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Peganum Harmala L. plant as green non-toxic adsorbent for iron removal from water

Raiedhah Alsaiari Iman Shedaiwa Fatima A. Al-Qadri Esraa M. Musa Huda Alqahtani Faeza Alkorbi Norah A. Alsaiari Mervate M. Mohamed
Archives of Environmental Protection | 2024 | 50 | 1 | 3-12 | DOI: 10.24425/aep.2024.149894
Keywords Fe (III); kinetics; adsorption isotherm; equilibrium; Penganum Harmala;
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Abstract

The present work focuses on examining the batch removal of Fe (III) from water using powdered Peganum Harmala seeds, characterized as FT-IR. In this work, several parameters are measured, including contact time, pH, Fe (III) concentration, reaction temperature effect, and adsorbent dose effect. Fe (III) adsorption was assessed using a UV-vis spectrophotometer at a wavelength of 620 nm. The findings demonstrated a positive correlation between the dosage of adsorbent and Fe (III) ions removal, with an increase in the adsorbent dose corresponding to higher elimination of Fe (III) ions. Therefore, the Langmuir isotherm model yielded more accurate equilibrium data compared to the Frendulich model. The kinetic data were mostly analyzed using a pseudo-second-order model rather than a pseudo-first-order model. Thermodynamic parameters, including enthalpy (ΔH◦), entropy (ΔS◦), and free energy (ΔG◦), were calculated. The adsorption process was found to be exothermic. Overall, Peganum Harmala was a favorable adsorbent for removing Fe (III) from aqueous solutions.
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Bibliography

