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Number of results: 33
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Abstract

This article discusses regulations on the management of rock mass resources more broadly than previous literature in this area. Significant changes in the directions of globalization development as well as the transformations and disruptions of existing raw-material supply chains and changes in their structure call for verification of and changes in regulations on raw-material management in individual countries, not only in the UE. The article examines the current EU regulations and their amendments in Poland. The article presents problems that have arisen during works on the necessary regulatory reform of the following policies: development, spatial (land-use), raw material, geology and mining, environmental protection, and waste and water management. The article shows that strategies, policies, and regulations prepared simultaneously, which were to be correlated with the horizontally integrated National Development Concept, are not. This should effectively enhance the country’s raw-material security. Deficiencies have been highlighted both in assumptions and procedures adopted in developing said documents. The author also emphasizes the need to balance competing values and make necessary choices when specific solutions affect at least two competitive areas, e.g. mineral deposits vs. water, farmlands or woodlands, critical infrastructure, housing, investment in the defense sector. The need is highlighted to rationally and sustainably manage resources and country space, to protect and explore them, and plan their management. The author justifies the need for a new Act of the Code status –that comprehensively and consistently regulates both the management of rock mass resources and land and water resources, and the country space management.
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Authors and Affiliations

Jan Andrzej Stefanowicz
1
ORCID: ORCID

  1. Kancelaria Juris sp. z o.o., Warszawa, Poland
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Abstract

The domestic (Polish) lignite deposits, including the Bełchatów deposit, are classified as multi- mineral and multi-raw materials. Ensuring the possibility of using a significant part of all minerals present in this type of deposits should be a matter of priority for mines. Over several dozen years of operation, the Bełchatów Lignite Mine, based on its own experience in documenting and exploiting both the main mineral and accompanying minerals, as well as rock mass components that are not solid minerals, this mine has developed a new approach to the problem of the comprehensive use of deposit resources. The content of the article is an attempt to answer the question: do the applicable laws guarantee a comprehensive and rational use of mineral deposits whose resources are non-renewable? On the example of the area of the Bełchatów lignite deposit, the comprehensive and rational use of mineral resources was analysed. It was indicated that the reasons for their use result from the lack of appropriate organizational, economic and financial solutions. Particular attention was paid to the need to modify the licensing procedures for prospecting, documenting and extracting minerals. It seems reasonable to introduce multi-resource concessions, which are an important element of the circular economy. Therefore, proposals were formulated regarding the introduction of additional legal regulations and instruments of an economic and financial nature. These would be able to guarantee the comprehensive and rational use of most mineral resources.
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Authors and Affiliations

Elżbieta Hycnar
1
ORCID: ORCID
Tadeusz Ratajczak
2
ORCID: ORCID
Ryszard Uberman
2
ORCID: ORCID

  1. AGH University of Kraków, Poland
  2. Mineral and Energy Economy Research Institute PAS, Kraków, Poland
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Abstract

Municipal waste is a global issue and they are generated in all countries around the world. Both in the European Union and the United States, a common method of non-recyclable waste utilization is thermal incineration with energy recovery. As a result of this treatment, residual waste like bottom ash, air pollution control residues and fly ashes are generated. This research shows that residues from waste incineration can be a potential source of critical raw materials. The analysis of the available literature prove that the residues of municipal waste incinerators contain most of the elements important for the US and EU economies. Material flow analysis has shown that each year, the content of elemental copper in residues may be 29,000 Mg (USA) and 51,000 Mg (EU), and the amount of rare earth elements in residues exceeds their mining in the EU. In the case of other elements, their content may exceed their extraction by even over 300%. The recovery of elements is difficult due to their encapsulation in the aggregate matrix. The heterogeneous nature of residues and the many interactions between different components and incineration techniques can make the process of recovery complicated. Recovery plants should process as much of the residues as possible to make their recovery profitable. However, policy makers from the EU and the US are introducing new legal regulations to increase the availability of critical raw materials. In the EU, new regulations are planned that will require at least 15% of the annual consumption of critical raw materials to come from recycling. Therefore, innovative technologies for recovering critical raw materials from waste have a chance to receive subsidies for research and development.
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Authors and Affiliations

Radosław Jędrusiak
1
ORCID: ORCID
Barbara Bielowicz
2
ORCID: ORCID
Agnieszka Drobniak
3 4
ORCID: ORCID

