This paper presents the results of research focused on the lowering of ash flow temperature at semianthracite coal from Donbas district by means of additive (calcite) dosing. Ash fusion temperatures were set for two coal samples (A, B) and for five various states (samples of ash without any additives, with 1%, with 3%, with 5% and with 7% of the additive) in total. The macroscopicphotographic method was used for identifying all specific temperatures. Obtained outputs prove that A type coal has a lower value of sphere temperature than B type coal in the whole scope of percentage representation of the additive. The flow temperature dropped in total from 1489 °C to 1280 °C, i.e. by 14% during the test of coal of type A with 7% of the additive; while it was near 10% for coal of type B (from 1450 °C to 1308 °C). Numerical simulations of the process showed that it is not effective to add an additive with a grain size lower than 280 μm by means of wastevapour burners.

The aim of the study was to determine the applicability of a new product added to water glass-containing foundry sands hardened with

ethylene glycol diacetate. The new additive designated by the symbol "B" is a composition of aqueous solutions of modified polyalcohols,

improving the sand knocking out properties. The scope of studies included testing various mechanical and technological properties

of foundry sand mixtures, such as permeability, friability, life cycle of cores and knocking out properties.

In the technological studies, two types of water glass with different values of the silica modulus and density, designated as R145 and R150,

were used. Moulding sands were prepared with the additive "B". For comparison, reference sands with water glass but without the additive

"B" were also made. In Part I of the article, the results of studies of the effect of additive "B" on the properties of foundry sands with water

glass hardened by CO2 blowing were discussed.

The effects of silica additive (Poraver) on selected properties of BioCo3 binder in form of an aqueous poly(sodium acrylate) and dextrin (PAANa/D) binder were determined. Based on the results of the thermoanalytical studies (TG-DTG, FTIR, Py-GC/MS), it was found that the silica additive results in the increase of the thermostability of the BioCo3 binder and its contribution does not affect the increase in the level of emissions of organic destruction products. Compounds from group of aromatic hydrocarbons are only generated in the third set temperature range (420-838°C). The addition of silicate into the moulding sand with BioCo3 causes also the formation of a hydrogen bonds network with its share in the microwave radiation field and they are mainly responsible for maintaining the cross-linked structures in the mineral matrix system. As a consequence, the microwave curing process in the presence of Poraver leads to improved strength properties of the moulding sand (���� �� ). The addition of Poraver's silica to moulding sand did not alter the permeability of the moulding sand samples, and consequently reduced their friability. Microstructure investigations (SEM) of microwave-cured samples have confirmed that heterogeneous sand grains are bonded to one another through a binder film (bridges).

Additive manufacturing (AM) is a process that joins similar or dissimilar materials into application-oriented objects in a wide range of sizes and shapes. This article presents an overview of two additive manufacturing techniques; namely Laser metal deposition (LMD) and Wire arc additive manufacturing (WAAM). In LMD, metallic powders are contained in one or more chambers, which are then channelled through deposition nozzles. A laser heats the particles to produce metallic beads, which are deposited in layers with the aid of an in-built motion system. In WAAM, a high voltage electric arc functions as the heat source, which helps with ensuring deposition of materials, while materials in wire form are used for the feedstock. This article highlights some of the strengths and challenges that are offered by both processes. As part of the authors’ original research work, ­Ti-6Al-4V, Stainless steel 316L and Al-12Si were prepared using LMD, while the WAAM technique was used to prepare two Al alloys; Al-5356 and CuAl8Ni2. Microstructural analysis will focus on similarity and differences in grains that are formed in layers. This article will also offer an overall comparison on how these samples compare with other materials that have been prepared using LMD and WAAM.

