Polychlorinated biphenyls (PCBs) are one group of persistent organic pollutants (POPs) that are of international concern because of global distribution, persistence, and toxicity. Removal of these compounds from the environment remains a very difficult challenge because the compounds are highly hydrophobic and have very low solubility in water. A 900 W domestic microwave oven, pyrex vessel reactor, pyrex tube connector and condensing system were used in this experiment. Radiation was discontinuous and ray powers were 540, 720 and 900 W. The PCBS were analyzed by GC-ECD. The application of microwave radiation and H2O2/TiO2 agents for the degradation of polychlorinated biphenyl contaminated oil was explored in this study. PCB – contaminated oil was treated in a pyrex reactor by microwave irradiation at 2450 MHz with the addition of H2O2/TiO2. A novel grain TiO2 (GT01) was used. The determination of PCB residues in oil by gas chromatography (GC) revealed that rates of PCB decomposition were highly dependent on microwave power, exposure time, ratio to solvent with transformer oil in 3:1, the optimal amount of GT01 (0.2 g) and 0.116 mol of H2O2 were used in the study. It was suggested that microwave irradiation with the assistance of H2O2/TiO2 might be a potential technology for the degradation of PCB – contaminated oil. The experiments show that MW irradiation, H2O2 oxidant and TiO2 catalyst lead to a degradation efficiency of PCBs only in the presence of ethanol. The results showed that the addition of ethanol significantly enhanced degradation efficiency of PCBs.

Prof. Andrzej Dziembowski of the PAS Institute of Biochemistry and Biophysics, laureate of this year’s Prize of the Foundation for Polish Science (FNP), talks about RNA-degrading enzymes, the role of yeast in studies that help humans, and two different types of scientists.

The focus of this study is to investigate the applicability of natural mineral iron disulfide (pyrite) in degradation of aromatic compounds including benzene and several chlorinated benzenes (from mono-chlorinated benzene (CB), di-chlorinated benzenes (di-CBs) to tri-chlorobenzenes (tri-CBs) in aerobic pyrite suspension by using laboratory batch experiments at 25°C and room pressure. At first, chlorobenzene was studied as a model compound for all considered aromatic compounds. CB was degraded in aerobic pyrite suspension, transformed to several organic acids and finally to CO₂ and Cl^-. Transformations of remaining aromatic compounds were pursued by measuring their degradation rates and CO₂ and Cl^- released with time. Transformation kinetics was fitted to the pseudo-first-order reactions to calculate degradation rate constant of each compound. Degradation rates of the aromatic compounds were different depending on their chemical structures, specifically the number and position of chlorine substituents on the benzene ring in this study. Compounds with the highest number of chlorine substituent at m-positions have highest degradation rate (1,3,5-triCB > 1,3-diCB > others). Three chlorine substituents closed together (1,2,3-triCB) generated steric hindrance effects. Therefore 1,2,3-triCB wasthe least degraded compound. The degradation rates of all compounds were in the following order: 1,3,5-triCB > 1,3-diCB > 1,2,4-triCB ≅ 1,2-diCB ≅ CB ≅ benzene > 1,4-diCB > 1,2,3-triCB. The final products of the transformations were CO₂ and Cl^-. Oxygen was the common oxidant for pyrite and aromatic compounds. The presence of aromatic compounds reduced the oxidation rate of pyrite, which reduced the amount of ferrous and sulfate ions release to aqueous solution.

The subject of investigations was the fragment of low peatland complex located close to Miękinia,

about 30 km from Wrocław. Within the range of the examined area of peat bog complex there can be distinguished three parts differing in their utilization and composition of species, namely: 1/ the area degraded by the

attempt to afforest it with alder trees Alnus glutinosa (L.) Gaertner, 2/ occasionally used bog hay meadow and

3/ typical peat forming phytocenosis. Total number of determined species, belonging to 11 phytosociological

classes, ranged 77, out of which more than a half constitute representatives of Molinio-Arrhenatheretea class.

