@ARTICLE{Adamczyk_Joanna_Rare_2023,
 author={Adamczyk, Joanna and Smołka-Danielowska, Danuta and Krzątała, Arkadiusz and Krzykawski, Tomasz},
 volume={vol. 39},
 number={No 2},
 journal={Gospodarka Surowcami Mineralnymi - Mineral Resources Management},
 pages={87-108},
 howpublished={online},
 year={2023},
 publisher={Komitet Zrównoważonej Gospodarki Surowcami Mineralnymi PAN},
 publisher={Instytut Gospodarki Surowcami Mineralnymi i Energią PAN},
 abstract={This study presents the results of concentrations of rare earth elements and yttrium (REY ), uranium (U), and thorium (Th) in ashes from combustion/co-combustion of biomass (20%, 40%, and 60% share) from the agri-food industry (pomace from apples, walnut shells, and sunflower husks) and hard coal. The study primarily focuses on ashes from the co-combustion of biomass and hard coal, in terms of their potential use for the recovery of rare earth elements (REE ), and the identification of the sources of these elements in the ashes. Research methods such as ICP-MS (inductively coupled plasma mass spectrometry), XRD (X-ray diffraction), and SEM -EDS (scanning electron microscopy with quantitative X-ray microanalysis) were used. The total average content of REY in ash from biomass combustion is 3.55–120.5 mg/kg, and in ash from co-combustion, it is from 187.3 to 73.5 mg/kg. The concentration of critical REE in biomass combustion ash is in the range 1.0–38.7 mg/kg, and in cocombustion ash it is 23.3–60.7 mg/kg. In hard-coal ash, the average concentration of REY and critical REY was determined at the level of 175 and 45.3 mg/kg, respectively. In all samples of the tested ashes, a higher concentration of Th (0.2–14.8 mg/kg) was found in comparison to U (0.1–6 mg/kg). In ashes from biomass and hard-coal combustion/co-combustion, the range of the prospective coefficient (Coutl) is 0.66–0.82 and 0.8–0.85, respectively, which may suggest a potential source for REE recovery. On the basis of SEM -EDS studies, yttrium was found in particles of ashes from biomass combustion, which is mainly bound to carbonates. The carriers of REY , U, and Th in ashes from biomass and hard-coal co-combustion are phosphates (monazite and xenotime), and probably the vitreous aluminosilicate substance.},
 type={Article},
 title={Rare earth elements, uranium, and thorium in ashes from biomass and hard coal combustion/co-combustion},
 URL={http://www.czasopisma.pan.pl/Content/127631/PDF/Adamczyk%20i%20inni.pdf},
 doi={10.24425/gsm.2023.145882},
 keywords={biomass, hard coal, ash, REY, mineral composition},
}