Trial series of cast alloy MO59 obtained from qualified scrap was investigated. SEM and TEM of resulting precipitates were conducted.

The SEM analysis demonstrated the dependence of silicon, phosphorus, iron, chromium and nickel in the composition of the so-called

hard precipitates. TEM analysis showed the formation of phase AlFeSi and AlCr. Made studies have shown the important role of the

composition of the batch melts brass CuZn39Pb2 type. The analysis of SEM and TEM resulting precipitates pointed to the formation of

various forms of divisions, only one of which was described in the literature character of the so-called hard inclusions. The SEM studies

demonstrated the dependence of the occurrence of inclusions rich in silicon, phosphorus, iron, chromium and nickel. In contrast, additional

TEM analysis indicated the formation of AlFeSi phase type and AlCr. The results of the analyses referred to the structure of the batch. Due

to the difficulty of obtaining recycled materials that do not contain these elements necessary to carry out further analyzes in the direction

of defining the role of phosphorus in the formation of the so-called hard inclusions.

The work determined the influence of aluminium in the amount from about 1% to about 7% on the graphite precipitates in cast iron with

relatively high silicon content (3.4% to 3.90%) and low manganese content (about 0.1%). The cast iron was spheroidized with cerium

mixture and graphitized with ferrosilicon. The performed treatment resulted in occurring of compact graphite precipitates, mainly nodular

and vermicular, of various size. The following parameters were determined: the area percentage occupied by graphite, perimeters of

graphite precipitates per unit area, and the number of graphite precipitates per unit area. The examinations were performed by means of

computer image analyser, taking into account four classes of shape factor. It was found that as the aluminium content in cast iron increases

from about 1.1% to about 3.4%, the number of graphite precipitates rises from about 700 to about 1000 per square mm. For higher

Al content (4.2% to 6.8%) this number falls within the range of 1300 – 1500 precipitates/mm2

. The degree of cast iron spheroidization

increases with an increase in aluminium content within the examined range, though when Al content exceeds about 2.8%, the area

occupied by graphite decreases. The average size of graphite precipitates is equal to 11-15 μm in cast iron containing aluminium in the

quantity from about 1.1% to about 3.4%, and for higher Al content it decreases to about 6 μm.

The influence of aluminium (added in quantity from about 0.6% to about 2.8%) on both the alloy matrix and the shape of graphite precipitates in cast iron treated with a fixed amounts of cerium mischmetal (0.11%) and ferrosilicon (1.29%) is discussed in the paper. The metallographic examinations were carried out for specimens cut out of the separately cast rods of 20 mm diameter. It was found that the addition of aluminium in the amounts from about 0.6% to about 1.1% to the cast iron containing about 3% of carbon, about 3.7% of silicon (after graphitizing modification), and 0.1% of manganese leads to the occurrence of the ferrite-pearlite matrix containing cementite precipitates in the case of the treatment of the alloy with cerium mischmetal . The increase in the quantity of aluminium up to about 1.9% or up to about 2.8% results either in purely ferrite matrix in this first case or in ferrite matrix containing small amounts of pearlite in the latter one. Nodular graphite precipitates occurred only in cast iron containing 1.9% or 2.8% of aluminium, and the greater aluminium content resulted in the higher degree of graphite spheroidization. The noticeable amount of vermicular graphite precipitates accompanied the nodular graphite.

The influence of aluminium added in amounts of about 1.6%, 2.1%, or 2.8% on the effectiveness of cast iron spheroidization

with magnesium was determined. The cast iron was melted and treated with FeSiMg7 master alloy under industrial conditions.

The metallographic examinations were performed for the separately cast rods of 20 mm diameter. They included the assessment of the

shape of graphite precipitates and of the matrix structure. The results allowed to state that the despheroidizing influence of aluminium

(introduced in the above mentioned quantities) is the stronger, the higher is the aluminium content in the alloy. The results of examinations

carried out by means of a computer image analyser enabled the quantitative assessment of the considered aluminium addition influence.

It was found that the despheroidizing influence of aluminium (up to about 2.8%) yields the crystallization of either the deformed nodular

graphite precipitates or vermicular graphite precipitates. None of the examined specimens, however, contained the flake graphite

precipitates. The results of examinations confirmed the already known opinion that aluminium widens the range of ferrite crystallization.

