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Abstract

AISI 316L steel was subjected to nitrocarburizing under glow discharge conditions, which was followed by DLC (diamond-like carbon) coatings deposition using the same device. The coatings were applied under conditions of direct current and pulsed glow discharge. In order to determine the influence of the produced nitrocarbon austenite layer and the type of discharge on the microstructure and mechanical properties of the coatings, the following features were analysed: surface roughness, coating thickness, structure, chemical composition, adhesion and resistance to frictional wear. For comparison purposes, DLC coatings were also deposited on steel without a nitrocarburised layer. The obtained results indicate a significant influence of the type of glow discharge on the roughness, hardness, nitrogen content and of the nitrocarburised layer on the resistance to wear by friction and adhesion of the produced coatings.
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Authors and Affiliations

T. Borowski
1
ORCID: ORCID
K. Kulikowski
1
ORCID: ORCID
M. Spychalski
1
ORCID: ORCID
K. Rożniatowski
1
ORCID: ORCID
B. Rajchel
2
B. Adamczyk-Cieślak
1
ORCID: ORCID
T. Wierzchoń
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Materials Science and Engineering, 141 Wołoska Str., 02-507 Warszawa, Poland
  2. Polish Academy of Sciences, Institute of Nuclear Physics, Poland
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Abstract

Nitrogen-doped DLC (diamond-like carbon) coatings were produced on 316L nitrided austenitic steel in direct current and pulsed glow discharge conditions. The chemical composition, surface topography, hardness and corrosion resistance of the obtained carbon coatings were examined. The coatings varied in surface morphology, roughness and hardness. Direct current glow discharge made it possible to produce a coating characterized by lower hardness, greater thickness and higher nitrogen content. The coating featured improved corrosion resistance and adhesion compared to coatings produced in the pulsed process.

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Authors and Affiliations

T. Borowski
ORCID: ORCID
M. Spychalski
ORCID: ORCID
K. Rożniatowski
ORCID: ORCID
K. Kulikowski
ORCID: ORCID
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Abstract

The low adherence of diamond-like carbon (DLC) films on titanium (Ti) alloys can be improved by using interlayer coatings. In this study, DLC (a-C:H) films were deposited using radio-frequency plasma-enhanced chemical vapor deposition (rf-PECVD), and a TiCN interlayer was applied between the extra low interstitial (ELI) grade of Ti-6Al-4V alloy and a-C:H film. The characteristics of the a-C:H-coated Ti-6Al-4V ELI alloy were investigated using field emission scanning electron microscopy, Vickers hardness, and scratch and wear tests. The DLC (a-C:H) films deposited by rf-PECVD had a thickness of 1.7 µm, and the TiCN interlayer had a thickness of 1.1 µm. Vickers hardness of the DLC (a-C:H) films were increased as a result of the influence of the TiCN interlayer. The resulting friction coefficient of the a-C:H-coated Ti-6Al-4V with the TiCN interlayer had an extremely low value of 0.07.

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Authors and Affiliations

Kwangmin Lee
ORCID: ORCID
Seokil Kang

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