As far as a non-afforested area was concerned, there were determined 5 phytocenosis, including 4 classified as

peat forming ones and one typical for post-bog meadows (Alopecuretum pratensis). The afforested area featured

herbaceous plant composition which indicated that the area with Alopecuretum pratensis phytocenosis had been

degraded. Analysis of environmental requirements, done with the use of ecological numbers, proved that prevailing number of species characterize similar requirements. It was mainly afforested part to feature taxons of

broader ecological scale, e.g. Polygonum bistora L., Carex hirta L. and Plantago lanceolata L.

The afforested area was purchased by a private person, therefore it can be assumed that the reason for such

a way of peatlands utilization was obtaining EU subsidies at minimum work effort. A higher financial profit,

however, would have been made by the owner if he had maintained a bog area as an extensive meadow.

For the reliable applications of silver nanowires, AgNW, which is used as a conductive transparent film in electronic devices, the isothermal degradation behaviors of AgNW films with and without overcoating were investigated. Accelerated isothermal degradation was performed as a function of temperature, time, and atmosphere. Electrical resistance and optical transmittance were measured and correlated with the microstructural damages, such as formation of oxide particles and fragmentations of AgNW, which were quantitatively determined from the scanning electron micrographs. The overcoating retarded the formation of oxide particles and subsequent fragmentations as well as resulting degradation in electrical resistance without affecting the optical transmittance.

A sediment trap with bamboo materials can be utilized as one alternative of eco-friendly technology to reduce the ero-sion that occurred on agricultural land. This study aims to determine the most efficient form of that sediment trap in the field. Location study is in the Tulungrejo Village, Batu, Indonesia, which has andosol soil type and 35 cases of a landslide in 2013. Three forms of sediment traps were used (square, trapezoidal, and stratified type) with the purpose to find the most effective form. It is obtained that the most effective sediment trap is a stratified form with the 31.91% effectiveness or able to withstand sediment of 25.02 kg, while the adequate number is two pieces with the ability to withstand the most consider-able sediment of (91.70%). Therefore this stratified form of sediment traps is effective in erosion prevention on agriculturalland in the study area. For further development, it is required to test out the variations of the contents in a broader area with a more varied level of the slope.

The paper presents the response of a three-layered annular plate with damaged laminated facings to the loads acting in their planes. The presented problem concerns the analysis of the combination of global plate failure in the form of buckling with the local micro defects, like fibre or matrix cracks, located in the laminas. The plate structure consists of thin laminated, fibre-reinforced composite facings and a thicker foam core. The matrix and fibre cracks of facings laminas can be transversally symmetrically or asymmetrically located in plate structure. Critical static and dynamic stability analyses were carried out solving the problem numerically and analytically. The numerical results show the static and dynamic stability state of the composite plate with different combinations of damages. The final results are compared with those for undamaged structure of the plate and treated as quasi-isotropic ones. The analysed problem makes it possible to evaluate the use of the non-ideal composite plate structure in practical applications.

This paper studies the assessment of sensitivity to land degradation of Deliblato sands (the northern part of Serbia), as a special nature reserve. Sandy soils of Deliblato sands are highly sensitive to degradation (given their fragility), while the system of land use is regulated according to the law, consisting of three zones under protection. Based on the MEDALUS approach and the characteristics of the study area, four main factors were considered for evaluation: soil, climate, vegetation and management. Several indicators affecting the quality of each factor were identified. Each indicator was quantified according to its quality and given a weighting of between 1.0 and 2.0. ArcGIS 9 was utilized to analyze and prepare the layers of quality maps, using the geometric mean to integrate the individual indicator map. In turn, the geometric mean of all four quality indices was used to generate sensitivity of land degradation status map. Results showed that 56.26% of the area is classified as critical; 43.18% as fragile; 0.55% as potentially affected and 0.01% as not affected by degradation. The values of vegetation quality index, expressed as coverage, diversity of vegetation functions and management policy during the protection regime are clearly represented through correlation coefficient (0.87 and 0.47).