  1. Abdel-Ghani, N. T., Hefny, M. & El-Chaghaby, G. A. F. (2007). Removal of Lead from Aqueous Solution Using Low Cost Abundantly Available Adsorbents. International Journal of Environmental Science & Technology 4(1), pp. 67–73. DOI:10.1007/BF03325963.
  2. Aksu, Z. & Alper Işoǧlu, I. (2005). Removal of Copper(II) Ions from Aqueous Solution by Biosorption onto Agricultural Waste Sugar Beet Pulp. Process Biochemistry 40(9), pp. 3031–3044. DOI:10.1016/J.PROCBIO.2005.02.004.
  3. Aksu, Z. & Tülin, K. (1991). A Bioseparation Process for Removing Lead(II) Ions from Waste Water by Using C. Vulgaris. Journal of Chemical Technology & Biotechnology 52(1), pp. 109–118. DOI:https://doi.org/10.1002/jctb.280520108.
  4. Ang, X. W., Sethu, V. S. Andresen, J. M. & Sivakumar, M. (2013). Copper(II) Ion Removal from Aqueous Solutions Using Biosorption Technology: Thermodynamic and SEM–EDX Studies.” Clean Technologies and Environmental Policy 15(2), pp. 401–407. DOI:10.1007/s10098-012-0523-0.
  5. Annadurai, G., R., Juang, S. and Lee, D. J. (2003). Adsorption of Heavy Metals from Water Using Banana and Orange Peels. Water Science and Technology, 47(1), pp. 185–190. DOI:10.2166/wst.2003.0049.
  6. Aregawi, B.H. & Mengistie, A.A. (2013). Removal of Ni(II) from Aqueous Solution Using Leaf, Bark and Seed of Moringa Stenopetala Adsorbents. Bulletin of the Chemical Society of Ethiopia 27(1), pp. 35–47. DOI:10.4314/bcse.v27i1.4.
  7. Ayaz, T., Khan,S., Khan, A.Z., Lei, M. & Mehboob, A. (2020). Remediation of Industrial Wastewater Using Four Hydrophyte Species: A Comparison of Individual (Pot Experiments) and Mix Plants (Constructed Wetland). Journal of Environmental Management 255:109833. DOI:https://doi.org/10.1016/j.jenvman.2019.109833.
  8. Belay, K.T. & Hayelom, A. (2014). Removal of Methyl Orange from Aqueous Solutions Using Thermally Treated Egg Shell (Locally Available and Low Cost Biosorbent).” Chemistry and Materials Research 6, pp. 31–39.
  9. Bhatti, I., Qureshi, K., Kazi, R, & Ansari, Q. (2008). Preparation and Characterization of Chemically Activated Almond Shells by Optimization of Adsorption Parameter for the Removal of Cr (VI) from Aqueous Solution. International Journal of Chemical and Biomolecular Engineering 1, pp. 50–55.
  10. Bulut, Y. & Tez, Z. (2007). Adsorption Studies on Ground Shells of Hazelnut and Almond. Journal of Hazardous Materials, 149(1), pp. 35–41. DOI:10.1016/J.JHAZMAT.2007.03.044.
  11. Chakravarty, P., Sen Sarma,N. & Sarma, H. P. (2010). Removal of Lead(II) from Aqueous Solution Using Heartwood of Areca Catechu Powder.” Desalination 256(1–3), pp. 16–21. DOI:10.1016/J.DESAL.2010.02.029.
  12. El-Araby, H.A,, Abel M. Ibrahim, M. A., Mangood, A.H. & Abdel-Rahman, M. A. (2017). Sesame Husk as Adsorbent for Copper(II) Ions Removal from Aqueous Solution. Journal of Geoscience and Environment Protection 05(07), pp. 109–152. DOI:10.4236/gep.2017.57011.
  13. El-Ashtoukhy, E. S. Z., Amin, N. K. & Abdelwahab, O. (2008). Removal of Lead (II) and Copper (II) from Aqueous Solution Using Pomegranate Peel as a New Adsorbent. Desalination 223(1–3), pp. 162–173. DOI:10.1016/J.DESAL.2007.01.206.
  14. El-Geundi, M.S. (1991). Homogeneous Surface Diffusion Model for the Adsorption of Basic Dyestuffs onto Natural Clay in Batch Adsorbers. Adsorption Science & Technology 8(4), pp. 217–225. DOI:10.1177/026361749100800404.
