A high content of fluorine was found in ornithogenic soils around penguin rookeries on King George Island. South Shetland Islands. Fluorine is inherent in 0.11% in krill (Euphausia superba). eaten by penguins. Fluorine content in penguins excreta increased approximately to 0.43%. and after decomposition and leaching to 1.03%. The concentration grew during mineralization of organic matter in guano (up to 2.2%). In a surface layer of guano fluorine occurred in apatite. A phosphatization was noted in a subsurface zone as the result of a reaction between guano leachates and weathered volcanic rocks. In the upper part of this zone near the large rookeries a fluorine occurred in minyulite (aluminium phosphate containing potassium and fluorine) and fluorine content here reached 3.5%. Sometimes fluorine was also bound with amorphous aluminium phosphate (up. to 2.0%). formed as a result of incongruently dissolving of minyulite in pure water.
The measurement of SO2, and fluorine compounds concentrations in the air at 8 points on the King George Island, South Shetland Islands, were done in January and February 1979. The received values were similar to the ones for regions recognized as the world background areas. The activity of the Polish Antarctic Station did not influence the air pollution status neither in its surroundings, nor in penguins colonies and extinct volcano areas on Penguin Island.