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Abstract

The aim of the study was to assess the feasibility of utilizing sodium alginate biopolymer as animmobilization carrier for laccase in the removal of indigo carmine (IC), an anionic dye. The main goal of this work was to optimize the decolourization process by selecting the appropriate immobilized enzyme dose per 1 mg of dye, as well as the process temperature. The effective immobilization of laccase using sodium alginate as a carrier was confirmed by Raman spectroscopy. An analysis of the size and geometric parameters of the alginate beads was also carried out. Tests of IC decolourization using alginate-laccase beads were conducted. Applying the most effective dose of the enzyme (320 mg of enzyme/1 mg of IC) made it possible to remove 92.5% of the dye over 40 days. The optimal temperature for the IC decolourization process, using laccase immobilized on sodium alginate, was established at 30-40ºC. The obtained results indicate that laccase from Trametes versicolor immobilized on sodium alginate was capable of decolourizing the tested dye primarily based on mechanism of biocatalysis.
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Bibliography

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Authors and Affiliations

Małgorzata Białowąs
1
ORCID: ORCID
Beata Kończak
1
Stanisław Chałupnik
1
Joanna Kalka
2
Magdalena Cempa
1
ORCID: ORCID

  1. Central Mining Institute – National Research Institute, Katowice, Poland
  2. Environmental Biotechnology Department, Faculty of Energy and Environmental Engineering,The Silesian University of Technology, Poland
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Abstract

The continuous process of urbanization and climate change has led to severe urban heat island (UHI) effects. Constructing parks with cooling capabilities is considered an effective measure to alleviate UHI effects. However, most studies only quantify the cooling effect from a maximum value perspective, lacking a measure of temperature diffusion in space. This study combines the perspectives of maximum value and accumulation to define a cold island index, quantifying the cooling effect of 40 urban parks in the main urban area of Xi'an city. The results show that, on average, urban parks can reduce the surrounding environment by approximately 2.3℃, with a cooling range of about 127.1ha, which is three times the park area. Different factors drive the measurement of the cooling effect using different cold island indexes, but all indexes are highly correlated with green space area. There are significant differences in the cooling effect among different types of parks, and overall, ecological parks have the best cooling effect. The directional spread of internal cold islands in parks is most related to park shape, while external spread is related to surrounding green spaces. The research results have practical value in the construction of parks with cooling effects and the sustainable development of cities in urban planning processes..
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Authors and Affiliations

Yao Zhang
1
Qian Wang
1
Yaqian Kong
1
Jing Quan
1
Yuxin Zhang
1
Yongjian Zhang
1

  1. Shaanxi University of Science and Technology, China
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Abstract

The waste production is closely related with human activity. Various approaches have been applied to manage and reduce its increasing volume (Paranjpe et al. 2023). One of the possibilities that comply with the assumptions of circular economy is utilization of wastes in anaerobic digestion (AD) process. This technology is common worldwide and it is recognized as the cost-effective methods of energy generation that also allow for nutrient recovery, as well as effective waste management (Alharbi et al. 2023). The biogas generated within this process is considered as a multifunctional renewable source that might be a promising alternative to the depleting traditional fuels. It finds various applications such as heat and power generation, fuel in automobiles, and substrate in chemical industry (Shitophyta et al. 2022, Pradeshwaran 2024). Typically, biogas contains 50–70% of CH4, 30–50% of CO2, and 1–10% of other trace gases like H2, H2S, CO, N2. Its composition mainly depends on the feedstock characteristics, operational conditions, and adopted technology (Gani et al. 2023, Archana et al. 2024). Considering further application, the priority action should be increasing its volume and methane content. There are several strategies to achieve these goals, including implementing codigestion strategy, adding additional component to the main substrate, introducing trace elements essential in AD, pretreatment strategies, and introducing enzymes and microbial strains to digesters (Zhang et al. 2019). Each method has limits related to the implementation costs, changes in the adopted technology, operator training needs, and additional energy input, which might negatively influence the energy balance of wastewater treatment plants (WWTPs) (Meng et al. 2022). Therefore, recent scientific attention has focused on combining various strategies to achieve intended goals. Moreover, such combinations might allow for an effective utilization of various wastes, the earlier use of which in AD was difficult. Orange waste could be an example of such a substrate. The previous studies indicated that its application in AD resulted in poor process efficiency, mainly due to the presence of limonene, recognized as the main inhibitor of biological activity (Calabro et al. 2020, Bouaita et al. 2022). In this study, the novel concept of implementing solidified carbon dioxide (SCO2) in the anaerobic co-digestion of municipal sewage sludge (SS) and orange peel waste (OPW) has been proposed. This approach may help overcome the disadvantages of the two-component AD of these wastes. Importantly, such studies have not been conducted thus far. However, the recent studies indicated that application of SCO2 to aerobic granular sludge improved biogas and methane yields and also enhanced the kinetics of biogas production (Kazimierowicz et al. 2023 a,b). Importantly, SCO2 might be generated in biogas upgrading technologies (Yousef 2019). Such solution is consistent with the principles of the circular economy and contributes to reducing the carbon footprint of WWTPs.
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Authors and Affiliations