Among the elements that compose steel slags and blast furnace slags, metallic precipitates occur alongside the dominant glass and crystalline phases. Their main component is metallic iron, the content of which varies from about 90% to 99% in steel slags, while in blast furnace slags the presence of precipitates was identified with the proportion of metallic iron amounting to 100%. During observations using scanning electron microscopy and X-ray spectral microanalysis it has been found that the form of occurrence of metallic precipitates is varied. There were fine drops of metal among them, surrounded by glass, larger, single precipitates in a regular, spherical shape, and metallic aggregates filling the open spaces between the crystalline phases. Tests carried out for: slags resulting from the open-hearth process, slags that are a by-product of smelting in electric arc furnaces, blast furnace slags and waste resulting from the production of ductile cast iron showed that depending on the type of slag, the proportion and form of metallic precipitates is variable and the amount of Fe in the precipitates is also varied. Research shows that in terms of quality, steel and blast furnace slag can be a potential source of iron recovery. However, further quantitative analyses are required regarding the percentage of precipitates in the composition of slags in order to determine the viability of iron recovery. This paper is the first part of a series of publications aimed at understanding the functional properties of steel and blast furnace slags in the aspect of their destructive impact on the components of devices involved in the process of their processing, which is a significant operational problem.

Height, frequency and spatial differentiation of atmospheric precipitation of the summer season for the period 1975-1982 are presented. Results of the respective investigations are compared with atmospheric precipitation in other areas of the western coast of Spitsbergen.

The objective of this study was to investigate the dependence of the room temperature tensile properties on the volume fraction of discontinuous precipitates (DPs) in a cast AZ91 magnesium alloy. In order to obtain various volume fractions of DPs, the solution-treated alloy was aged at 428 K for up to 48 h. The volume fraction of DPs increased from 0% to 72% with an increase in the aging time up to 24 h; for aging times longer than 24 h, discontinuous precipitation was substantially inhibited owing to the occurrence of significant continuous precipitation within the α-(Mg) grains. YS and UTS of the alloy increased with the volume fraction of DPs, whereas the elongation showed a reverse trend. A relatively rapid change in the tensile properties with increasing volume fraction of DPs up to ~40% was noted, which would be due to the reduction of the effective α grain size in response to the formation of DPs along the grain boundaries.

The article is focused on thermomechanical and plastic properties of two high-manganese TRIPLEX type steels with an internal marking 1043 and 1045. Tensile tests at ambient temperature and at a temperature interval 600°C to 1100°C were performed for these heats with a different chemical composition. After the samples having been ruptured, ductility was observed which was expressed by reduction of material after the tensile test. Then the stacking fault energy was calculated and dilatation of both high-manganese steels was measured. At ambient temperature (20°C), 1043 heat featured higher tensile strength by 66MPa than 1045 heat. Microhardness was higher by 8HV0,2 for 1045 steel than for 1043 steel (203HV0,2). At 20°C, ductility only differed by 3% for the both heats. Decrease of tensile properties occurred at higher temperatures of 600 up to 1100°C. This tensile properties decrease at high temperatures is evident for most of metals. The strength level difference of the both heats in the temperature range 20°C up to 1100°C corresponded to 83 MPa, while between 600°C and 1100°C the difference was only 18 MPa. In the temperature range 600°C to 800°C, a decrease in ductility values down to 14 % (1045 heat), or 22 % (1043 heat), was noticed. This decrease was accompanied with occurrence of complex Aluminium oxides in a superposition with detected AlN particles. Further ductility decrease was only noted for 1043 heat where higher occurrence of shrinkag porosity was observed which might have contributed to a slight decrease in reduction of area values in the temperature range 900°C to 1100°C, in contrast to 1045 heat matrix.

The work presents results of investigations concerning the production of cast iron containing about 5-6% aluminium, with the ferritic

matrix in the as-cast state and nodular or vermicular graphite precipitates. The examined cast iron came from six melts produced under the

laboratory conditions. It contained aluminium in the amount of 5.15% to 6.02% (carbon in the amount of 2.41% to 2.87%, silicon in the

amount of 4.50% to 5.30%, and manganese in the amount of 0.12% to 0.14%). After its treatment with cerium mixture and graphitization

with ferrosilicon (75% Si), only nodular and vermicular graphite precipitates were achieved in the examined cast iron. Moreover, it is

possible to achieve the alloy of pure ferritic matrix, even after the spheroidizing treatment, when both the aluminium and the silicon occur

in cast iron in amounts of about 5.2÷5.3%.