  1. Krakowski Holding Komunalny Spółka Akcyjna w Krakowie; AGH University of Kraków, Poland
  2. AGH University of Kraków, Poland
  3. University of Silesia in Katowice, Poland
  4. Indiana University, Indiana Geological and Water Survey; United States
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Abstract

There is a sulfide mineralization vein type in the Cindakko area, Maros Regency, South Sulawesi. The results of mineralogical studies on the Cindakko prospects for sulfide ore mineralization are explained in this paper. Petrographic, mineragraphic, and XRD methods analyzed the mineralization and alteration samples from the research area. The results showed that the host rock mineralization is basalt, a member of the Baturappe-Cindakko Volcano from the Late Miocene age. The identified hydrothermal alteration mineral associations include quartz, chlorite, epidote, biotite, actinolite, and pyrite, generally formed in propyllitic alteration zones mainly characterized by chlorite. The analysis provides the occurrence of mineralization types: crustiform-banding quartz veins, vuggy quartz, and disseminated, contain hypogenic pyrite, chalcopyrite, sphalerite, bornite, and tennantite ores, and supergene ore minerals in the form of covellite. Ore textures recognized under a microscope are intergrowth, replacement, open-space filling, and exsolution. Based on the interpretation of temperature stability of hydrothermal alteration minerals, it is concluded that it was formed at approximately 200 to 320°C with the hydrothermal fluid pH almost neutral. The fundamental characteristics of hydrothermal alteration, ore mineral assemblage and texture, mineralization type, temperature range form, and hydrothermal fluid pH indicate that the mineralization in the Cindakko Prospect is an epithermal type.
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Authors and Affiliations

Ibnu Munzir
1
ORCID: ORCID
Arif Arif
2
Musri Mawaleda
3
Irzal Nur
4

  1. Institute of Geological Science, Jagiellonian University, Kraków, Poland
  2. Department of Earth Resources Engineering, Kyushu University; Japan
  3. Geology Engineering Department, Hasanuddin University, Gowa 92171, South Sulawesi; Indonesia
  4. Mining Engineering Department, Hasanuddin University, Gowa 92171, South Sulawesi; Indonesia
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Abstract

Natural stones are used as coating material on the exteriors and terraces of buildings in architecture, and in places such as entrances, halls, living rooms, kitchens, bathrooms and stairs in interior spaces. Limra limestone and travertine are used as natural building materials in many structures depending on their colors. However, the water absorption values of these two natural stones are high due to their porosity, resulting in negative effects from atmospheric conditions. In this study, two different carbonate-based natural stones, limra limestone and travertine, were treated with two different water-repellent chemicals, one solvent-based and one water-based. After application, thermal shock tests were performed with a sodium chloride solution consisting of twenty cycles. The changes in the weights of samples dried to constant mass, ultrasonic permeability, Leeb hardness, and color change values in the samples were determined after the thermal shock tests. In addition, the effects of water-repellent chemicals on the formation of NaCl crystals accumulated in the pores of the rocks were examined by SEM and EDX analysis. Changes in non-destructively measured values were compared with the values of reference samples without surface protection. The solvent- based water-repellent chemical made the sample surface more hydrophobic than the water-based repellent. In both types of natural stones, the solvent-based water repellent chemical showed more protective properties against salt crystallization under thermal shock conditions compared to the water-based repellent.
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Authors and Affiliations

Gökhan Ekincioğlu
1
ORCID: ORCID

  1. Kırşehir Ahi Evran University, Kaman Vocational School, Department of Mining and Mineral Extraction,Turkey
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Abstract

Nowadays, hydrogen is considered a potential successor to the current fossil-fuel-based energy. Within a few years, it will be an essential energy carrier, and an economy based on hydrogen will require appropriate hydrogen storage systems. Due to their large capacity, underground geological structures (deep aquifers, depleted hydrocarbon fields, salt caverns) are being considered for hydrogen storage. Their use for this purpose requires an understanding of geological and reservoir conditions, including an analysis of the preparation and operation of underground hydrogen storage. The results of hydrogen injection and withdrawal modeling in relation to the deep Lower Jurassic, saline aquifer of the Konary geological structure (trap) are presented in this paper. A geological model of the considered structure was built, allowable pressures were estimated, the time period of the initial hydrogen filling of the underground storage was determined and thirty cycles of underground storage operations (gas injection and withdrawal) were simulated. The simulations made it possible to determine the essential parameters affecting underground hydrogen storage operation: maximum flow rate of injected hydrogen, total capacity, working gas and cushion gas capacity. The best option for hydrogen storage is a two-year period of initial filling, using the least amount of cushion gas. Extracted water will pose a problem in relation to its disposal. The obtained results are essential for the analysis of underground hydrogen storage operations and affect the economic aspects of UHS in deep aquifers.
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Authors and Affiliations

