There are presents the internal recycling in anode furnace, in addition to mainly blister copper and converter copper. During the process

there arise the two types of semi-finished products intended for further pyro metallurgical processing: anode copper and anode slag. The

stream of liquid blister copper enters into the anode furnace treatment, in which the losses are recovered, e.g. copper, resulting from

oxidation and reduction of sulfides, oxides and the oxidation of metallic compounds of lead, zinc and iron. In the liquid phase there are

still gaseous states, which gives the inverse relationship relating to the solid phase, wherein the gases found an outlet in waste gas or

steam. The results of chemical analysis apparently differ from each other, because crystallite placement, the matrix structure and the

presence of other phases and earth elements are not compared, which can be regained in the process of electrorefining. One should not

interpret negatively smaller proportion of copper in the alloy, since during the later part of the production more elements can be obtained,

for example from sludge, such as platinum group metals and lanthanides. According to the research the quality of blister copper, to a large

extent, present in the alloy phase to many other elements, which can be recovered.

Rare earth metals including yttrium and europium are one of several critical raw materials, the use of which ensures the development of the so-called high technology. The possibility of their recovery in Europe is limited practically only to secondary materials such as phosphogypsum and electronic waste.

The article presents the results of our research concerning the development of recovery technology of yttrium and europium from luminophore CRT used lamps. It describes the principle of separation of elements and the test results of cleaning the concentrate. It was shown that the costs of preparing the concentrate according to the proposed technology are lower than the phosphogypsum processing technology and the composition of the resulting product does not contain hazardous substances.

In the present work, amine based extractant and its mixture with cationic and solvating extractants were tested for the extraction of HCl from chloride solution containing Al(III). The chloride feed solution resulted from the leaching of spent HDS (hydro-desulfurization) catalysts. For this purpose, amine extractants, such as TOA (trioctyl amine), Alamine 336 (a mixture of tri-octyl/decyl amine), Alamine 308 (tri-isooctyl amine), and TEHA (tri 2-ethylhexyl amine) were used and the extraction and stripping behavior of HCl was compared. The extracted HCl was easily stripped from loaded TEHA phase, when compared with the other tested tertiary amine system. Solvent extraction reaction of HCl by TEHA was determined from the extraction data. Unlike TOA and Alamine 336, adding cationic extractant to TEHA had negligible effect on the extraction and stripping of HCl. In our experimental ranges, no Al was extracted by amines and pure HCl was recovered. MaCabe- Thiele diagrams for the extraction and stripping of HCl by TEHA were constructed.

This paper presents studies carried out in a pilot-scale plant for recovery of waste heat from a flue gas which has been built in a lignite-fired power plant. The purpose of the studies was to check the operation of the heat recovery system in a pilot scale, while the purpose of the plant was recovery of waste heat from the flue gas in the form of hot water with a temperature of approx. 90 °C. The main part of the test rig was a condensing heat exchanger designed and built on the basis of laboratory tests conducted by the authors of this paper. Tests conducted on the pilot-scale plant concerned the thermal and flow parameters of the condensing heat exchanger as well as the impact of the volumetric flow rate of the flue gas and the cooling water on the heat flux recovered. Results show that the system with a condensing heat exchanger for recovery of low-temperature waste heat from the flue gas enables the recovery of much higher heat flux as compared with conventional systems without a condensing heat exchanger.

The application of enhanced oil recovery processes (EOR – Enhanced Oil Recovery) on oil fields increases recovery efficiency. This is especially important in depleted and mature fields. This should result in an increase in production by raising the recovery factor (the ratio of oil produced to total geological reserves). This review presents the growing trend of gas injection (particularly carbon dioxide). In Polish oil fields, conventional methods are currently used. This means that much can still be done in this area. The selection of the optimum method for a given field is a complex procedure consisting of many stages, from collecting data about the field, through more advanced data interpretation, to working out a detailed proposal for the most efficient method of extraction. The pre-selection stage involves excluding methods which, owing to their specific mechanisms, cannot be used for a particular field – e.g. thermal methods in light oil fields or nitrogen injection into shallow reservoirs. This paper analyzes the potential for the application of EOR methods in Poland using a binary technical screening method. Forty-nine, mature Polish oil fields were analyzed. Apart from the rock type, other parameters were also taken into account in the analysis as follows: oil density and viscosity, average porosity, permeability and thickness of the reservoir, and also depth of deposit. In regard to the criteria for the EOR methods applied, the subjects of analysis are oil fields with medium density and viscosity and low permeability (double porosity in carbonate rocks), which are at a relatively shallow or medium depth of deposit. The results of analysis show that gas injection methods, especially carbon dioxide or nitrogen, have the highest potential. Application of this method must be preceded by detailed research and field pilot tests. International experience cannot be applied directly to Poland because of different field characteristics as well as technological and economic conditions.