Thermal/cold spray deposition were used for additive manufacture of oxide dispersion strengthened (ODS) steel layers. Mechanically alloyed F/M ODS steel powders (Fe(bal.)-10Cr-1Mo-0.25Ti-0.35Y2O3 in wt.%) were sprayed by a high velocity oxygen fuel (HVOF) and cold spray methods. HVOF, as a thermal method, was used for manufacturing a 1 mm-thick ODS steel layer with a ~95% density. The source to objective distance (SOD) and feeding rate were controlled to achieve sound manufacturing. Y2Ti2O7 nano-particles were preserved in the HVOF sprayed layer; however, unexpected Cr2O3 phases were frequently observed at the boundary area of the powders. A cold spray was used for manufacturing the Cr2O3-free layer and showed great feasibility. The density and yield of the cold spray were roughly 80% and 45%, respectively. The softening of ODS powders before the cold spray was conducted using a tube furnace of up to 1200°C. Microstructural characteristics of the cold sprayed layer were investigated by electron back-scattered diffraction (EBSD), the uniformity of deformation amount inside powders was observed.

The method of a phase shift angle measurement using conditional averaging of delayed signal absolute value (CAAV) is presented in this paper. The input sinusoidal signal x(t) is without noise. White noise with normal distribution and band limited to low frequencies has been applied as disturbance of delayed sinusoidal signal z(t). Noise n(t) - N(0, σn) is added to the delayed signal - the noised and delayed signal z(t) is obtained. The phase angle shift is proportional to time location of CAAV's minimum (minimum of the characteristic of conditional averaging of delayed signal's absolute value). The phase angle shift can be determined on the basis of conditional averaging value of elaborated algorithm. The characteristics of conditional average of delayed signal's absolute value in the surrounding of the minimum of this function (the results of practical investigations and theoretical calculation) are presented. The experimental variance of characteristic CAAV in surroundings of the minimum (obtained from practical investigations and calculation) is illustrated in the paper. The algorithms of conditional averaging have been elaborated and practically realized in the LabVIEW environment.

The paper deals with analysis of samples made of Inconel 718 nickel superalloy, produced using direct metal laser sintering (DMLS), known as “sintering”, and precision casting technologies. The theoretical part is focused on the characteristics of producing samples of the nickel superalloy by modern additive methods (those for processing metallic materials) and by the conventional technology of precision casting. The practical part involves the investigation of the mechanical properties and texture of the surfaces of the tested samples. A significant part of this study is devoted to analysis of fracture surfaces and EDX experimental testing of TEM lamella by using of electron microscopy methods. The conclusions of this paper include a discussion, evaluation and explanation of both technologies applied on tested samples. Finally, the main benefits of using modern additive technologies in the design and production of heat-resistant components of turbochargers are discussed.

The purpose of the present paper was to investigate the effect of shot peening on the condition of the surface layer and abrasion resistance of specimens made of Ti-6Al-4V titanium alloy produced by Direct Metal Laser Sintering (DMLS) process. The specimens have been produced by means of EOSINT M280 system dedicated for laser sintering of metal powders and their surfaces have been subjected to the shot peening process under three different working pressures (0.2, 0.3 and 0.4 MPa) and by means of three different media i.e. CrNi steel shot, crushed nut shells and ceramic balls. The specimens have been subjected to profilometric analysis, to SEM examinations, microhardness tests and to tribological tests on ball-on-disc stand in Ringer fluid environment. The general results of all tests indicate to favourable effect of shot peening process on the hardness and tribological performance of titanium alloy.

The aim of this paper was to attain defect free, pure copper castings with the highest possible electrical conductivity. In this connection, the effect of magnesium additives on the structure, the degree of undercooling (ΔTα = Tα-Tmin, where Tα – the equilibrium solidification temperature, Tmin – the minimum temperature at the beginning of solidification), electrical conductivity, and the oxygen concentration of pure copper castings have been studied. The two magnesium doses have been investigated; namely 0.1 wt.% and 0.2 wt.%. A thermal analysis was performed (using a type-S thermocouple) to determine the cooling curves. The degree of undercooling and recalescence were determined from the cooling and solidification curves, whereas the macrostructure characteristics were conducted based on a metallographic examination. It has been shown that the reaction of Mg causes solidification to transform from exogenous to endogenous. Finally, the results of electrical conductivity have been shown as well as the oxygen concentration for the used Mg additives.