Katarzyna Luboń
1
ORCID: ORCID
Radosław Tarkowski
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Kraków, Poland
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Abstract

Energy transition is a process that affects entire regions, not only reducing the prevailing socio- -economic conditions but most importantly, creating a new framework of functioning for their inhabitants. The changes that are taking place can be described as territorial stresses, which are factors that affect not only the psychological well-being of residents but also the economic, demographic, technological and ecological conditions of the regions. The article presents the partial results of research work conducted within the EN TRAN CES project. The authors compare two carbon-intensive regions: Kraków Metropolitan Area (high air pollution area) and Silesia (coal mining area). Comparing the results of the two components and thus the research methods: - the identification and systematization of the socio-cultural stress situation (a component describing events relevant to the transformation of the regions from 1945–2022 and the sparing of its significance on the development conditions in the regions; - the assessment of the adaptive capacity of the residents based on their attachment to the place, individual adaptation strategies for resolving tensions and the level of life satisfaction (socio-psychological component).
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Authors and Affiliations

Wit Hubert
1
ORCID: ORCID
Wojciech Kowalik
2
ORCID: ORCID
Aleksandra Komorowska
1
ORCID: ORCID
Dominik Kryzia
1
ORCID: ORCID
Monika Pepłowska
1
ORCID: ORCID
Lidia Gawlik
1
ORCID: ORCID

  1. Mineral and Energy Economy Research Institute PAS, Kraków, Poland
  2. AGH University of Krakow, Kraków, Poland
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Abstract

The suitability of several low-labor geostatistical procedures in the interpolation of highly positively skewed seismic data distributions was tested in the Baltic Basin. These procedures were a combination of various estimators of the model of spatial variation (theoretical variogram) and kriging techniques, together with the initial data transformation to normal distribution or lack thereof. This transformation consisted of logarithmization or normalization using the anamorphosis technique. Two variations of the theoretical variogram estimator were used: the commonly used classical Matheron estimator and the inverse covariance estimator (InvCov), which is robust with regard to non-ergodic data. It was expected that the latter would also be resistant to strongly skewed data distributions. The kriging techniques used included the commonly used ordinary kriging, simple kriging useful for standardized data and the non-linear median indicator kriging technique. It was confirmed that normalization (anamorphosis) is the most useful and less laborious geostatistical procedure of those suitable for such data, which results in a standardized normal distribution. The second, not obvious statement for highly skewed data distributions suggests that the non-ergodic inverted covariance (InvCov) estimator of variogram has an advantage over the Matheron’s estimator. It gives a better assessment of the C 0 (nugget effect) and C (sill) parameters of the spatial variability model. Such a conclusion can be drawn from the fact that the higher the estimation of the relative nugget effect L = C 0/(C 0 + C) using the InvCov estimator, the weaker the correlation between the kriging estimates and the observed values. The values of the coefficient L estimates obtained by using the Matheron’s estimator do not meet this expectation.
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Authors and Affiliations

Justyna Sowińska-Botor
1
Wojciech Mastej
1
ORCID: ORCID
Tomasz Maćkowski
1
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Kraków, Poland
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Abstract

Sorting coal and gangue is important in raw coal production; accurately identifying coal and gangue is a prerequisite for effectively separating coal and gangue. The method of extracting coal and gangue using image grayscale information can effectively identify coal and gangue, but the recognition rate of the sorting process based on image grayscale information needs to substantially higher than that which is needed to meet production requirements. A sorting method of coal and gangue using object surface grayscale-gloss characteristics is proposed to improve the recognition rate of coal and gangue. Using different comparative experiments, bituminous coal from the Huainan area was used as the experimental object. It was found that the number of pixel points corresponding to the highest level grey value of the grayscale moment and illumination component of the coal and gangue images were combined into a total discriminant value and used as input for the best classification of coal and gangue using the GWO-SVM classification model. The recognition rate could reach up to 98.14%. This method sorts coal and gangue by combining surface greyness and glossiness features, optimizes the traditional greyness-based recognition method, improves the recognition rate, makes the model generalizable, enriches the research on coal and gangue recognition, and has theoretical and practical significance in enterprise production operations.
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Authors and Affiliations