Aleksandra Szaja
1
ORCID: ORCID
Izabela Bartkowska
2

  1. Lublin University of Technology, Faculty of Environmental Engineering, Lublin, Poland
  2. Bialystok University of Technology, Department of Water Supply and Sewage Systems,Faculty of Civil Engineering and Environmental Sciences, Poland
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Abstract

Due to the widespread presence and harmfulness of heavy metals in the environment, scholars around the world have evaluated the exposure characteristics and health risks of heavy metals. To understand the status, hotspots, and development treads of heavy metal health risk assessment research, we used bibliometric analysis tools to conduct scientometric analysis of the literature related to the health risk assessment of heavy metals in the Web of Science database from 2000 to 2022. The analysis results indicate that research related to heavy metal health risk assessment is rapidly developing in both developed and developing countries. China’s significant international influence in this field is worth noting, as there are many publications and highly cited documents related to China. France and other developed countries also play an important role in this field due to their high centrality and strong bursts. The results of co-citation cluster analysis and keyword co-occurrence analysis indicate that in the past two decades, the primary research domains and hotspots of heavy metal health risk assessment have been the study of heavy metals in soil, dust, drinking water, vegetables, fish, and sediment. There is a specific focus on bioaccumulation, bioavailability, source apportionment, and spatial distribution of heavy metals. The main types of heavy metals studied are lead, cadmium, mercury, and zinc. The results of the bursts keywords analysis suggest that future research trends may focus more on the health risks of heavy metals in different functional areas of cities.
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Authors and Affiliations

Yingsen Zhang
1
Xinwei Lu
1
Sijia Deng
1
Tong Zhu
1
Bo Yu
1

  1. School of Geography and Tourism, Shaanxi Normal University, China
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Abstract

The aim of the work was to develop a mathematical model using equations of fluid mechanics that describe the dynamics of air flow in a part of the compost aerating system integrated with a stationary reactor. The results of the simulation show that adjusting the flow resistance along the entire length of the compost aerating duct, depending on the distance from the connection of the duct with the fan's pressure conduit pipe through gradually increasing the air outflow area by increasing the number of repeatable gaps, yields a uniform pressure distribution above the grate. The process parameters used for computation were relevant to composting a subscreen fraction separated from mixed municipal waste using 80 mm mesh screen (Fr<80 mm) under real conditions. Microsoft EXCEL 2010 software and STATISTICA version 13.3 by StatSoft were used for numerical and statistical analysis of the test results. The research results are presented in four tables and five figures and discussed in the text of the article. During tests performed in real conditions, various variants were tested for reactor filling level and air outflow active surfaces in subsequent grate parts (Fc (i)). It was found that the target waste layer thickness i.e. 3.0 m and Fc (i) changes, in accordance with the values of the developed model, result in a stable pressure distribution pd, amounting to 1506 Pa and 1495 Pa at the grate front and end part.
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Authors and Affiliations

Robert Sidełko
1
Dariusz Boruszko
2
ORCID: ORCID

  1. Koszalin University of Technology, Poland
  2. Bialystok University of Technology, Poland
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Abstract