  15. Freundlich, H. M. F. (1906). Over the Adsorption in Solution. J. Phys. Chem 57, pp. 385–471.
  16. Gładysz-Płaska, A., Majdan, M., Pikus, SD. & Sternik, D. (2012). Simultaneous Adsorption of Chromium(VI) and Phenol on Natural Red Clay Modified by HDTMA. Chemical Engineering Journal 179, pp. 140–150. DOI:10.1016/J.CEJ.2011.10.071.
  17. Hejna, M., Moscatelli, A., Stroppa, N., Onelli, E., Pilu, S., Baldi, A. & Rossi, L. (2020). Bioaccumulation of Heavy Metals from Wastewater through a Typha Latifolia and Thelypteris Palustris Phytoremediation System. Chemosphere 241, 125018. DOI:10.1016/J.CHEMOSPHERE.2019.125018.
  18. Hema, M. A., & Arivoli, S. (2010). Adsorption Kinetics and Thermodynamics of Malachite Green Dye unto Acid Activated Low Cost Carbon. Journal of Applied Sciences and Environmental Management 12(1), pp. 43-51.
  19. Ho, Y. S. &. McKay, G. (1998). Sorption of Dye from Aqueous Solution by Peat. Chemical Engineering Journal 70(2), pp. 115–24. DOI:10.1016/S0923-0467(98)00076-1.
  20. Hossain, M. A., Ngo, H. H., Guo, W. S. & Setiadi, T. (2012). Adsorption and Desorption of Copper(II) Ions onto Garden Grass. Bioresource Technology 121, pp. 386–395. DOI:10.1016/J.BIORTECH.2012.06.119.
  21. Imran, A. & Gupta, V. K. (2006). Adsorbents for Water Treatment: Development of Low-Cost Alternatives to Carbon. pp. 149–184 [in] Encyclopedia of Surface and Colloid Science, Taylor & Francis, New York,. Vol. 2nd Edition.
  22. Kučić, D., Simonič, M. & Furač, L. (2017). Batch Adsorption of Cr (VI) Ions on Zeolite and Agroindustrial Waste. Chemical and Biochemical Engineering Quarterly 31(4), pp. 497–507.
  23. Kumar, M.A., Chitra, R. & Mishra, G. K. (2010). REMOVAL OF HEAVY METAL IONS Removal of Heavy Metal Ions from Aqueous Solutions Using Chemically (Na 2 S) Treated Granular Activated Carbon as an Adsorbent. Vol. 69.
  24. Laghrib, F., Sana S., Lahrich, S. & El Mhammedi, M.A. (2021). Best of Advanced Remediation Process: Treatment of Heavy Metals in Water Using Phosphate Materials. International Journal of Environmental Analytical Chemistry 101(9), pp. 1192–1208. DOI:10.1080/03067319.2019.1678603.
  25. Langmuir, I. (1916). “THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. PART I. SOLIDS.” Journal of the American Chemical Society, 38(11), pp. 2221–2295. DOI:10.1021/ja02268a002.
  26. Lesley, J., Jun, B.M., Flora, J.R.V., Park, C.M. & Yoon, Y. (2019). Removal of Heavy Metals from Water Sources in the Developing World Using Low-Cost Materials: A Review. Chemosphere 229, pp. 142–159. DOI:10.1016/J.CHEMOSPHERE.2019.04.198.
  27. Mamba, B. B., Dlamini, N. P. & Mulaba-Bafubiandi. A. F. (2009). Biosorptive Removal of Copper and Cobalt from Aqueous Solutions: Shewanella Spp. Put to the Test. Physics and Chemistry of the Earth, Parts A/B/C 34(13–16), pp. 841–849. DOI:10.1016/J.PCE.2009.07.009.
  28. Moussavi, G. & Khosravi, R. (2012). Preparation and Characterization of a Biochar from Pistachio Hull Biomass and Its Catalytic Potential for Ozonation of Water Recalcitrant Contaminants. Bioresource Technology 119, pp. 66–71. DOI:10.1016/J.BIORTECH.2012.05.101.