Gang Cheng
1
Yifan Wei
1 2
ORCID: ORCID
Jie Chen
1
Zeye Pan
1

  1. School of Mechanical Engineering, Anhui University of Science and Technology, Huainan, China
  2. State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines,Anhui University of Science and Technology, Huainan, China
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Abstract

Turkey has 19.3 billion tons of lignite reserves and the vast majority of these Neogene lignite deposits are preferred for use in thermal power plants due to their low calorific value. The calorific value of lignite used in thermal power plants for electricity generation must be kept under constant control. In the control of calorific value, the estimation of the lower and higher heating values (LHV and HHV) of lignite is of great importance. In the literature, there are many studies that establish a relationship between the heating values of coal and proximate and ultimate analysis variables. In the studies dealing with proximate analysis data, it is observed that although the coefficients of the obtained multiple linear regression models (MRM) are statistically insignificant, these models are used to predict heating values because of the meaningful correlation coefficient. In this study, it is investigated whether moderator variables are effective on LHV estimation with proximate analysis data collected from forty-one lignite basins in different regions of Turkey, and a moderator variable analysis (MVA) model is developed to be used for the prediction of LHV. As a result of the study, it is found that the proposed MVA model is in accordance with observation values (coefficient of determination R 2 = 0.951), and absolute and standard errors are also small. Therefore, it is concluded that the use of MVA to estimate the LHV of Turkey’s lignite is found to be more statistically meaningful.
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Authors and Affiliations

Mehmet Aksoy
1
ORCID: ORCID

  1. Eskişehir Osmangazi University, Turkey
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Abstract

Human-induced climate change is caused by the emission of pollutants into the environment. One of the sources of the formation of harmful compounds is the combustion of solid fuels in heating boilers. These contribute to the occurrence of respiratory and circulatory system diseases, allergies, cancer and developmental disorders in children. In this research, the concentrations of carbon monoxide, nitrogen oxides, sulfur dioxide and hydrocarbons in samples obtained from the combustion of hard coal intended for fuel in household furnaces were measured using an exhaust-gas analyzer equipped with electrochemical sensors. The combustion of test samples was performed using an up-draft research furnace. The results show that the average total concentration of the tested pollutants emitted from the combustion of type 32 and type 33 coal is over 20% lower compared to the emission from the combustion of type 31 coal. Moreover, the concentration of carbon monoxide, the permissible levels of which are regulated by the chimney emission standards, is significantly lower during the combustion of type 32 and type 33 coal compared to the combustion of type 31 coal. Therefore, one of the ways to locally reduce pollutant emission from the combustion of solid fuels in home heating boilers might be the accurate choice of the type of hard coal used for heating. Before the use of coal stoves in households is completely dismissed, local regulations can be introduced to limit emissions in places where air quality indicators are exceeded and improve the health of the population.
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Authors and Affiliations

Aleksandra Kęska
1
ORCID: ORCID
Iwona Jatowczyc-Borkowska
1
ORCID: ORCID

  1. Wrocław University of Science and Technology, Wrocław, Poland
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Abstract

Here One important aspect of the process of anaerobic stabilisation of sewage sludge in medium and large sewage treatment plants, in addition to sludge mineralisation, is the acquisition of a valuable source of energy, which is biogas. There are well-known methods of intensifying the process of methane fermentation by subjecting sludge to disintegration using physical factors, i.e. ultrasonic field. Acetate production is the ratelimiting step in the acetate consumption pathway and affects the efficiency of the anaerobic stabilisation process. The product of the first stage of the process is also the substrate for the next stage. Therefore, it is advisable to subject sewage sludge to disintegration, which increases its susceptibility to biodegradation. Sludge modification with the above-mentioned method causes a significant increase in the concentration of organic substances in the supernatant liquid. The reflection of the physical and chemical transformations of sludge in the disintegration processes is the change in their structure expressed by the increase in the degree of particle dispersion. The disintegration of sludge using sonolysis is an effective process solution, both in terms of technology and energy, in terms of obtaining biogas, which is a valuable source of energy.
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Authors and Affiliations

Iwona Zawieja
1
ORCID: ORCID

  1. Faculty of Infrastructure and Environment, Czestochowa University of Technology,Dąbrowskiego 73, 42-201, Czestochowa, Poland, ORCID 0000-0002-4480-8736
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Abstract