The amount of solid organic waste is constantly growing. This is caused by the growth of industrial and agricultural capacities, and the inefficiency of existing waste processing technologies. Biotechnologies can provide effective environmentally friendly solutions for waste treatment. Therefore, the goal of our work was to compare the efficiency of strictly anaerobic fermentation of multi-component solid organic waste with hydrogen synthesis and waste treatment with pulsed air access in batch bioreactors.During fermentation, the following parameters were controlled: pH, redox potential (Eh), concentration of dissolved organics, and the content of H2, O2, and CO2 in the gas phase. The efficiency was evaluated via the process duration, calculation of the ratio of the initial and final weight of waste (Кd), and the yield of molecular hydrogen. Obtained results revealed high efficiency of organic waste degradation in both variants. The weight of waste 83-fold and 86-fold decreased, respectively. The time required for fermentation in strictly anaerobic conditions was 4 days, whereas 7 days were required for the mode with pulsed air access. The first variant provided a 2.8-fold higher hydrogen yield (54±4,1 L/kg of waste), and the second one provided a decrease in the concentration of dissolved organic compounds in the fermentation fluid. Fermentation is the effective approach for accelerated degradation of solid organic waste. Strictly anaerobic fermentation appeared to be useful in the need to accelerate the process. The mode with the pulsed air access can provide not only degradation of solid waste but also purification of the fermentation fluid.
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Authors and Affiliations

Vira Hovorukha
1 2
ORCID: ORCID

  1. Institute of Environmental Engineering and Biotechnology, University of Opole, Poland
  2. Department of Extremophilic Microorganisms Biology, D.K. Zabolotny Institute of Microbiologyand Virology of the National Academy of Sciences of Ukraine, Kyiv, Ukraine
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Abstract

The main aim of the study was to assess the feasibility of using biopolymers of different viscosities (high, medium and low viscosity) as immobilization carriers for laccase in synthetic dye removal. The following dye solutions were decolorized: indigo carmine (IC, anionic dye), methylene blue (MB, cationic dye), and their mixture in a molar mass ratio MB/IC=0.69, using biopolymers of different viscosities as laccase immobilization carriers. Toxicity tests were also carried out to assess the toxicity of the post-decolorization samples. Decolorization tests showed that the main decolorization mechanism depends on the dye class. The removal of IC (max. total removal efficiency 72.15%) was mainly by biocatalysis. The mechanism of the MB decolorization process was mainly by sorption on alginate beads, and the efficiency of enzymatic removal was low. However, the highest efficiency of MB decolorization (45.80%) was obtained for beads prepared using the high viscosity alginate when decolorization occurred by both sorption and biocatalysis. The results of mixture decolorization tests differ from the results obtained for single dyes.The results showed differences in the efficiency of the dye sorption process depending on the alginate used for immobilization. Moreover, the varying mechanisms of dye removal from the dye mixture were confirmed by toxicity tests. The occurrence of both biocatalysis and sorption promotes reduced toxicity
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Authors and Affiliations

Małgorzata Białowąs
ORCID: ORCID
Beata Kończak
1
Stanisław Chałupnik
1
Joanna Kalka
2

  1. Central Mining Institute – National Research Institute, Poland
  2. Environmental Biotechnology Department, Faculty of Energy and Environmental Engineering,The Silesian University of Technology, Poland
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Abstract

The present work focuses on examining the batch removal of Fe (III) from water using powdered Peganum Harmala seeds, characterized as FT-IR. In this work, several parameters are measured, including contact time, pH, Fe (III) concentration, reaction temperature effect, and adsorbent dose effect. Fe (III) adsorption was assessed using a UV-vis spectrophotometer at a wavelength of 620 nm. The findings demonstrated a positive correlation between the dosage of adsorbent and Fe (III) ions removal, with an increase in the adsorbent dose corresponding to higher elimination of Fe (III) ions. Therefore, the Langmuir isotherm model yielded more accurate equilibrium data compared to the Frendulich model. The kinetic data were mostly analyzed using a pseudo-second-order model rather than a pseudo-first-order model. Thermodynamic parameters, including enthalpy (ΔH◦), entropy (ΔS◦), and free energy (ΔG◦), were calculated. The adsorption process was found to be exothermic. Overall, Peganum Harmala was a favorable adsorbent for removing Fe (III) from aqueous solutions.
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Authors and Affiliations

Raiedhah Alsaiari
1
Iman Shedaiwa
1
Fatima A. Al-Qadri
1
Esraa M. Musa
1 2
Huda Alqahtani
3
Faeza Alkorbi
1
Norah A. Alsaiari
1
Mervate M. Mohamed
1 4

