@ARTICLE{Gunia_Marcin_Assessment_2023, author={Gunia, Marcin and Ciećko, Julia and Bizon, Katarzyna}, volume={vol. 44}, number={No 3 (24th Polish Conference of Chemical and Process Engineering, 13-16 June 2023, Szczecin, Poland. Guest editor: Prof. Rafał Rakoczy and 8th European Process Intensification Conference, 31.05–2.06.2023, Warsaw, Poland.)}, journal={Chemical and Process Engineering: New Frontiers}, pages={e13}, howpublished={online}, year={2023}, publisher={Polish Academy of Sciences Committee of Chemical and Process Engineering}, abstract={The development of efficient carbon dioxide sequestration and utilization technologies is an indispensable aspect of a wide range of measures directed at reducing the negative effects of anthropogenic emissions on the environment. One route is its capture via physical adsorption and further conversion to methane in the Sabatier reaction. The sorption process can be carried out, among others, in fixed-bed adsorptive reactors, in which the packing is made up of adsorbent and catalyst particles. Proper structuring of such a hybrid bed can contribute to increasing the efficiency of both stages of the process. Of importance in this regard is, first of all, the proper management of heat transfer. This study examines the sorption step of the operation of an adsorptive reactor for CO2 sequestration and methanation using a one-dimensional non-isothermal model of a layered fixed bed. Numerical calculations for different configurations and different volume adsorbent to catalyst ratios were carried out to determine how the hybrid structure of the bed and the atypical thermal waves it induces affect the sorption process. The results obtained prove that proper tailoring of the bed can be an excellent tool to control the temperature profiles and thus the performance of the apparatus and possibly its optimization.}, type={Article}, title={Assessment of the bed macrostructuring and thermal waves impact on carbon dioxide adsorption efficiency in a hybrid fixed-bed reactor}, URL={http://www.czasopisma.pan.pl/Content/127850/PDF/e13-Accepted%20Article-2.pdf}, doi={10.24425/cpe.2023.144699}, keywords={hybrid fixed bed, CO2 sequestration, adsorptive reactor, mathematical modelling}, }