The two aims of this study were to obtain stable thyme-oil loaded nanoemulsions using the statistical design of experiment method (DOE) and to confirm their antimicrobial and disinfecting properties. Thyme oil was used as the oil phase, ECO Tween ® 80 acted as an emulsifier, and the rest of the formulation was deionized water. Ultrasonication was chosen as the method of obtaining the nanoemulsions. It was checked whether the input parameters (oil concentration, emulsifier concentration, amplitude, and sonication time) had a significant impact on the output parameters (nanoemulsion particle size, polydispersity index, viscosity, and stability over time). For the formulations selected on the basis of the statistical data analysis, the values of minimum inhibitory concentrations (MIC) and minimum biocidal concentrations (MBC/MFC) were determined in relation to 10 bacterial strains and 10 strains fungi (filamentous fungi, yeast-like fungi). The results obtained from the statistical analysis showed that the optimal concentration of the thyme oil in nanoemulsion should amount up to 2%. Biological studies proved that the obtained formulation had stronger antibacterial and antifungal activity compared to pure oil. Moreover, it was shown that the nanoemulsion caused the required for disinfectants reduction of > 5 log of bacterial strains ( S. aureus, P. aeruginosa) and > 4 log of fungal strains ( C. albicans) after 30 minutes.
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Authors and Affiliations

Małgorzata Miastkowska
1
ORCID: ORCID
Anna Łętocha
1
Alicja Michalczyk
2
ORCID: ORCID

  1. Department of Chemical Engineering and Technology, Cracow University of Technology,Cracow, Poland
  2. Lukasiewicz - Research Network-Institute of Industrial Organic Chemistry, Warsaw, Poland
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Abstract

Humic acids (HAs) are components of natural organic matter found in soil and are considered responsible for its fertility. They can be extracted from sources such as peat and lignite on an industrial scale. In order to increase the efficiency and reduce the duration of the alkaline extraction step, microwave-assisted extraction (MAE) was used in this study. Statistical analysis was implemented to describe the influence of microwave power, temperature, and time on the yield of HA extraction. Experimental points were created on the basis of the matrix, according to the Box-Behnken design. Statistical analysis showed the importance of linear correlations between the process parameters and the response. The last part of the presented study was to create the polynomial model and response surface plots, attached in poster form, which describe the result as a function of parameters of the MAE process.
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Authors and Affiliations

Kinga M. Marecka
1
ORCID: ORCID
Dominik Nieweś
1
ORCID: ORCID
Magdalena Braun-Giwerska
1
ORCID: ORCID
Marta Huculak-Mączka
1
ORCID: ORCID

  1. Wrocław University of Science and Technology, Department of Chemical Process Engineering and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
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Abstract

In this study continuous pilot plant configuration for helical flow type Ultrasound Assisted Extraction (UAE) reactor is decribed, and carotenoid extraction results from carrot- water extraction system are presented. The pilot plant configuration consists of all necessary unit operations from washed raw material to extracted natural ingredient product. According to our best knowledge the published data from the whole processing line of continuous UAE has not been described. One of the subjects in this study has been patented in-house UAE design which enables to prolong extractable solids material residence time under ultrasound field. Process operation was verified with several hour pilot tests. Extraction results have been presented in case of carotenoids from fresh carrots and strawberry extract from frozen strawberries. The extracted carotenoid concentration was improved 40 % comparison to macerated carrot results, and absorbance ratio of strawberry extract increased by factor 5.
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Authors and Affiliations

Tuomas Koiranen
1
ORCID: ORCID
Jussi Tamminen
2
ORCID: ORCID
Dmitry Gradov
1
ORCID: ORCID

  1. Lappeenranta-Lahti University of Technology, Department of Separation Science, Yliopiston katu 34, 53851 Lappeenranta, Finland
  2. Satakunta University of Applied Sciences, Satakunnankatu 23 28130 Pori, Finland
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Abstract

The paper presents research on a novel catalytic carrier, called "streamlined structure". The carrier is a short-channel monolith, whose walls are shaped like an airfoil profile (airplane wing). The intention is heat transfer intensification coupled with moderate flow resistance. Streamlined structures with triangular channel cross-section, 3mm, 6mm and 12 mm long, were designed and manufactured using the SLM (Selective Laser Melting) technique for the experimental verification. The structures were modelled using the CFD (Computational Fluid Dynamics) software to derive flow resistance, flow patterns and heat transfer coefficients. Compared to classic structures, CFD showed intensified heat transfer, combined with acceptable flow resistance increase. CFD proved the lack of an inlet vortex, which in classical structures seriously reduces the intensity of heat transfer. The CFD has been satisfactorily verified by experiments.
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Authors and Affiliations