  1. Empty Quarter Research Unit, Department of Chemistry, College of Science and Art in Sharurah, Najran University, Saudi Arabia
  2. Veterinary Research Institute (VRI), P. O BOX 8067, AL Amarat, Khartoum, Sudan
  3. Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia
  4. Chemistry Department, Faculty of Science, Suez Canal University, Ismailia, Egypt
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Abstract

There are approximately 15 million users of system heat in Poland, but unfortunately nearly 70% of the fuel used in heat production is fossil fuel. Therefore, the CO2 emission reduction in the heat production industry is becoming one of the key challenges. City Heat Distribution Enterprise Ltd. in Nowy Sącz (Miejskie Przedsiębiorstwo Energetyki Cieplnej sp. z o.o.) has been conducting a self-financed research and development project entitled The use of algae as carbon dioxide absorbers at MPEC Nowy Sącz. The project deals with postcombustion CO2 capture using Chlorella vulgaris algae. As a result of tests conducted in a 1000 l hermetic container under optimal temperature and light conditions, the recovery of biomass can be performed in weekly cycles, yielding approximately 25 kilograms of biomass per year. Assuming that half of the dry mass of the algae is carbon, it can be said that 240 grams of carbon is bound in one cycle, which, converted to CO2, gives 880 grams of this gas. Our results showed that around 45.8 kilograms of CO2 per year was absorbed. Additionally, it is possible to use waste materials and by-products of technological processes as a nutrient medium for algae
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Authors and Affiliations

Paweł Kupczak
1
ORCID: ORCID
Sylwester Kulig
1
ORCID: ORCID

  1. Miejskie Przedsiębiorstwo Energetyki Cieplnej sp. z o.o. w Nowym Sączu, Poland
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Abstract

The measurements of the concentrations of gaseous and dust pollutants in the anthropogenic environment are an important element of environmental monitoring and for determining directions of preventive activities in the field of health protection. The article presents the results involving the concentrations of suspended dust and gaseous pollutants in the outdoor air, which were recorded at three measuring stations of air quality in the Silesian and Opole voivodeships (Wodzisław Śląski, Zabrze, Kędzierzyn-Koźle). The results were supplemented with the values recorded by the mobile laboratory located at the Center for Continuing Education - Branch of the Silesian University of Technology in Rybnik. The research results were used for a synthetic assessment of the threat level to the anthropogenic environment. In the computational layer, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) was employed, which is included in the group of methods for solving multi-criteria decision-making problems (Multi Attribute Decision Making).
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Authors and Affiliations

Elwira Zajusz-Zubek
1
ORCID: ORCID
Zygmunt Korban
2

  1. Silesian University of Technology, Faculty of Energy and Environmental Engineering, Poland
  2. Silesian University of Technology, Faculty of Mining, Safety Engineering and Industrial Automation, Poland
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Abstract

Plastic pollution in the hydrosphere ranks among the most pervasive environmental issues since the inception of the plastic industry and its widespread use in our daily lives. Nowadays, numerous countries worldwide suffer from this pollution not only along coastlines but also in deep-sea ecosystems. Our study carried out in the Gulf of Annaba aims to assess the prevalence and spatial distribution of plastic waste. Sampling was conducted at four coastal sites: El Battah, Seybousse, Rizzi Amor, and Ain Achir, both before and after the Covid-19 pandemic. The results reveal varying rates of macro and microplastic contamination, influenced by geographical differences, urban activities, and hydrodynamic factors. Moreover, the proportions of contamination depend on the types of waste. Furthermore, our study showed a clear divergence, particularly in two periods before and after the pandemic. Due to the lockdown, implemented in 2020, there was a marked decrease in the percentage of sediment plastic pollution, attributed to reduced human activity and partial cessation of industrial operations in these areas.
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Authors and Affiliations

Ouali Kheireddine
1
ORCID: ORCID
Lakbar Chanez
1
Djennane Rania
1
Trea Fouzia
1
ORCID: ORCID
Samar Faouzi
2

  1. Laboratory of Environmental Biosurveillance, Badji Mokhtar University, BP 12 Sidi Amar, Annaba 23000, Algeria
  2. University Chadli Bendjedid, El Tarf 36000, Algeria
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Abstract