A determination of the heating degree of the moulding sand with bentonite on the grounds of simulating investigations with the application of the MAGMA program, constitutes the contents of the paper. To this end the numerical simulation of the temperature distribution in the virtual casting mould was performed. It was assumed that the mould cavity was filled with a moulding sand with bentonite of a moisture content 3,2 % and bentonite content 8 %. A computer simulation can be used for predicting the heating degree of moulding sands with bentonite. Thus, prediction of the active bentonite (montmorillonite) content in individual layers of the overheated moulding sand can be done by means of the simulation. An overheating degree of a moulding sand with bentonite, and thus the bentonite deactivation depends on a temperature of a casting alloy, casting mass, ratio of: masssand : masscasting, moulding sand amount in the mould and contact area: metal – mould (geometry of the casting shape). Generally it can be stated, that the bentonite deactivation degree depends on two main factors: temperature of moulding sand heating and time of its operation.

The paper presents the test results for the microstructure of ZnO varistors comprising high voltage gapless surge arresters. The tests were performed on varistors produced in different periods and by various manufacturers. The research was inspired by different characteristics of changes in values of current flowing through surge arresters as a function of changes in values of system voltage in a 220 kV substation, and the temperature in a multi-year cycle. Furthermore, the effects of varistor microstructure degradation following a failure of an unsealed surge arrester were investigated. The results provided the grounds for assessment of ZnO varistor microstructure parameters in terms of their durability and resistance to degradation processes.

The aim of the presented work is to prove that construction of large sports facilities in the urban space, can generate positive changes and revitalization of degraded areas. On the basis of comparative analysis of cases in which such activities took place, it can be concluded that locating these facilities in heavily degraded urban areas is one of the most eff ective methods of large-scale revitalization. This is mainly visible in post-industrial areas, which are usually well linked to canals, rivers and other waterways or reservoirs. The vast spaces around sports facilities create favorable conditions for additional recreational functions, such as parks and green areas, which in connection with water become a very attractive place for the residents of the city. Increasing interest in the area leads to new investments such as housing estates and gradual development of a multi-functional urban structure. One of the most important factors leading to this type of transformation is the modernization of the communication infrastructure which enables connection between revitalized areas and the rest of the city. A well-planned program of newly emerging sports facilities is also an extremely important factor. As research shows, large multifunctional sports and entertainment facilities, can function as a new kind of public space in the city. This leads not only to the establishment of completely new social relations, but also to the creation of jobs and the general improvement of the broadly understood image of the district.

In accordance with the principles of conducting revitalization activities specified in the Revitalization Act in force from 9 October 2015 and horizontal guidelines for revitalization in operational programs for 2014-2020, the preparatory phase of the revitalization process should include multi-layered analyzes concluded with deductions included in communal urban regeneration programs. The article describes the role of student architectural and urban competitions performed in cooperation between municipalities and universities as innovative analytical and conceptual activities that could form the basis for specifying recommendations in revitalization strategies planned by a given municipality. The infl uence of the student competitions’ results on the development of the city revitalization strategy is presented on grounds of periodic competitions organized at the Faculty of Architecture of the Gdańsk University of Technology in cooperation with the Department of Plans and Marketing of the City Hall of the City of Gdańsk.

In this study, X-ray diffraction, thermogravimetric analysis and differential scanning calorimetry (DSC) method were used to analyze the main characteristics of sweet potato starch, and to analyze the thermal degradation process of sweet potato starch. Specifically, X-ray diffraction to study its structure, thermogravimetric analysis to study the thermal degradation kinetics, and differential scanning calorimetry to study the thermogram of sweet potato starch. The thermal decomposition kinetics of sweet potato starch was examined within different heating rates in nitrogen atmosphere. Different models of kinetic analysis were used to calculate the activation energies using thermogravimetric data of the thermal degradation process. Activation energies obtained from Kissinger, Flynn-Wall- Ozawa, and Šatava-Šesták models were 173.85, 174.87 and 174.34 kJ/mol, respectively. The values of activation energy indicated that the thermal degradation of the sweet potato starch was a single reaction mechanism or the combination of multi-reaction mechanisms. The differential scanning calorimetry analysis show that two decomposition stages were presented: the first at a low temperature involves the decomposition of long chain; and the second at a high temperature represents the scission of glucose ring. This information was helpful to design the processing process of many natural polymers. Thermogravimetric Fourier transform-infrared (TG–FTIR) analysis showed that the main pyrolysis products included water, methane, carbon dioxide, ammonia, and others.