academy of Agriculture and Forestry Sciences, Qinghai University, Xining, Qinghai 810016, China
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Abstract

The paper presents the results of anaerobic digestion and co-digestion under mesophilic conditions in the OxiTop system and in lab-scale fermentors. The goal of the study was to determine the effect of reaction-based oil waste on biogas production in co-fermentation with sewage sludge (mixture of thickened primary and excess sludge). The average water content in sewage sludge was 97 %, with 70 % of total volatile solids concentration (TVS) in total solids. Weight content of oil waste in the mixture of sewage sludge ranged from 15 to 45 % (w/w) and the increase in TVS to 83.7 % was observed. The primary investigations of gas productivity by manometrie method (OxiTop) showed that biogas production increased with increasing content of oil waste in the mixture with sewage sludge. The rate constant of the first-order kinetics for biogas production was determined. To determine the yield parameters of cofermentation, the experiment was performed in four continuously stirred anaerobic reactors with a working volume of IO drrr'. Organic loading rate (OLR) changed from 0.9 to 3.1 kg TVS/m3•d. High correlation between biogas flow rate and OLR was observed. Volumetric biogas production rate and the average methane content in the biogas increased from 0.79 to 1.98 m3/m3-d and from 52.3 to 62.3 %, respectively, as OLR increased. The results obtained in lab-scale fermentors are promising and open the possibilities of the implementation of co-fermentation of sewage sludge and oil waste.
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Authors and Affiliations

Katarzyna Bernat
Andrzej Białowiec
Irena Wojnowska-Baryła
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Abstract

The pot experiment was conducted to access the soil microorganisms biomass (physiological method – Substrate Induced Respiration) and emissions of N2O, CO2 and CH4 (photoacoustic infrared detection method), and grasses biomass (weight method). The obtained results of analysed gases were converted to CO2 equivalent. There was no effect of the microorganisms biomass on the N2O emissions. The increase in CO2 emissions was accompanied by an increase in the microorganisms biomass (r = 0.48) under the conditions of the I swath and acid soil reaction, as well as the II swath and neutral reaction ( r = 0.94). On the other hand, in the case of CH4 emission, such a relationship was noted both swaths under the conditions of neutral reaction ( r = 0.51), but a negative correlation ( r = –0.71) was noted for the acid reaction only at the II swath. The increase in the grasses biomass with the increase in the microorganisms biomass was recorded only at the II swath in neutral reaction ( r = 0.91). In a short period of time, with the neutral soil reaction with the increase in the soil microorganisms biomass, an increase in CO2 sequestration and biomass of cultivated grasses was noted. Information on the determination of the microorganisms groups responsible mainly for the transformation of carbon compounds and CO2 and CH4 emissions from the soils of grasslands would be valuable scientifically.
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Authors and Affiliations

Renata Gamrat
1
ORCID: ORCID
Małgorzata Gałczyńska
1
ORCID: ORCID
Adam Brysiewicz
2
ORCID: ORCID

  1. West Pomeranian University of Technology in Szczecin, al. Piastów 17, 70-310 Szczecin, Poland
  2. Institute of Technology and Life Sciences – National Research Institute, Falenty, Poland
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Abstract

This paper presents the results of investigations into dry methane reforming (DMR). The process was aimed at obtaining synthesis gas required for the production of dimethyl ether (DME). The effect of temperature, pressure and inlet gas composition on the process was determined in the experimental part of this work. The tests were carried out in a laboratory tubular reactor over a Ni/CaO–Al2O3 catalyst. The obtained experimental results were used to verify literature kinetic data and to develop a mathematical model of the DMR process.
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Authors and Affiliations

Robert Cherbański
1
ORCID: ORCID
Ewelina Franczyk
2
Michał Lewak
1
Piotr Machniewski
1
Eugeniusz Molga
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Chemical and Process Engineering, ul. Warynskiego 1, 00-645 Warsaw, Poland
  2. Łukasiewicz Research Network – New Chemical Syntheses Institute, Al. Tysiaclecia Panstwa Polskiego 13a, 24-110 Puławy, Poland
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Abstract

The paper discusses the application possibilities of ceramic foam in a thermal combustion process of a lean methane-air mixture. The experiments were done in a ceramic foam bed. The foam (Vukopor ® A) was made mainly of Al 2O 3. The foam samples were packed in a tubular reactor symmetrically placed in a laboratory furnace. It was assumed that the tested foam should have a surface close to the monolith surface area which was tested in a previous work (Pawlaczyk and Gosiewski, 2015). Pore density of the tested foam was 10 PPI. The tested air mixture contained 0.51 - 0.76 vol. % of methane. The results show that thermal methane oxidation in foam is possible in the acceptable range of temperatures. The combustion process in foam is characterized by similar ignition temperature to tests carried out in monolith, a more intense course, and better methane conversion at lower temperatures.
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Authors and Affiliations

Anna Pawlaczyk-Kurek
1
ORCID: ORCID
Aleksandra Janusz-Cygan
1
ORCID: ORCID

  1. Polish Academy of Sciences, Institute of Chemical Engineering, Baltycka 5, 44-100 Gliwice, Poland

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