The present work deals with ultrasound assisted crystallisation of lactose from lactose solution. The crystallisation of lactose was completed rapidly by applying the ultrasound waves in the presence of an anti-solvent (n-propanol), at the room temperature (30±3°C). The yield of lactose was found to be more than 85% (w/w) in 4 minutes of sonication. The spread of the crystal size distribution was found to decrease with increase in sonication time.

The scope of work included the launch of the process of refining slag suspension in a gas oven using a variety of technological additives.

After the refining process (in the context of copper recovery), an assessment of the effect of selected reagents at the level of the slag

refining suspension (in terms of copper recovery). Method sieve separated from the slag waste fraction of metallic, iron - silicate and

powdery waste. Comparison of these photographs macroscopic allowed us to evaluate the most advantageous method of separating

metallic fraction from the slag. After applying the sample A (with KF2 + NaCl) we note that in some parts of the slag are still large

amounts of metallic fraction. The fraction of slag in a large majority of the elements has the same size of 1 mm, and a larger portion of the

slag, the size of which is from 2 to 6 mm. Definitely the best way is to remove the copper by means of the component B (with NaCl ) and

D (with KF2

). However, as a result of removing the copper by means of component C (with CaO) were also obtained a relatively large

number of tiny droplets of copper, which was problematic during segregation. In both cases we were able to separate the two fractions in a

fast and simple manner.

Considering the advantages of hollow fiber supported liquid membrane (HFSLM), it has been applied for extraction of Co(II) with a motivation to extract cobalt from various waste resources. Extraction efficiency and transport behavior of Co(II) through HFSLM containing Cyanex 272 diluted in kerosene were investigated. Experiments were performed as a function of aqueous feed solution velocity (1000 mL/min) for both feed and strip, pH of feed solution in the range of 4.00-6.75, the carrier concentration of 25-1000 mol/m3, and acid concentration in strip solution of 1-500 mol/m3on. The mass transfer rate or flux JCo(II), which is a function of metal concentration, volume of solution, and membrane area were analyzed. The optimum condition for extraction of Co(II) was pH of 6.00, Cyanex 272 concentration of 500 mol/m3 and H2SO4 concentration of 100 mol/m3.

A simple robust cheap LQG control is considered for discrete-time systems with constant input delay. It is well known that the full loop transfer recovery (LTR) effect measured by error function ∆(z) can only be obtained for minimum-phase (MPH) systems without time-delay. Explicit analytical expressions for ∆(z) versus delay d are derived for both MPH and NMPH (nonminimum-phase) systems. Obviously, introducing delay deteriorates the LTR effect. In this context the ARMAX system as a simple example of noise-correlated system is examined. The robustness of LQG/LTR control is analyzed and compared with state prediction control whose robust stability is formulated via LMI. Also, the robustness with respect to uncertain time-delay is considered including the control systems which are unstable in open-loop. An analysis of LQG/LTR problem for noise-correlated systems, particularly for ARMAX system, is included and the case of proper systems is analyzed. Computer simulations of second-order systems with constant time-delay are given to illustrate the performance and recovery error for considered systems and controllers.

Copper slag is a by-product obtained during smelting and refining of copper. Copper smelting slag typically contains about 1 wt.% copper and 40 wt.% iron depending upon the initial ore quality and the furnace type. Main components of copper slag are iron oxide and silica. These exist in copper slag mainly in the form of fayalite (2FeO ·SiO2). This study was intended to recover pig iron from the copper smelting slag by reduction smelting method. At the reaction temperature of below 1400°С the whole copper smelting slag was not smelted, and some agglomerated, showing a mass in a sponge form. The recovery behavior of pig iron from copper smelting slag increases with increasing smelting temperature and duration. The recovery rate of pig iron varied greatly depending on the reaction temperature.

