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Abstract

In order to determine the leading phase of the Fe - 4.25% C eutectic alloy, the method of directional crystallization, which allows to study the character of the solid / liquid growth front, was used. Examined eutectic was directionally solidified with a constant temperature gradient of G = 33,5 K/mm and growth rate of v = 125 μm/s (450 mm/h). The Bridgman technique was used for the solidification process. The sample was grown by pulling it downwards up to 30 mm in length. The alloy quenched by rapid pulling down into the Ga-In-Sn liquid metal. The sample was examined on the longitudinal section using a light microscope and scanning electron microscope. The shape of the solid/liquid interface and particularly the leading phase protrusion were revealed. The formation of the concave – convex interface has been identified in the quasi-regular eutectic growth arrested by quenching. The cementite phase was determined to be a leading phase. The total protrusion d is marked in the adequate figure.

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Authors and Affiliations

M. Trepczyńska-Łent
ORCID: ORCID

Authors and Affiliations

Małgorzata Perek-Nowak
1
Grzegorz Boczkal
1
ORCID: ORCID
Paweł Pałka
1
ORCID: ORCID
Piotr Kuropatwa
1

  1. Faculty of Non-Ferrous Metals, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków, Poland
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Abstract

The current work is dedicated to the mathematical description of a protrusion of the leading phase (cementite) over the wetting phase (austenite) observed during the author’s experiments in previous articles. A cementite protrusion is confirmed in the directionally solidified Fe-4.25% C eutectic alloy. The protrusion is defined due to the mass balance fulfilment. A coordinate system is attached to the solid/liquid interface, which is moving with the constant growth rate v.
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Bibliography

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[5] D .M. Stefanescu, Eutectic solidification, Science and Engineering of Casting Solidification, Springer 207 (2015).
[6] E . Fraś, Krystalizacja metali, Wydawnictwo Naukowo Techniczne, Warszawa (2003).
[7] M. Trepczyńska-Łent, Archives of Foundry Engineering 13 (3), 101-106 (2013).
[8] M. Trepczyńska-Łent, Archives of Metallurgy and Materials 58 (3), 987-991. (2013). DOI : https://doi.org/10.2478/amm-2013-0116
[9] M. Trepczyńska-Łent, Archives of Foundry Engineering 16 (4), 169-174 (2016). DOI : https://doi.org/10.1515/afe-2016-0104
[10] M. Trepczyńska-Łent, Archives of Metallurgy and Materials 62 (1), 365-368 (2017). DOI : https://doi.org/10.1515/amm-2017-0056
[11] M. Trepczyńska-Łent, Crystal Research and Technology 52 (7), 1600359 (2017). DOI : https://doi.org/10.1002/crat.201600359
[12] M. Trepczyńska-Łent, Archives of Foundry Engineering 19 (4), 113-116 (2019).
[13] E . Guzik, A model of irregular eutectic growth taking as an example the graphite eutectic in Fe-C alloys. Dissertations Monographies 15, AGH Kraków (1994).
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[21] W. Wołczyński, Archives of Metallurgy and Materials 65 (2), 653-666 (2020). DOI : https://doi.org/10.24425/amm.2020.132804
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Authors and Affiliations

M. Trepczyńska-Łent
1
ORCID: ORCID

  1. UTP University of Science and Technology, Mechanical Engineering Faculty, Bydgoszcz, Poland
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Abstract

Cu-2wt%Ag alloy with diameter of 10 mm was fabricated by induction heating directional solidification (IHDS). The effect of different mold temperatures on microstructure of IHDS Cu-2wt%Ag alloy was investigated. The results show that IHDS ­Cu-2wt%Ag alloy is mainly composed of coarse columnar grains at mold temperature of 1075°C. While the mold temperature is at 1100°C, 1150°C and 1200°C, respectively, the IHDS Cu-2wt%Ag alloy is composed of columnar grains and equiaxed grains and the number of grains increases. Meanwhile, the growth direction of columnar grains in the edge of alloys deviates from the direction of continuous casting to form “V” shape. While the mold temperature is controlled at high temperature, the induced current increases, which leads to the enhancement of eddy current in the mold. Therefore, the dendrites fall off to form new grains under the effect of eddy stirring, resulting in an increasing in the number of grains.

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Authors and Affiliations

Jihui Luo
Yangyang Li
Yanke Huang
Yuehao Huang
Yuling Zheng
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Abstract

One of the most important factors directly affecting microstructure and mechanical properties in directional solidification process is secondary dendrite arm spacing (SDAS). It is very important to measure the SDAS and examine the factors that may affect them. To investigate the effect of growth rate on the SDAS, the alloy specimens were directional solidified upward with different growth rates ( V = 8.3-83.0 μm/s) at a constant temperature gradient ( G = 4 K/mm) in a Bridgman-type growth apparatus. After the specimens are directionally solidified, they were exposed to metallographic processes in order to observe the dendritic solidification structure on the longitudinal section of the specimens. Coarsen secondary dendrite arm spacings (λ 2C) were measured excluding the first arms near the tip of the dendrite. Local solidification times ( tf) were calculated by ratio of spacings to growth rates. It was determined that the tf values decreased with increasing V values. The relationships between tf and λ 2C were defined by means of the binary regression analysis. Exponent values of tf were obtained as 0.37, 0.43, 0.46 and 0.47 according to increasing V values, respectively. These exponent values are close to the exponent value (0.33) predicted by the Rappaz-Boettinger theoretical model and good agreement with the exponent values (0.33-0.50) obtained by other experimental studies.
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Authors and Affiliations

Erkan Üstün
1
ORCID: ORCID
Emin Çadirli
1
ORCID: ORCID

  1. Niğde Ömer Halisdemir University, Institute of Science, Department of Physics, Niğde, Turkey
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Abstract

CM247LC alloy was manufactured by using selective laser melting (SLM) process, one of the laser powder bed fusion ­(L-PBF) methods. The hot isostatic pressing (HIP) process was additionally conducted on the SLM-built CM247LC to control its microstructures and defects. The high temperature oxidation property was investigated, and it was compared with conventional DS247LC sample (reference) prepared via the directional solidification process. The L-PBF HIP sample showed blocky-type MC carbides generated along the grain boundary with average size of about 200 nm. A semi-spherical primary γ' phase of size 0.4-1.0 μm was also observed inside the grains. Moreover, the DS247LC sample displayed a coarse eutectic γ' phase and many script-type MC carbides. Furthermore, cuboidal-type γ' with an average size of about 0.5 μm was detected. High-temperature oxidation tests were conducted at 1000°C and 1100°C for 24 hours. The results at 1100°C oxidation temperature showed that the measured oxidation weight gains for HIP and DS247LC were 1.96 mg/cm2 and 2.26 mg/cm2, respectively, indicating the superior high-temperature oxidation resistance of the L-PBF HIP sample. Based on the above results, a high-temperature oxidation mechanism of the CM247LC alloys manufactured by the SLM process and the directional solidification process has been proposed.
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Authors and Affiliations

Jung-Uk Lee
1
Young-Kyun Kim
2
ORCID: ORCID
Seong-Moon Seo
2
Kee-Ahn Lee
1
ORCID: ORCID

  1. Inha University, Department of Materials Science and Engineering, Incheon 22212, Republic of Korea
  2. Korea Institute of Materials Science, Changwon 51508, Republic of Korea

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