This paper deals with the amplitude estimation in the frequency domain of low-level sine waves, i.e. sine waves spanning a small number of quantization steps of an analog-to-digital converter. This is a quite common condition for high-speed low-resolution converters. A digitized sine wave is transformed into the frequency domain through the discrete Fourier transform. The error in the amplitude estimate is treated as a random variable since the offset and the phase of the sine wave are usually unknown. Therefore, the estimate is characterized by its standard deviation. The proposed model evaluates properly such a standard deviation by treating the quantization with a Fourier series approach. On the other hand, it is shown that the conventional noise model of quantization would lead to a large underestimation of the error standard deviation. The effects of measurement parameters, such as the number of samples and a kind of the time window, are also investigated. Finally, a threshold for the additive noise is provided as the boundary for validity of the two quantization models

In the present study, a titanium cellular lattice structure with a mathematical designed porosity gradient was successfully fabricated using the selective laser melting method. The samples with smooth gradient transition of porosity of between 60% and 80% were received for different elementary cell geometries. Elementary cells belong to the triply periodic minimal surfaces family (G, D, I2Y, IWP). Each sample was subjected to a comprehensive analysis including: dimensional metrology and assessment of material defects (X-ray micro-tomography), surface morphology tests (scanning electron microscopy) and mechanical properties (universal testing machine). It has been shown that a cellular lattice with high dimensional accuracy (+0.16/–0.08 mm) and full dense struts can be obtained. According to the assumption, the gradient increases the strength of the cellular lattice samples. The highest increase in plateau stress between the samples with and without gradient was found for the I2Y series (about 185%). Furthermore, it was found that the stress-strain response of the samples depends not only on total porosity, but also on the 3D geometry of the cellular lattice. The stress-strain curves for G, IWP and I2Y samples are smooth and exhibit three characteristic regions: linear elasticity, plateau region and densification region. The size of regions depends on the geometric features of the cellular lattice. For series D, in the plateau region, the fluctuations in stress value are clearly visible. The smoothest stress-strain curve can be noted for the G series, which combined with good mechanical properties (the plateau stress and energy absorbed, at respectively 25.5 and 43.2 MPa, and 46.3J and 59.5J for Gyr_80 and Gyr_6080, which corresponds to a strain of almost 65% and 50%) positively affects the applicability of cellular structures with such geometry.

Food additives, especially E numbers, are widely perceived by consumers as artificial and harmful. However, the fact is that they are an essential ingredient in numerous products, many have “natural” origins and none of them pose a risk to health.

Effect of Cu addition on oxide growth of Al-7 mass%Mg alloy at high temperature was investigated. As-cast microstructures of Al-7 mass%Mg and Al-7 mass%Mg-1 mass%Cu alloys showed α-Al dendrites and area of secondary particles. The 1 mass%Cu addition into Al-7 mass%Mg alloy formed Mg32(Al, Cu)49 ternary phase with β-Al3Mg2. The total fraction of two Mg-containing phases in Cu-added alloy was higher than the β-Al3Mg2 fraction in Cu-free alloy. From measured weight gains depending on time at 500°C under an air atmosphere, it was shown that all samples exhibited significant weight gains depending on time. Al-7mass%Mg-1mass%Cu alloy showed the relatively increased oxidation rate when compared with Cu-free alloy. All the oxidized cross-sections throughout the entire oxidation time showed coarse and dark areas regarded as oxides grown from the surface to inside, but bigger oxidized areas were formed in the Al-7mass%Mg-1mass%Cu alloy containing higher fraction of Mg-based phases in the as-cast microstructure. As a result of compositional analysis on the oxide clusters, it was found that the oxide clusters contained Mg-based oxides formed through internal oxidation during a long time exposure to oxidizing environments.