The necessity of rational water resource management and reduction of water consumption demandsthat water utilities address water losses during water treatment. Therefore, the backwash water generated during the filtration process is often the focus of research aimed at its reuse within the water treatment system. The studies outlined here were conducted in a large water treatment plant (100,000 m3), focusing on the backwash water produced from sand bed filter flushing. Prior to its reintroduction into the treatment train, the backwash water underwent pre-treatment using ultrafiltration (UF) process with two different modules: a spiral module with a PVFD (200kDa) membrane and a capillary module with a PES (80kDa) membrane. The effectiveness of the process was evaluated based on the degree of retention of organic substances and microorganisms, which pose health risks in backwash water recirculation. The capillary membrane exhibited greater effectiveness in retaining these contaminants, thereby ensuring the complete elimination of pathogenic microorganisms. The study findings indicate that pre-treating backwash water using UF membranes and reintroducing it into the water treatment system before the ozonation process can lead to a reduction of environmental fees. However, this process results in a 1.5% increase in water treatment costs
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Authors and Affiliations

Małgorzata Wolska
1
ORCID: ORCID
Małgorzata Kabsch-Korbutowicz
1
ORCID: ORCID
Małgorzata Solipiwko-Pieścik
1
ORCID: ORCID
Halina Urbanska-Kozłowska
2
ORCID: ORCID
Zbigniew Ferenc
1
ORCID: ORCID

  1. Wroclaw University of Science and Technology, Poland
  2. MPWiK S.A we Wrocławiu, Poland
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Abstract

This article describes the population of Xizang, the composition of municipal solid waste, and the distribution of municipal solid waste treatment facilities. With the development of Xizang's economy and tourism, the amount of municipal solid waste cleared and transported in Xizang has increased from 380,000 tons in 2003 to 692,200 tons in 2021, with an average annual growth rate of 4.56%. The proportions of kitchen waste, paper waste, and ash waste in the municipal solid waste components in Xizang have significantly decreased over the past 10 years. For example, the proportion of ash decreased from 22.83% in 2012 to 13.04% in 2021. Overall, recyclables such as paper, plastic rubber, textiles, glass, metal and wood and bamboo accounted for between 55.69% and 58.22% of the total municipal solid waste in Lhasa City. The disposal of municipal solid waste in Xizang was mainly through landfill. There are more than 130 landfill sites, 1 incineration plant, 5 pyrolysis pilot sites, 2 kitchen waste treatment plants, and more than 160 waste transfer stations for municipal solid waste disposal in Xizang. The designed daily disposal capacity of municipal solid waste is 3,768.4 tons per day.
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Bibliography

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Authors and Affiliations

Wenwu Zhou
1
ORCID: ORCID
Zeng Dan
1

  1. School of Ecology and Environment ,Tibet University, Lhasa, China
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Abstract

This study represents the first culture-independent profiling of microbial diversity in post-processing wastewater from underground coal gasification (UCG) processes. Three types of post-processing wastewater, named W1, W2 and W3, were obtained from three UCG processes involving two types of coal and two gasification agents, namely oxygen-enriched air and oxygen. Very high concentrations of BTEX (benzene, toluene, ethylbenzene, xylene), polyaromatic hydrocarbons (PAHs), and phenol were detected in the wastewater, classifying it into the fifth toxicity class, indicating very high acute toxicity. The values for the Shannon (H), Ace and Chao1 indices in W2 were the lowest compared to their values in W1 and W3. The dominate phyla were Proteobacteria, contributing 84.64% and 77.92% in W1 and W3, respectively, while Firmicutes dominated in W2 with a contribution of 66.85%. At the class level, Gammaproteobacteria and Alphaproteobacteria were predominant in W1 and W3, while Bacilli and Actinobacteria were predominant in W2. Among Bacilli, the Paenibacillus and Bacillus genera were the most numerous. Our results suggest that the main differentiating factor of the bacterial structure and diversity in the wastewater could be the gasification agent. These findings provide new insights into the shifting patterns of dominant bacteria in post-processing wastewater and illustrate the spread of bacteria in industrial contaminated wastewater.
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Authors and Affiliations

Łukasz Jałowiecki
1
Jacek Borgulat
1
Aleksandra Strugała-Wilczek
2
Jan Jastrzębski
3
Marek Matejczyk
1
Grażyna Płaza
4