  29. Oo, C.-W., Osman, H., Fatinathan, S. & Akmar, Md. Zin.M. (2013). The Uptake of Copper(II) Ions by Chelating Schiff Base Derived from 4-Aminoantipyrine and 2-Methoxybenzaldehyde. International Journal of Nonferrous Metallurgy 02(01), pp. 1–9. DOI:10.4236/ijnm.2013.21001.
  30. Pandey, P., Sambi,S.S., Sharma, S. K. & Singh, S. (2009). Batch Adsorption Studies for the Removal of Cu (II) Ions by ZeoliteNaX from Aqueous Stream. edited by Proceedings of the World Congress on Engineering and Computer Science. San Francisco.
  31. Rasgele, P.G. (2021). The Use of Allium Cepa L. Assay as Bioindicator for the Investigation of Genotoxic Effects of Industrial Waste Water. Archives of Environmental Protection 47(4), pp. 3–8. DOI:10.24425/aep.2021.139497.
  32. Skwarek, E., Matysek-Nawrocka, M., Zarko, V. & Moiseevich, V. (2008). Adsorption of Heavy Metal Ions at the Al2O3-SiO2/NaClO4 Electrolyte Interface. Physicochemical Problems of Mineral Processing 42.
  33. Sud, D., Mahajan, G. & Kaur, M. P. (2008). Agricultural Waste Material as Potential Adsorbent for Sequestering Heavy Metal Ions from Aqueous Solutions – A Review. Bioresource Technology, 99(14), pp, 6017–6027. DOI:10.1016/J.BIORTECH.2007.11.064.
  34. Tran, H.N., You, S.J. & Chao, H.P. (2016). Thermodynamic Parameters of Cadmium Adsorption onto Orange Peel Calculated from Various Methods: A Comparison Study. Journal of Environmental Chemical Engineering 4(3), pp. 2671–2682. DOI:10.1016/J.JECE.2016.05.009.
  35. Trus, I., Gomelya, M., Vorobyova, V. & Skіba, M. (2021). Promising Method of Ion Exchange Separation of Anions before Reverse Osmosis. Archives of Environmental Protection, 47(4), pp. 93–97. DOI:10.24425/aep.2021.139505.
  36. Tumin, N., Chuah, A.L., Zawani, Z. & Suraya, A. R. (2008). Adsorption of Copper from Aqueous Solution by Elais Guineensis Kernel Activated Carbon. Journal of Engineering Science and Technology 3(2), pp. 180-189.
  37. Veli, S. & Alyüz, B. (2007). Adsorption of Copper and Zinc from Aqueous Solutions by Using Natural Clay. Journal of Hazardous Materials 149(1), pp. 226–233. DOI:https://doi.org/10.1016/j.jhazmat.2007.04.109.
  38. Vijayaraghavan, K., Teo, T.T., Balasubramanian, R. & Joshi, U.M. (2009). Application of Sargassum Biomass to Remove Heavy Metal Ions from Synthetic Multi-Metal Solutions and Urban Storm Water Runoff. Journal of Hazardous Materials 164(2–3), pp. 1019–1023. DOI:10.1016/J.JHAZMAT.2008.08.105.
  39. Weber, T.W..& Chkravorti,R.K. (1974). Pore and Solid Diffusion Models for Fixed-Bed Adsorbers. AIChE Journal, 20(2), pp. 228–238. DOI:10.1002/aic.690200204.
  40. Wu, H., Wu, Q., Zhang, J., Gu, Q., Wei, L., Guo, W. & He, M. (2019). Chromium Ion Removal from Raw Water by Magnetic Iron Composites and Shewanella Oneidensis MR-1. Scientific Reports, 9(1). DOI:10.1038/s41598-018-37470-1.
  41. Yao, Z. Y., Qi, J. H. & Wang, L. H. (2010). Equilibrium, Kinetic and Thermodynamic Studies on the Biosorption of Cu(II) onto Chestnut Shell. Journal of Hazardous Materials 174(1–3), pp. 137–143. DOI:10.1016/J.JHAZMAT.2009.09.027.
  42. Zendelska, A., Golomeova, M., Blazev, K., Krstev, B., Golomeov, B. & Krstev, A. (2015). Adsorption of Copper Ions from Aqueous Solutions on Natural Zeolite. Environment Protection Engineering, 41(4), pp. `,17–36. DOI:10.5277/epe150402.
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Authors and Affiliations

