Wyroby stalowe i żeliwne ze względu na niską cenę i korzystne właściwości znajdują najszersze zastosowanie wśród metali w gospodarce, a ich zużycie stało się wskaźnikiem rozwoju gospodarczego. W artykule przedstawiono charakterystykę surowców żelaza w odniesieniu do obecnych wymagań hutnictwa. Globalizacja handlu i rozwój technologii wytwarzania stali w ostatnim półwieczu spowodowały istotne zmiany w jakości wsadowych surowców mineralnych. Wymusiło to usprawnienie technologii przeróbczych przez zakłady górnicze. Przedmiotem światowego handlu są obecnie standardowe koncentraty o zawartości żelaza ponad 60%, tj. niemal dwukrotnie bogatsze niż rudy przetwarzane w połowie XX wieku w wielu krajach. Udoskonalone zostały sposoby oceny jakości surowców wsadowych i zaostrzono normy jakości.

W publikacji dokonano przeglądu wymagań jakościowych najbardziej istotnych surowców: rud i koncentratów żelaza, złomu stalowego, głównych metali stopowych, węgla koksowego i koksu oraz gazu i innych nośników energii. Zwrócono szczególną uwagę na metodykę badania jakości surowców oraz standaryzację surowców wsadowych. Jakość surowców oceniana jest wieloparametrycznie; istotne są zarówno cechy chemiczne, jak i fizyczne. Gorsze parametry jakościowe surowców wsadowych skutkują niższymi cenami uzyskiwanymi przez dostawców w obrocie.

Rynki tych surowców są zróżnicowane, kierowane odrębnymi i częściowo nowymi regułami. W obrocie handlowym funkcjonują standardy odniesień cenowych (np. ceny węgla metalurgicznego w Australii czy indeksy cenowe koncentratów żelaza). Część surowców kwotowana jest w systemie giełdowym (niektóre składniki stopowe i złom stalowy). Rezygnacja z powszechnych dawniej kontraktów wieloletnich doprowadziła do dużych wahań cen, które osiągnęły podobną skalę jak inne metale.

The aim of the study was to select the optimal content of zirconium introduced as an alloying additive to obtain the best strength properties of Al-Si alloy. A technically important disadvantage is the tendency of silumins to form a coarse-grained structure that adversely affects the mechanical properties of castings. To improve the structure, modification processes and alloying additives are used, both of which can effectively refine the structure and thus increase the mechanical properties. According to the Hall-Petch relationship, the finer is the structure, the higher are the mechanical properties of the alloy. The proposed addition of zirconium as an alloying element has a beneficial effect on the structure and properties of silumins, inhibiting the grain growth. The starting material was an aluminium-silicon casting alloy designated as EN AC-AlSi9Mg (AK9). Zirconium (Zr) was added to the alloy in an amount of 0.1%, 0.2%, 0.3%, 0.4% and 0.5% by weight. From the modified alloy, after verification of the chemical composition, samples were cast into sand moulds based on a phenolic resin.
The first step in the research was testing the casting properties of alloys with the addition of Zr (castability, density, porosity). In the next step, the effect of zirconium addition on the structure and mechanical properties of castings was determined.

The paper discusses issues related to the technology of melting and processing of copper alloys. An assessment was made of the impact of titanium and iron introduced in the form of pre-alloy - Ti73Fe master alloy on the microstructure and selected properties of pure copper and copper-silicon alloy. There are known examples of the use of titanium and iron additive to the copper alloy. Titanium as an additive introduced to copper alloys to improve their properties is sometimes also applicable. In the first stage of the study, a series of experimental castings were conducted with variable content of Ti73Fe master alloy entering copper in quantities of 5 %, 15 %, 25 % in relation to the mass of the metal charge. In the second stage, a silicon additive was introduced into copper in the amount of about 4 % by weight and 0.5 % and 1 % respectively of the initial Ti73Fe alloy. Thermodynamic phase parameters were modelled using CALPHAD method and Thermo-Calc software, thus obtaining the crystallization characteristics of the test alloys and the percentage of structural components at ambient temperature. Experiments confirmed the validity of the use of Ti73Fe master alloy as an additive. The pre-alloy used showed a favourable performance, both in terms of addition solubility and in the area of improvement of strength properties. Changes were achieved in the microstructure, mainly within the grain, but also in the developed dendrites of the solid solution. Changes occur with the introduction of titanium with iron into copper as well as to two-component silicon bronze.

Microstructure, mechanical, and corrosion properties of as-cast pure zinc and its binary and ternary alloys with magnesium (Mg), and copper (Cu) additions were investigated. Analysis of microstructure conducted by scanning electron microscopy revealed that alloying additives contributed to decreasing average grain size compared to pure zinc. Corrosion rate was calculated based on immersion and potentiodynamic tests and its value was lower for materials with Cu content. Moreover, it was shown that the intermetallic phase, formed as a result of Mg addition, constitutes a specific place for corrosion. It was observed that a different type of strengthening was obtained depending on the additive used. The presence of the second phase with Mg improved the tensile strength of the Zn-based materials, while Cu dissolved in the solution had a positive effect on their elongation.