Lysimeters represent the ideal tool for direct measurement of soil water balance components in soil profiles. Changes in the water content in a soil monolith can be measured with sufficient accuracy by the precise lysimeter weighing system.Water content changes in soil monolith as derived from lysimeter mass represent one of the basic water balance compo-nent. This paper deals with the development and comparison of individual soil water balance components in two different soil profiles from the Easter-Slovakian-Lowland. Two lysimeter vessels were filled monolithically with two different soil profiles covered with grass: one sandy soil profile from locality Poľany and one silty-loam soil profile from locality Vysoká nad Uhom. A constant groundwater level of 1 m below ground level was maintained in both soil profiles. Under the same meteorological conditions, all differences in the development of water balance components were caused only by the differences in soil profiles. The actual evapotranspiration and water flows at the bottom of the soil profiles were compared. Sandy soils are generally considered to be more prone to drought than silty-loam soils. Under the specific conditions of this experiment (maintaining a constant groundwater level) the opposite was shown, when the silty-loam soil profile was more prone to drought than sandy soil profile. Sandy soilprofile from Poľany reacted more quickly to precipitation (or evaporation). Due to the higher hydraulic conductivity of the sandy soil compared to the silty-loamy soil, the groundwater level response to external stimuli was much faster.

In this paper results of microstructural observations for series of CuZn39Pb2 alloys produced from qualified scraps are presented. The individual alloy melts were differentiated in terms of thermal parameters of continuous casting as well as refining methods and modifications. Structural observations performed by SEM and TEM revealed formation of different types of intermetallic phases including “hard particles”. EDS results show that “hard particles” are enrich in silicon, phosphorus, iron, chromium and nickel elements. Additionally, formation of Al-Fe-Si and Al-Cr in alloy melts was observed as well. It was found that quantity and morphology of intermetallic phases strongly depends upon the chemical composition of raw materials, process parameters, modifiers and refining procedure applied during casting. It was observed that refining process results in very effective refinement of intermetallic phases, whereas modifiers, particularly carbon-based, results in formation of large particles in the microstructure.

Certain chemical parameters such pH, specific electric conductivity (SpC) and concentrations of chloride ions (Cl-) have been analysed in samples of precipitation collected close to the Polish Polar Station at Hornsund (PPS), SW Spitsbergen. On the basis of seasonal data from years 1993-1994 and 1998-1999, some differences are apparent from the two sets. There is also a marked difference in the seasonal results, especially with respects to pH values; summer precipitation (pH of which can be as low as 3.78) is much more acidic than winter. This was particularly notable in respect of the summer of 1993, and was presumably the result of a relatively unusual atmospheric circulation and a high influx of airborne contaminants from Europe. The wide variation in specific electrical conductivity measurements is considered to be related to variations in wind direction and speed. That precipitation the highest total dissolved salts, of 11.7 mm w.e. (water equivalent), (November 1993), provided 10.7 g of salt per square metre of tundra near the Polish Polar Station. The proximity of the sea, consequently the development of marine aerosols, largely determines the chemical nature of the precipitation. Thus, variations in the chloride ion concentrations during the study periods more or less reflect the variations in the marine aerosol influences on the nature of the polluted precipitation. An analysis of the atmospheric circulation reveals that the most acid precipitation occurs most frequently in the C-8 type of circulation (cyclonic S + SW) and also, less so, for type C-3 (anticyclonic S + SW).

Independent Arctic records of temperature and precipitation from the same proxy archives are rare. Nevertheless, they are important for providing detailed information on long-term climate changes and temperature-precipitation relationships in the context of large-scale atmospheric dynamics. Here, we used chironomid and cladoceran fossil assemblages to reconstruct summer air- temperature and water-level changes, during the past 400 years, in a small lake located in Finnish Lapland. Temperatures remained persistently cold over the Little Ice Age (LIA), but increased in the 20th century. After a cooler phase in the 1970s, the climate rapidly warmed to the record-high temperatures of the most recent decades. The lake-level reconstruction suggested persistently wet conditions for the LIA, followed by a dry period between ~1910 and 1970 CE, when the lake apparently became almost dry. Since the 1980s, the lake level has returned to a similar position as during the LIA. The temperature development was consistent with earlier records, but a significant local feature was found in the lake-level reconstruction – the LIA appears to have been continuously wet, without the generally depicted dry phase during the 18th and 19th centuries. Therefore, the results suggest local precipitation patterns and enforce the concept of spatially divergent LIA conditions.

Two MgLiAl alloys of composition 4.5% Li and 1.5% Al (in wt.%) composed of α phase and of 9% Li, 1.5% Al composed of α (hcp) + β (bcc) phases were subjected to twist channel angular pressing (TCAP) deformation. Such deformation of α + β alloys caused less effective grain refinement than that of single α phase alloy. However, with increasing number of passes, grain size of single α phase alloy increased and that of β phase in two phase α + β alloy also grew, which suggested the effect of dynamic recrystallization. TEM studies allowed identifying particles of Li2MgAl phase of size of few μm. {001}<100> texture was observed in extruded alloy. Texture studies of extruded and TCAPed single phase hcp alloy indicated texture with {101 – 0} plane perpendicular to the extrusion direction and {0002} plane parallel to the extrusion direction. Duplex α + β alloys showed poor texture development.