The paper analyzes a new concept of integration of combined cycle with the installation of supplementary firing. The whole system was enclosed by thermodynamic analysis, which consists of a gas-steam unit with triple-pressure heat recovery steam generator. The system uses a determined model of the gas turbine and the assumptions relating to the construction features of steam-water part were made. The proposed conception involves building of supplementary firing installation only on part of the exhaust stream leaving the gas turbine. In the proposed solution superheater was divided into two sections, one of which was located on the exhaust gases leaving the installation of supplementary firing. The paper presents the results of the analyses of which the main aim was to demonstrate the superiority of the new thermodynamic concept of the supplementary firing over the classical one. For this purpose a model of a system was built, in which it was possible to carry out simulations of the gradual transition from a classically understood supplementary firing to the supplementary firing completely modified. For building of a model the GateCycle™ software was used.
Among the technologies which allow to reduce greenhouse gas emission, mainly carbon dioxide, special attention deserves the idea of 'zero-emission' technology based on boilers working in oxy-combustion technology. In the paper the results of analyses of the influence of changing two quantities, namely oxygen share in oxidant produced in the air separation unit, and oxygen share in oxidant supplied to the furnace chamber on the selected characteristics of a steam boiler including the degree of exhaust gas recirculation, boiler efficiency and adiabatic flame temperature, was examined. Due to the possibility of the integration of boiler model with carbon dioxide capture, separation and storage installation, the subject of the analysis was also to determine composition of the flue gas at the outlet of a moisture condensation installation. Required calculations were made using a model of a supercritical circulating fluidized bed boiler working in oxy-combustion technology, which was built in a commercial software and in-house codes.
Low manganese and sulfur gray irons were produced by adding inoculant base Fe-Si with small amounts of Al and Ca in the ladle. The effect of the cast thickness, inoculant amount and shakeout time of the green sand molds were studied on the graphite flake formation by microscopically techniques. A thermodynamic analysis was carried out for the cast iron produced with the FactSage 7.2 software. Stability phase diagrams were obtained for both gray cast irons to different manganese (0.1 to 0.9 wt.%) and sulfur (0.01 to 0.12 wt.%) amounts to 1150°C. It was shown that lower amounts of manganese and sulfur allow forming the 3Al2O3·2SiO2, Al2O3, and ZrO2 solid compounds. The thermodynamic results match with those obtained by SEM-EDS. It is possible to form MnS particles in the liquid phase when the solubility product (%Mn) × (%S) equals 0.042 and 0.039 for heats A and B, respectively.
Because the heat release of plutonium material, the composite structure is heated and the stress and strain of the composite structure will increase, which will affect the thermodynamic properties of the structure. The thermodynamic analysis of complex structures, which are composed of concentric structures of plutonium, beryllium, tungsten, explosives, and steel, was carried out. The results showed that when the structure is spherical, the temperature is higher than that of the ellipsoid structure. Stress of the elliptical structure is greater than the spherical structure. This study showed that the more flat the shell is, the greater the stress concentration point occurs at the long axis, and the maximum stress occurs at the beryllium layer. These conclusions provide theoretical support for the plutonium composite component testing.
The objective of the paper is to analyse thermodynamical and operational parameters of the supercritical power plant with reference conditions as well as following the introduction of the hybrid system incorporating ORC. In ORC the upper heat source is a stream of hot water from the system of heat recovery having temperature of 90 °C, which is additionally aided by heat from the bleeds of the steam turbine. Thermodynamical analysis of the supercritical plant with and without incorporation of ORC was accomplished using computational flow mechanics numerical codes. Investigated were six working fluids such as propane, isobutane, pentane, ethanol, R236ea and R245fa. In the course of calculations determined were primarily the increase of the unit power and efficiency for the reference case and that with the ORC.