Katarzyna Sindera
1
ORCID: ORCID
Mateusz Korpyś
1
ORCID: ORCID
Marzena Iwaniszyn
1
ORCID: ORCID
Anna Gancarczyk
1
ORCID: ORCID
Mikołaj Suwak
1
Andrzej Kołodziej
1 2
ORCID: ORCID

  1. Polish Academy of Sciences, Institute of Chemical Engineering, Bałtycka 5, 44-100 Gliwice, Poland
  2. Opole University of Technology, Faculty of Civil Engineering and Architecture, Katowicka 48, 45-061 Opole, Poland
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Abstract

Control of reaction conditions, short residence times and completely inert surfaces are of major importance when studying aging mechanisms by soot formation. The use of ceramics as reactor material in combination with a special reactor design allows control over industrially relevant reaction conditions (T max = 1100 °C, t Residence = 50 ms) and sample shapes while avoiding interfering side reactions. We have successfully tested new ceramic kinetic reactors in two model systems of propane dehydrogenation and reactor coil material. The presented reactor setup allows long-term measurements with industrially relevant material samples under controlled conditions. In both model reactions it was possible to perform studies on regeneration methods by oxidation and to study the effects on the material using different in-situ and ex-situ techniques including 31 P MAS NMR measurements.
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Authors and Affiliations

Jörn H. Matthies
1
Daniel Dittmann
2
ORCID: ORCID
Michael Dyballa
2
ORCID: ORCID
Ulrich Nieken
1
ORCID: ORCID

  1. University of Stuttgart, Institute of Chemical Engineering, Germany
  2. University of Stuttgart, Institute of Technical Chemistry, Germany
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Abstract

Currently, there is a tendency for new forms of carrier-drug systems to appear with prolonged and controlled release. However, in order to design medical or pharmaceutical devices, which have to be characterized by high quality and the assumed parameters in real conditions, it is necessary to analyze this process based on in vitro release (IVR) testing methods. For this purpose, extracorporeal studies are carried out, which enable the determination of the release profiles of active substances using a simulated tissue-like environment. Here, we focused on the release tests of poorly water-soluble compounds (salicylic acid and fluocinolone acetonide) from the dual drug delivery system using the flow-through cell method (USP4). Additionally, bio-hybrid hydrogel matrix containing the system of thermosensitive nanocarrier with salicylic acid and fluocinolone acetonide was subjected to the following investigations: physicochemical (swelling ability, gel fraction), morphological (SEM analysis) and structural using FT-IR spectroscopy. On the basis of results, we can conclude that the USP4 method may be suitable, especially for the release tests of poorly water-soluble components introduced into modern forms of drug administration, such as polymeric matrices, hydrogels, nano- and microcarriers as well as hybrid systems.
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Authors and Affiliations

Katarzyna Bialik-Wąs
1
ORCID: ORCID
Paulina Sapuła
1
ORCID: ORCID

  1. Cracow University of Technology, Faculty of Chemical Engineering and Technology, Department of Organic Chemistry and Technology, Warszawska 24, 31-155 Cracow, Poland
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Abstract

Humic substances (HS) are hydrophobic parts of dissolved organic matter, which are hard to degrade using biological processes. When exposed to disinfection processes, the HS present in wastewater could lead to the formation of disinfection by-products (DBPs), which are harmful and dangerous to health. Thus, a chemical coagulation process is commonly used for HS removal. This work used a cylindrical galvanic cell (CGC) with an iron anode and a copper cathode, where the dissolution of the anode served as an alternative source of metal ions for HS coagulation. The galvanic cell current for CGC stabilized at around 0.6 mA, and the voltage fluctuated, ca. 0.5 V for all solutions. The peaks observed on cyclic voltammograms could be associated only with oxidation and dissolution of iron; no other process was identified. After the process, the structures and molecular composition of the anode surface suggest the loss of Fe mass and the formation of iron oxides due to corrosion. The initial pH of the tested solution influenced the total Fe concentration in the solution as well as colour and turbidity. The quantitative removal of HS by electrolysis and membrane filtration processes at initial pHi = 6.0 yielded 72% and 90%, respectively, after 6 and 10 min. The mechanism of sorption on the flocs of hydroxides as a primary factor in HA removal was suggested.
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Authors and Affiliations

Bartosz Libecki
1
ORCID: ORCID
Tomasz Mikołajczyk
1
ORCID: ORCID
Bogusław Pierożyński
1
ORCID: ORCID
Mateusz Kuczyński
1
ORCID: ORCID