Raiedhah Alsaiari
1
Iman Shedaiwa
1
Fatima A. Al-Qadri
1
Esraa M. Musa
1 2
Huda Alqahtani
3
Faeza Alkorbi
1
Norah A. Alsaiari
1
Mervate M. Mohamed
1 4
  1. Empty Quarter Research Unit, Department of Chemistry, College of Science and Art in Sharurah, Najran University, Saudi Arabia
  2. Veterinary Research Institute (VRI), P. O BOX 8067, AL Amarat, Khartoum, Sudan
  3. Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia
  4. Chemistry Department, Faculty of Science, Suez Canal University, Ismailia, Egypt

Cleaning of pesticides from aqueous solution by a newly synthesized organoclay

Gülay Baysal
Archives of Environmental Protection | 2019 | vol. 45 | No 3 | 21-30 | DOI: 10.24425/aep.2019.128637
Keywords adsorption isotherms and kinetics 1-methyl-di-octyl-1 phenyl ammonium iodide toxic compounds organoclay
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Abstract

In the present study, the novel quaternary ammonium salt (QAS+), 1-methyl-di-octyl-1 phenyl ammonium iodide (QAS1), was synthesized by complete alkylation reaction. Sodium montmorillonite (Mt) was modified via an ion-exchange reaction with QAS1+. The modified material and quarternary ammonium salt (Mt1 and QAS1) were analyzed by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Removal capacity of hydrophobic organic pollutants such as 4-nitrophenol (4-NP) and 2,4-dinitrophenol (2,4-DNP) from solution media of synthesized organoclay was evaluated. The optimum conditions and batch kinetics of adsorption of 4-nitrophenol and 2,4-dinitrophenol from aqueous solutions are reported. It was shown that the adsorption capacity decreased in the order 4-NP> 2,4-DNP. The total mass loss during the drying process was 66% and 78%, respectively. Thermodynamic parameters enthalpy (∆H0) and entropy (∆S0) and the mean free energy (E) for the adsorption of nitrophenol compounds (NCP) were determined.

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Authors and Affiliations

Gülay Baysal

The Removal of Cr(VI) from the Aqueous Solution by Granular Ferric Hydroxide (GFH)

Bai Yuan Bronisław Bartkiewicz
Archives of Environmental Protection | 2009 | vol.35 | No 2 | 115-123
Keywords Granular ferric hydroxide (GrH) adsorption isotherms batch tests column tests Chromium Carbide
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Abstract

In this work, sorption of chromium on granular ferric hydroxide (GFH) has been investigated using batch and column techniques. The adsorption behavior of Cr on GFH, depending on pH, contact lime and sorbent amount were studied. The equilibrium adsorption capacity of GFH for Cr was measured and cxtrapo latcd using Freundlich isotherms. Metal ions bounded lo the GFH could be recovered by alkaline solution, and the GFH can be recycled. The sorption capacity of GFH was 25.0 mg/g. The ion exchange of chromium on GFH follows pseudo-first-order kinetics. The intraparticlc diffusion of chromium on GFH presents the limiting rate. The results indicated practical value of this method for industry and also provide strong evidence to support the proposed thesis about the adsorption mechanism.
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Authors and Affiliations

Bai Yuan
Bronisław Bartkiewicz

Low-cost removal of basic red 9 using cow dung ash

Raj Kumar Arya Ghanshyam Meena Devyani Thapliyal Sanghamitra Barman Gopinath Halder Pooja Shandilya
Chemical and Process Engineering | 2022 | vol. 43 | No 2 (The International Chemical Engineering Conference 2021 (ICHEEC): 100 Glorious Years of Chemical Engineering and Technology, held from September 16–19, 2021 at Dr B. R. Ambedkar National Institute of Technology, Jalandhar, Punjab, India. Guest editor: Dr Raj Kumar Arya, Dr Anurag Kumar Tiwari) | 229-242 | DOI: 10.24425/cpe.2022.140826
Keywords adsorption isotherms adsorption kinetics dye removal low-cost adsorbent cow dungash
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Abstract

In the present study, basic red 9 had been removed from synthetic waste water using animal waste. Cow dung ash had been prepared and characterized by scanning electron microscope. Morphology analysis shows very fine particles of less than 1 μm. The pH analysis study favours a pH of 8.5 for maximum dye removal. The removal of basic red 9 was very fast on cow dung ash. Percentage dye removal was 80.24% and 95.24 in 5 minutes and 90 minutes, respectively at initial dye concentration of 10 ppm.
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Authors and Affiliations

Raj Kumar Arya
1
Ghanshyam Meena
2 3
Devyani Thapliyal
1
Sanghamitra Barman
4
Gopinath Halder
5
Pooja Shandilya
6
  1. Dr. B.R. Ambedkar National Institute of Technology, Department of Chemical Engineering, Jalandhar,144011, Punjab, India
  2. Jaypee University of Engineering and Technology, Guna, 473226, Madhya Pradesh, India
  3. National Fertilizers Ltd., Bathinda, Punjab-151003, India
  4. Thapar Institute of Engineering and Technology, Department of Chemical Engineering, Patiala, 147004, Punjab, India
  5. National Institute of Technology Durgapur, Department of Chemical Engineering, M. G. Avenue, Durgapur-713209, West Bengal, India
  6. Shoolini University, School of Advanced Chemical Sciences, Solan HP, 173229, India

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