One of the problems in Russia Power Sector strategy until 2035 is the technologies development for mitigation of harmful emissions by the heat and power production industry. This goal may be reached by the transition to environmentally friendly generation units such as oxy-fuel combustion power cycles that burn organic fuels in pure oxygen. This paper provides the results of research on one of the most efficient oxy-fuel combustion power cycle, which was modified by the usage of nitrogen for turbine cooling. The computer simulation and parametric optimization approaches are described in detail. The net efficiency of the oxy-fuel combustion power cycle in relationship to the carbon dioxide turbine exhaust pressure is shown. Moreover, the influence of the regenerator scheme and modeling parameters on heat performance is obtained. Particularly, it was found that the transition to a scheme with five two-threaded heat exchangers decrease cycle efficiency by 4.2% compare to a scheme with a multi-stream regenerator.
This paper presents the results of thermodynamic analysis of the crude distillation units of two refineries in Nigeria. The analysis was intended to assess the thermodynamic efficiencies of the refineries and proffer methods of improving the efficiencies. Presented results show the atmospheric distillation units of the refineries have 33.3% and 31.6% exergetic efficiencies and 86.5% and 74.6% energetic efficiencies, respectively. Modifications of the operating and feed conditions of the refineries resulted in increased exergetic efficiencies for as much as 62.3% and 38.7% for the refineries. Thermodynamic analysis of the refineries can bring about efficiency improvement and effectiveness of the refineries.
Most satellites stationed in space use catalytic propulsion systems for attitude control and orbit adjustment. Hydrazine is consumed extensively as liquid monopropellant, in the thrusters. Catalytic reactor is the most important section in the catalytic thruster. Ammonia and nitrogen gases are produced as a result of complete catalytic decomposition of hydrazine in the reactor, causing an increase in temperature and a rise in specific impulse. Ammonia is subsequently decomposed, leading to nitrogen and hydrogen gases. Decomposition of ammonia leads to a decrease in temperature, molecular weight and specific impulse. The latter phenomenon is unavoidable. The effect of ammonia decomposition on the reactor temperature, molecular weight of gaseous products and conclusively on specific impulse was studied in this article. At adiabatic state, thermodynamic analysis revealed that the maximum and minimum temperatures were 1655 K and 773 K, respectively. The highest molecular weight was obtained at ammonia conversion of zero and the lowest when ammonia conversion was 100%. The maximum specific impulse (305.4 S) was obtained at ammonia conversion of zero and completely conversion of ammonia, the minimum specific impulse (about 213.7 s) was obtained. For specific impulse, the result of thermodynamic calculation in this work was validated by the empirical results.
In this paper, thermodynamic analysis of a proposed innovative double Brayton cycle with the use of oxy combustion and capture of CO2, is presented. For that purpose, the computation flow mechanics (CFM) approach has been developed. The double Brayton cycle (DBC) consists of primary Brayton and secondary inverse Brayton cycle. Inversion means that the role of the compressor and the gas turbine is changed and firstly we have expansion before compression. Additionally, the workingfluid in the DBC with the use of oxy combustion and CO2 capture contains a great amount of H2O and CO2, and the condensation process of steam (H2O) overlaps in negative pressure conditions. The analysis has been done for variants values of the compression ratio, which determines the lowest pressure in the double Brayton cycle.
In the paper the results of analysis of an integrated gasification combined cycle IGCC polygeneration system, of which the task is to produce both electricity and synthesis gas, are shown. Assuming the structure of the system and the power rating of a combined cycle, the consumption of the synthesis gas for chemical production makes it necessary to supplement the lack of synthesis gas used for electricity production with the natural gas. As a result a change of the composition of the fuel gas supplied to the gas turbine occurs. In the paper the influence of the change of gas composition on the gas turbine characteristics is shown. In the calculations of the gas turbine the own computational algorithm was used. During the study the influence of the change of composition of gaseous fuel on the characteristic quantities was examined. The calculations were realized for different cases of cooling of the gas turbine expander’s blades (constant cooling air mass flow, constant cooling air index, constant temperature of blade material). Subsequently, the influence of the degree of integration of the gas turbine with the air separation unit on the main characteristics was analyzed.