  1. Institute for Ecology of Industrial Areas,Katowice, Poland
  2. Department of Energy Saving and Air Protection, Central Mining Institute, Katowice, Poland
  3. Faculty of Biology and Biotechnology, University of Warmia and Mazury in Olsztyn, Poland
  4. Silesian University of Technology, Poland
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Abstract

The investigation of Nida Valley water aimed to assess fluctuations in physicochemical properties. In this study, environmental monitoring method was utilized to evaluate the changes in physicochemical properties of water. Over a 24-month period, from June 2021 to May 2023, a total of 228 water samples were collected from 10 sampling sites, with a monthly sampling frequency. Statistical analyses were utilized including the Shapiro–Wilk test (α = 0.05), Kruskal–Wallis test and Wilcoxon (Mann–Whitney) rank sum test (α = 0.05), Pearson correlation analysis (α = 0.001) and principal component analysis (PCA). Statistical analyses revealed significant differences between months in GW samples for for temperature, dissolved oxygen, pH, total nitrogen, total phosphorus, chloride, manganese, and zinc in GW samples and for T and DO in SW samples. Pearson correlation coefficient analysis (α = 0.001) identified strong positive correlations within the SW dataset. Similarly, significant positive correlations were observed among the GW dataset. Noteworthy positive correlations were also detected between the GW and SW datasets. Principal component analysis (PCA) revealed a substantial dissimilarity between GW2 samples compared to others, characterized by elevated manganese, iron, and Sulfate content. Two distinct groups emerged: Group 1 included samples at GW1, GW2, GW3, GW5, and SW2, while Group 2 comprised all other samples. This study demonstrated the stability in the physicochemical properties of SW and underscore a discernible correlation between the hydrochemical compositions of both SW and GW in the riparian area. Outstanding characteristics in hydrochemical component of sample waters have been indicated.
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Authors and Affiliations

Cong Ngoc Phan
1 2
ORCID: ORCID
Andrzej Strużyński
1
ORCID: ORCID
Tomasz Kowalik
1
ORCID: ORCID

  1. Faculty of Environmental Engineering and Land Surveying, University of Agriculture in Krakow, Poland
  2. Institute of Chemistry, Biology and Environment, Vinh University, Vietnam
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Abstract

Sapropel is a layer of sediment composed of organic and inorganic substances that accumulates at the bottom of lakes. The water of such lakes often have elevated levels of heavy metals such as Cd, Cr, Cu, and Zn, which can pose risks to human health. Sapropel may be used as a biosorbent in removing these heavy metals from aqueous solutions. Various doses of sapropel ranging from 1 to 50 g/L and different mixing times from15 to150 minutes have been tested. The maximum removal efficiencies for Cd (93%), Cr (31%), Cu (84%), and Zn (84%) from aqueous solutions were achieved using the minimum doses of sapropel (50 g/L). The study has shown that mixing sapropel for 15 minutes is sufficient for the removal of Cr, 30 minutes for Cd and Cu, and 60 minutes for Zn.
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Authors and Affiliations

Ramunė Albrektienė-Plačakė
1
Dainius Paliulis
2

  1. Department of Chemistry and Bioengineering, Vilnius TECH, Lithuania
  2. Department of Environmental Protection and Water Engineering, Vilnius TECH, Lithuania
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Abstract

This paper aims to explore the relationship between the Air Quality Index (AQI), COVID-19 incidence rates, and population density within Malaysia’s ten most populous cities from January 2018 to December 2021. Data were sourced from the Department of Statistics Malaysia, the World Air Quality Index Project, and Our World in Statistics. The methodology integrated population-based city classification and AQI assessment, cluster analysis through SPSS, and Generalized Additive Mixed Model (GAMM) analysis using R Studio despite encountering a data gap in AQI for five months in 2019. Cities were organized into three clusters based on their AQI: Cluster One included Ipoh, Penang, Kuala Lumpur, and Melaka, Cluster Two comprised Kuantan, Seremban, Johor Bahru, and Kota Bharu, Cluster Three featured Kota Kinabalu and Kuching. GAMM analysis revealed prediction accuracies for AQI variations of 58%, 60%, and 41% for the respective clusters, indicating a notable impact of population density on air quality. AQI variations remained unaffected by COVID-19, with a forecasted improvement in air quality across all clusters. The paper presents novel insights into the negligible impact of COVID-19 on AQI variations and underscores the predictive power of population dynamics on urban air quality, offering valuable perspectives for environmental and urban planning.
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Authors and Affiliations