  1. University of Warmia and Mazury in Olsztyn, Faculty of Agriculture and Forestry, Departmentof Chemistry, Łódzki Square 4, 10-727 Olsztyn, Poland
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Abstract

The hydrolysis of lignocellulosic biomass results in the production of so-called fermentation inhibitors, which reduce the efficiency of biohydrogen production. To increase the efficiency of hydrogen production, inhibitors should be removed from aqueous hydrolysate solutions before the fermentation process. This paper presents a new approach to the detoxification of hydrolysates with the simultaneous formation of in-situ deep eutectic solvents (DES). In the first stage of the study, inhibitors were identified in the real hydrolysate samples using highperformance liquid chromatography (HPLC). Four monoterpenes were tested for their potential to extract furfural (FF) with simultaneous DES formation. An optimization process of the most important parameters affecting the extraction process and DES formation (Thymol:FF) was conducted using the Central Composite Design (CCD) model. A temperature of 40 °C, pH of 7, mHBD:mHYD ratio of 2:1, and time of 50 min were selected as the optimal conditions. These results indicate the high efficiency of FF removal from hydrolysates (92.1 - 94.6 %) in a onestep process. Meanwhile, the structural properties of the formed DES measured by Fouriertransform infrared spectroscopy (FT-IR) and Nuclear magnetic resonance spectroscopy (NMR) differed only slightly from those of the DES composed of pure substances (Furfural and Thymol).
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Authors and Affiliations

Patrycja Makoś-Chełstowska
1
ORCID: ORCID
Edyta Słupek
1
ORCID: ORCID
Karolina Kucharska
1
ORCID: ORCID
Jacek Gębicki
1
ORCID: ORCID

  1. Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineeringand Chemical Technology, 80-233 Gdansk, Poland
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Abstract

Radiation therapy can be adopted for many cancers, and it can damage healthy tissues and often induces skin lesions (pain/skin irritation/itchiness/dryness/swelling/redness). Many factors influence the adverse effects of radiotherapy, such as radiation dosage, dose frequency and fractioning, the area of skin exposed to radiation and treatment length. In this paper, multiple emulsions with a nonsteroidal anti-inflammatory drug-NSAID (diclofenac) were developed and evaluated for effective topical treatment of skin lesions following anticancer therapy. Multiple emulsions with different drop sizes were prepared in a Couette- Taylor flow contactor. High encapsulation efficiency (> 90%) of diclofenac and high volume packing fraction of the internal droplets (0.54–0.96) were obtained. In addition, due to the presence of a polymer with adhesive properties - sodium carboxymethylcellulose, high emulsion stability (> 60 days) was achieved. The emulsions displayed properties of shearthinning fluids. The release study of diclofenac from a complex emulsion structure confirmed the possibility of modifying the release rates. The effectiveness of emulsion formulations was evaluated based on the viability tests of the fibroblast cell line irradiated with UV dose (15 J/m2) and then treated with the emulsion with diclofenac. The results showed that the multiple emulsion-based formulations might be appropriate carriers for the topical delivery of NSAID drugs.
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Authors and Affiliations

Agnieszka Markowska-Radomska
1
ORCID: ORCID
Patryk Skowroński
1
ORCID: ORCID
Konrad Kosicki
2
ORCID: ORCID
Ewa Dluska
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Chemical and Process Engineering,Waryńskiego 1, 00-645 Warsaw, Poland
  2. University of Warsaw, Faculty of Biology, Institute of Genetics and Biotechnology, AdolfaPawińskiego 5A, 02-106 Warsaw, Poland
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Abstract

Ammonia solutions are considered to be effective solvents for carbon dioxide absorption. Despite numerous advantages of these solvents, their high volatility is a significant technical and economic problem. Therefore, in this work, silica particles were used as additives to improve CO 2 absorption and inhibit NH 3 desorption. SiO 2 microparticles and colloidal SiO 2 particles in the concentration range of 0-0.15 wt.% were used in this study. The most favorable mass transport for CO2 absorption was at the concentration of colloidal particles of 0.05 wt.%. Under these conditions, the enhancement in the number of moles of absorbed CO 2 was above 30%. However, in solvents containing 0.01 wt.% SiO2 microparticles, the increase in CO 2 absorption was about 20%. At the same time, the addition of SiO2 particles significantly reduced the escape of ammonia from the solution. The best improvement was obtained when colloidal SiO 2 particles were added, and then NH 3 escape was decreased by about 60%. This unfavorable phenomenon was also inhibited in ammonia solutions containing SiO2 microparticles at a concentration of 0.01 wt.%.
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Authors and Affiliations

