The authors established the chemical and phase compositions of grain fractions of the magnesia carbon scrap disintegrated using industrial cone crushers. The investigations included chemical and XRD analyses and optical investigations. The contents of admixtures: SiO2, CaO, Fe2O3 and Al2O3 increase with the decreasing size of the scrap grain fractions, whereas the C/S ratio decreases in finer and finer fractions due to changes of the phase composition. These relations are caused by the presence of low-fusible silicate phases, characterized by their cleavage and brittleness. Such phases were mainly derived from the graphite ash containing a high silica content. The scrap after removing its finest grain fractions can be recycled and utilized for producing the magnesia-carbon refractory materials. However, the finest grain fractions may be used, e.g. as a component of gunite mixes. Many years of experience collected by the ArcelorMittal Refractories Ltd., Krakow, Poland in the field of refractory scrap utilization has also been presented.
The Polish basis of dolomites is remarkable. Their total reserves reported in the 62 deposits listed in current data bases of mineral resources amount to 1,500,000 t. However, there is a shortage of the so-called converter dolomites of high quality applicable in manufacturing of refractory materials. Such dolomites of the Triassic age have been quarried for many years in the Brudzowice and Ząbkowice Śląskie I deposits in the Silesian-Cracow region. The Libiąż deposit is perspective of this area, considering the character and properties of its dolomites. The dolomites of the Nowa Wioska and Stare Gliny deposits belong into the same group although their applying as refractories seems to be disputable at the moment and would require more detailed analyses of the chemical composition and firing properties of the rocks mentioned. The reason is that the dolomites of these deposits have been reported andmassively quarried up to now mainly for civil engineering (roads, buildings, etc.). Unfortunately, worsening properties of the dolomites occurring in Żelatowa, still another large and developed deposit of the region, have been excluded using these rocks in producing of refractories. Among the group of reserve converter dolomite deposits, the best rock properties have been found in four of them, i.e., Chruszczobród, Chruszczobród I, Chruszczobród II and Libiąż Wielki. The survey presented indicates that there are some possibilities of including dolomites of the Winna and, to a lesser degree, Radkowice-Podwole deposits as the raw materials in manufacturing of refractories. Again, more detailed analyses of the chemical composition and petrographical development, mainly of the grain size distribution, would be required. Dolomitic marbles of the Lower Silesia region represent a separate problem. Traditionally, they have been considered to be non-applicable in manufacturing of refractories because of too coarse grain size of these rocks. It should be stressed, however, that the Lower Silesian marbles occur in several varieties and among them also fineand coarse-grained dolomites occur. Their finest and chemically purest varieties can be an interesting option in extending the basis of refractory dolomitic raw materials in Poland, although selective quarrying would be required in such a case.
Chromium ore is treated as an important strategic raw material. It is used by many branches of the industry. The most important applications are metallurgical, refractory and chemical. Unfortunately, no chromium ore deposits have been found in Poland until now, with the exception of two chromium ore sites described in the Lower Silesia region. These concentrations are formed by chromitite, which is rock consisting mainly of chromian spinel. They are localized within so called Sudetic Ophiolite rocks along the edge of the Góry Sowie Massif. They form typical podiform deposits, which are characterized by the high Al content of the rock. The first locality, near Tąpadła village (the Gogołów-Jordanów Massif), is better known. The ore was exploited here at the turn of the19th century and at the beginning of the 20th century. According to the literature, 3500 tons of the ore was obtained - all the resources at this location. The second locality, situated at the Braszowice-Brzeźnica Massif, was never studied and described properly, falling into obscurity since the 19th century. During the field work at the Braszowice-Brzeźnica Massif, the author has found numerous chromium ore fragments among the debris. The rising prices of chromium on the world's markets suggest that it is reasonable to study the ore quality and overall resource potential of this deposit. The preliminary studies have shown that chromitities from Braszowice are typical ores of the podiform variety, the majority texturally massive and nodular. The chemical analyses of the primary chromianspinels grains revealed that they could be treated as refractory chromite (38% wt. of Cr2O3, lower than 30% wt. of Al2O3, and Cr/Fe ratio about 3:1). However, the metamorphic processes modified the primary chemical composition of the studied ore. They caused enrichment in Fe and Cr, and a decrease in Al in comparison to the primary ore. Moreover, the whole rock chemical analyses revealed that the content of the main elements is insufficient to use the ore without enrichment processes. Furthermore, the size and number of the potential ore bodies are presumably small. Consequently, both the chemical composition and the resources of the chromium ores from the Braszowice–Brzeźnica Massif are insufficient to allow for profitable exploitation, despite the high price of chromium.
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