Wong Ming Wong
1
ORCID: ORCID
Shian-Yang Tzeng
2
ORCID: ORCID
Hao-Fan Mo
3
ORCID: ORCID
Wunhong Su
4
ORCID: ORCID

  1. International College, Krirk University, Thailand
  2. School of Economics and Management, Quanzhou University of Information Engineering, China
  3. JinWen University of Science and Technology, Taiwan
  4. 4School of Accounting, Hangzhou Dianzi University, China
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Abstract

This study used PM10 and PM2.5 measurements from the State Environmental Monitoring stations in Warsaw and its suburban areas. Analysis of variability characteristics at the traffic and urban background stations was carried out for 2016-2021. A six-year analysis (2016-2021) of air quality in Warsaw, Poland, focusing highlights the persistent impact of transportation on particulate matter concentrations. Comparing a city centre traffic station with urban background locations reveals consistently higher PM10 concentrations at the traffic station throughout the year, with an annual traffic-related increase of 12.6 μg/m³ (32%). PM2.5 concentrations at the traffic station are also consistently about 1.5 μg/m³ (7%) higher. For monthly averages, the highest PM10 concentrations at the traffic station were noted in March, which may be related to the resuspention of sand and salt left over from winter snow removalp rocesses. In the case of PM2.5, the typical annual cycle with maximum concentrations in winter and minimum concentrations in summer was not observed. Diurnal variability patterns show elevated PM10 concentrations at the traffic station from 8:00 a.m. to 10:00 p.m., attributed to the resuspension process. PM2.5 patterns exhibit a smaller amplitude at the traffic station, with nighttime accumulation due to inflow. This study emphasizes the lasting impact of transportation on air quality, providing insights into pollution control strategies in urban areas.
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Authors and Affiliations

Aleksandra Starzomska
1
ORCID: ORCID
Joanna Strużewska
1

  1. Institute of Environmental Protection—National Research Institute, Poland
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Abstract

The cyanobacteria bloom is one of typical manifestations of eutrophication, yet the effects of heavy metals entering water on cyanobacteria bloom remain unclear. In the present study, the effects of copper and zinc ions on the growth of Microcystic aeruginosa (M. aeruginosa) and the production of microcystins (MCs) were investigated. The results showed that a Cu2+ concentration of 0.02 mg/L stimulated the growth of M. aeruginosa, while growth inhibition occurred at a Cu2+ concentration of 0.1 mg/L. The maximum value of MC-LR (167.74 μg/L) occurred at a Cu2+ concentration of 0.02 mg/L. In contrast, a Zn2+ concentration of 0.1 mg/L stimulated the growth of M. aeruginosa, whereas growth inhibition was observed at a Zn2+ concentration of 0.5 mg/L. The maximum MC-LR value of 130 μg/L appeared under control conditions. Moreover, the production of MC-LR increased as the growth of M. aeruginosa was inhibited with a Cu2+ concentration of 0.1 mg/L, whereas the production of MC-LR decreased as the growth of M. aeruginosa was stimulated with a Zn2+ concentration of 0.1 mg/L, compared to their respective controls.
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Authors and Affiliations

Benjun Zhou
1
Weihao Xing
1

  1. School of Resources and Environmental Engineering, Hefei University of Technology, China
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Abstract

The article analyzes soil organic carbon (SOC) content of in Poland from 2015 to 2021. The research aims to determine SOC levels and their dependence on soil agronomic categories and drought intensity. Soil samples from 1011 farms across 8 Polish voivodships were collected for analysis, all from the same agricultural plots. SOC determination was conducted using the Tiurin method. The results indicate a low SOC content nationwide (0.85-2.35%). Heavy soils exhibited higher SOC accumulation compared to light soils. Moreover, significant drought impact led to decreased SOC content in affected regions. Scientific evidence underscores a declining trend in organic carbon stock within agricultural soils, attributed to natural soil changes and unsustainable management practices. This decline is concerning given the crucial role of SOC in soil health, quality, and crop productivity. Therefore, it is imperative to monitor and address areas with low SOC levels to enhance SOC abundance. Furthermore, when used as a whole-cell biocatalyst in a low-cost upflow MFC, the Morganella morganii-rich SF11 consortium demonstrated the highest voltage and power density of 964.93±1.86 mV and 0.56±0.00 W/m3, respectively. These results suggest that the SF11 bacterial consortium has the potential for use in ceramic separator MFCs for the removal of penicillin and electricity generation.
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Authors and Affiliations