Donata Konopacka-Łyskawa
1
ORCID: ORCID
Temesgen Abeto Amibo
1 2
ORCID: ORCID
Dominik Dobrzyniewski
1
ORCID: ORCID
Marcin Łapiński
3
ORCID: ORCID

  1. Gdańsk University of Technology, Faculty of Chemistry, Department of Process Engineeringand Chemical Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
  2. School of Chemical Engineering, Jimma Institute of Technology, Jimma University, Jimma,P.O. Box-378, Ethiopia
  3. Gdańsk University of Technology, Faculty of Applied Physics and Mathematics, Institute ofNanotechnology and Materials Engineering, Narutowicza 11/12, 80-233 Gdańsk, Poland
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Abstract

In the present study, peroxymonosulfate (PMS) activation was proposed for efficient photocatalytic degradation of aspartame, acesulfame, saccharin, and cyclamate - artificial sweeteners frequently present in wastewaters and surface waters worldwide. TiO 2 nanosheets with exposed {0 0 1} facets were synthesised using the fluorine-free lyophilisation technique as a green concept for the synthesis and used for the photodegradation of selected sweeteners not susceptible to biodegradation. The synergetic effect of photocatalysis with the sulfate radical-based process was for the first time investigated. It was found that the studied artificial sweeteners were practically not susceptible to photolysis within 60 minutes of irradiation. In the presence of 2D titanium (IV) oxide, the artificial sweeteners were degraded entirely in less than 30 min, whereas the addition of peroxymonosulfate resulted in complete degradation after 10 – 15 minutes of the process.
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Authors and Affiliations

Jakub Smoliński
1
ORCID: ORCID
Agnieszka Fiszka Borzyszkowska
1
ORCID: ORCID
Paweł Kubica
2
ORCID: ORCID
Anna Zielińska-Jurek
1
ORCID: ORCID

  1. Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
  2. Department of Analytical Chemistry, Faculty of Chemistry, Gdańsk University of Technology, 7 Narutowicza 11/12, 80-233 Gdańsk
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Abstract

Environmental contamination is an urgent topic to be solved for sustainable society. Among various pollutants, microorganisms are believed to be the most dangerous and difficult to be completely inactivated. In this research, a new hybrid photoreactor assisted with rotating magnetic field (RMF) has been proposed for the efficient removal of two types of bacteria, i.e., gram-negative Escherichia coli and gram-positive Staphylococcus epidermidis. Three selfsynthesized photocatalysts were used, based on commercial titanium(IV) oxide - P25, homogenized and then modified with copper by photodeposition, as follows: 0.5Cu@HomoP25, 2.0Cu@HomoP25 and 5.0Cu@HomoP25 containg 0.5, 2.0 and 5.0 wt% of deposited copper, respectively. The response surface methodology (RSM) was employed to design the experiments and to deteremine the optimal conditions. The effects of various parameters such as copper concentration [% w/w], time [h] and frequency of RMF [Hz] were studied. Results: Analysis of variance (ANOVA), revealed a good agreement between experimental data and proposed quadratic polynomial model ((R2=0.86 for E. coli and R2=0.69 for S. epidermidis). Experimental results showed that with increasing copper concentration, time and decreasing of frequency of RMF removal efficiency was increased. Accordingly, the water disinfection efficiency of 100% in terms of the independent variables was optimized, including cooper concentration c =5 % and 2.5% w/w, time t = 3 h and 1.3 h and frequency of rotating magnetic field f = 50 Hz and 26.6 for E.coli and S. epidermidis, respectively. This study showed that response surface methodology is a useful tool for optimizing the operating parameters for photocatalytic disinfection process.
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Authors and Affiliations

Oliwia Paszkiewicz
1
ORCID: ORCID
Kunlei Wang
2
ORCID: ORCID
Marian Kordas
1
ORCID: ORCID
Rafał Rakoczy
1
ORCID: ORCID
Ewa Kowalska
2 3
ORCID: ORCID
Agata Markowska-Szczupak
1
ORCID: ORCID

  1. West Pomeranian University of Technology in Szczecin, Faculty of Chemical Technologyand Engineering, Department of Chemical and Process Engineering, Piastow 42, 71-065Szczecin, Poland
  2. Hokkaido University, Institute for Catalysis (ICAT), N21, W9, 001-0021 Sapporo, Japan
  3. Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Krakow, Poland

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