In the paper, the extended finite element method (XFEM) is combined with a recovery procedure in the analysis of the discontinuous Poisson problem. The model considers the weak as well as the strong discontinuity. Computationally efficient low-order finite elements provided good convergence are used. The combination of the XFEM with a recovery procedure allows for optimal convergence rates in the gradient i.e. as the same order as the primary solution. The discontinuity is modelled independently of the finite element mesh using a step-enrichment and level set approach. The results show improved gradient prediction locally for the interface element and globally for the entire domain.

The article discusses issues related to the generation, use, and transboundary movement of waste labeled with the code 191210 according to the waste catalogue regardless of its origin (municipal, industrial or mixed). Data contained in voivodship reports related to waste management and information about transboundary shipments shared by the Chief Inspectorate of Environmental Protection were also used in the article. The imbalance in the amount of produced and energetically used alternative fuels in Poland in the years 2015 to 2017 has been confirmed. This affects the economy of the waste management sector involved in the production of alternative fuels. The oversupply causes the prices of alternative fuels to fall and increases the need for subsidies in the case of the recovery or disposal of alternative fuels of lower quality. In the near future one should expect a stabilization of the supply of combustible waste to the cement industry, which is now beginning to achieve its technological potential; this is due to a high degree of replacement of fossil fuels. One should also expect an increase in the demand for alternative fuels from the commercial power sector and heating sector. It has been shown that much more alternative fuel is imported than exported from Poland. The amount of imported alternative fuel in the market is relatively low compared to the amount of fuel produced in the country. This oversupply affects, although not significantly, the possibility of using domestic waste for energy recovery. The export of the alternative fuel produced in the country is a favorable phenomenon when there is no possibility of sale on the domestic market. It seems rational, especially in the case of exports from installations producing fuels in border provinces.

The use of biomass in the energy industry is the consequence of ongoing efforts to replace Energy from fossil fuels with energy from renewable sources. However, due to the diversity of the biomass, its use as a solid fuel generates waste with diverse and unstable chemical composition. Waste from biomass combustion is a raw material with a very diverse composition, even in the case of using only one type of biomass. The content of individual elements in fly ash from the combustion of biomass ranges from zero to tens of percent. This makes it difficult to determine the optimal recovery methods. The ashes from the combustion of biomass are most commonly used in the production of building materials and agriculture. This article presents the elemental composition of the most commonly used biomass fuels. The results of the analysis of elemental composition of fly ashes from the combustion of forest and agricultural biomass in fluidized bed boilers used in the commercial power industry were presented. These ashes are characterized by a high content of calcium (12.3–19.4%), silicon (1.2–8.3%), potassium (0.05–1.46%), chlorine (1.1–6.1%), and iron (0.8–6.5%). The discussed ashes contained no sodium. Aluminum was found only in one of the five ashes. Manganese, chromium, copper, nickel, lead, zinc, sulfur, bismuth, titanium and zirconium were found in all of the examined ashes. The analysis of elemental composition may allow for a preliminary assessment of the recovery potential of a given ash.

The policy of sustainable development seeks to improve energy efficiency of industrial equipment. Efforts to improve energy efficiency also apply to the paint shops, where the recovery of waste heat is sought. The main source of a large amount of low-temperature waste heat in the paint shop is the spray booth. The second place where a large amount of low temperature waste heat is released is the room where the compressed air is prepared. Low energy efficiency of air compressors requires a large electric power supply. As a result, the emitted large heat fluxes become waste energy of the technological process. Heat is equivalent to up to 93% of the electric power supplied in the air compression process. There are solutions for recovering heat from compressors coming from the oil cooling water, but then the waste heat from the cooling of the compressed air and from the electric motor is released into air in the room. A method for recovering low-temperature waste heat from the air preparation room by means of an air-source heat pump has been proposed. An energy balance of the air compression and dehumidification process for the paint shop was made. A Matlab’s built-in numerical model includes air compressor and dehumidifier, heat recovery and accumulation for the purposes of use in the spray booth. A simulation experiment was carried out on the effectiveness of heat recovery from the air preparation room. The use of combined energy management in paint shops was proposed.