Urszula Zimnoch
1 2
Paulina Bogusz
1 3
Marzena Sylwia Brodowska
1
Jacek Michalak
4

  1. Department of Agricultural and Environmental Chemistry, University of Life Sciences in Lublin, Poland
  2. Complexor Fertilizer Group, Stawiski, Poland
  3. Fertilizers Research Group, Łukasiewicz Research Network–New Chemical Syntheses Institute, Puławy, Poland
  4. Regional Chemical and Agricultural Station in Łódź, Poland
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Abstract

The starting point of the study on the problems, dilemmas and hopes for effective implementation of revitalization projects in Polish cities was the conviction that revitalization is one of the processes affecting the development and changes in the spatial and functional fabric of cities. Revitalization is defined as a deliberate and purposeful process, the effect of which is to restore life in the dysfunctional and degraded parts of cities. Taking up such a topic required an answer to the question about the nature of revitalization and its aspects. The focus of the study was on the problems of revitalization that stem from the legal and socio-economic situation and the dilemmas faced by local government authorities of Polish cities. The introduction to these considerations is the brief outline of the revitalization of Polish cities in the period after World War II, while the conclusion deals with the fears and hopes related to revitalization activities that are presently initiated. The discussion takes into account the existing, critically assessed, legal regulations on revitalization.

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Authors and Affiliations

Jerzy J. Parysek
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Abstract

The category of small towns is progressively polarized under the impact of metropolitan development. There is a growing diversification of such places with regard to functions performed and the overall position in settlement systems at regional and national levels. Aside from the division line which separates these towns that are located within, from those situated beyond the commuting range of large urban centres, this is increasingly related to local, territorial capital held. In general, however, the flattening of urban hierarchy and the decreasing importance of hierarchical linkages affect in particular the role of local service centres, especially in sparsely settled peripheral areas. Concerning the future, three alternative development paths are discussed in the article against the relevant conceptual background. These refer to the cyclical nature of urbanization processes, assume an extrapolation of trends observed or, alternatively, consider a containment of metropolization phenomena. With respect to policy related questions, changes in small town networks in peri-urban zones are identified as a specific, sensitive issue.

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Authors and Affiliations

Piotr Korcelli
Ewa Korcelli-Olejniczak
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Abstract

The article aims to explain whether in 2004–2015 Poland experienced economic convergence between regions and counties (Polish: powiat), and whether this process occurred within the regions (Polish: województwo). Following Poland’s EU accession, the Polish policy became dominated by the polarization and diffusion concept of regional development, which may cause differences in the short term, while in the long run it may contribute not only to the increased efficiency of public funds allocation, but also to the elimination of disparities in growth levels. In the analysed period Poland experienced a process of economic divergence between the regions, only the years 2006–2008 saw a short-term reduction in regional disparities. On the other hand, a slow process of reducing economic inequalities between counties took place after 2004. It was, however, varied – a clear reduction in disparities occurred between the land counties (Polish: powiat ziemski) in an almost monotonic manner, whereas city counties (Polish: miasto na prawach powiatu) did not undergo any convergence. Within the regions, the process of economic convergence varied: in five regions, β-convergence was identified, and σ-convergence occurred in all the regions. The process of reducing disparities was significantly dependent on the development pathway of the region.

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Authors and Affiliations

Wanda M. Gaczek
Wojciech Kisiała
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Abstract

The paper presents the indicator method as an important tool of research in social sciences with the focus on socio-economic geography. It introduces the notion of indicator in the methodological meaning and concentrates on its basic type, i.e. the inferential indicator. The concept of an indicator is explained using a realistic approach, which assumes that unobservable conceptual properties can be represented by observable real properties. In this approach, an indicator is characterised as an observable variable assumed to point to, or estimate, some other unobservable variable. The indicator method is then a way of the realistic conceptualization and a cognitive operation as well. The paper contains the systematization of cognitive indicators in socio-economic geography. It also shows the examples of the construction and interpretation of applied indicators.

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Authors and Affiliations

Teresa Czyż

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