Influence of Si addition on oxide layer growth of Al-6 mass%Mg alloys in molten state was investigated in this study. After melt holding for 24 h, the melt surface of only Si-free alloy became significantly bumpy, while no considerably oxidized surface was observed even with 1 mass%Si addition. There was no visible change on the appearance of melt surfaces with increasing Si content. As a result of compositional analysis on the melt samples between before and after melt holding, the Si-added alloys nearly maintained their Mg contents even after the melt holding for 24 h. On the other hand, the Mg content in the Si-free alloy showed a great reduction. The bumpy surface on Si-free alloy melt showed a large amount of pores and oxide clusters in its cross-section, while the Si-added alloy had no significantly grown oxide clusters on the surfaces. As a result of compositional analysis on the surfaces, the oxide clusters in Si-free alloy contained a great amount of Mg and oxygen. The oxide layer on the Si-added alloy was divided into Mg-rich and Mg-poor areas and contained certain amounts of Si. Such a mixed oxide layer containing Si would act as a protective layer during the melt holding for a long duration.

This paper presents the results of a metrological analysis of the additively manufactured (AM) copies of a complex geometrical object, namely the fossil skull of Madygenerpeton pustulatum. This fossil represents the unique remains of an extinct “reptiliomorph amphibian” of high importance for palaeontological science. For this research, the surface was scanned and twelve different copies were 3D-printed using various devices, materials, and AM techniques. The same digitized model was used as a reference to compare with the surfaces obtained by Mitutoyo Coordinate Measuring Machine (CMM) CRYSTA-Apex S 9166 for each copy. The fidelity of the copies was assessed through statistical analysis of the distances between compared surfaces. The methodology provided a good background for the choice of the most accurate copies and the elimination of the less accurate ones. The proposed approach can be applied to any object of complex geometry when reproduction accuracy is to be assessed.

The aim of the paper was to analyse the possibility to use waste material which is created during the production of mineral-asphalt mixes as a side effect of the process of drying and dedusting diabase aggregate in high temperature. Experimental studies included the analysis of the influence of the addition of diabase dust on the improvement of the properties of cement concrete destined for the construction of local roads. The mineral additive in the form of diabase dust, which constitutes natural waste, was inserted into the concrete mix as a mineral additive substituting a part of the aggregate with the constant amount of cement and water, and additionally as the substitute for cement. The performed studies resulted in the conclusion that adding diabase dust significantly increased the tightness and density of concrete, which impacts the increase of compressive strength by 7, 21 and 28% in reference to model concrete. The insertion of the waste diabase dust into the concrete mix significantly improved the freeze-thaw resistance of concrete after 150 cycles of testing and reduced the water absorption by 6, 15 and 21%. Using diabase dust as a substitute in the following amount: 50, 100 and 150 kg/m3 did not cause significant changes in the scope of density and water absorption, whereas the reduction of the compressive strength was from 8, 23 and 33% in reference to the model concrete. The application of dust as the substitute for cement resulted in the reduction of the costs of concrete by 6, 12 and 18% and resulted in the possibility to fully apply waste material, which confirms the justness of undertaking implementation research. Concrete with the use of waste rock dusts may be qualified as concrete that is environmentally friendly and compliant with the sustainable development of modern construction materials.

The advancement of contemporary internal combustion engine technologies necessitates not only design enhancements but also the exploration of alternative fuels or fuel catalysts. These endeavors are integral to curbing the emission of hazardous substances in exhaust gases. Most contemporary catalyst additives are of complex chemical origins, introduced into the fuel during the fuel preparation stage. Nonetheless, none of these additives yield a significant reduction in fuel consumption. The research endeavors to develop the fuel system of a primary marine diesel engine to facilitate the incorporation of pure hydrogen additives into diesel fuel. Notably, this study introduces a pioneering approach, employing compressed gaseous hydrogen up to 5 MPa as an additive to the principal diesel fuel. This method obviates the need for extensive modifications to the ship engine fuel equipment and is adaptable to modern marine power plants. With the introduction of modest quantities of hydrogen into the primary fuel, observable shifts in the behavior of the fuel equipment become apparent, aligning with the calculations outlined in the methodology. The innovative outcomes of the experimental study affirm that the mass consumption of hydrogen is contingent upon the hydrogen supply pressure, the settings of the fuel equipment, and the structural attributes of the fuel delivery system. The modulation of engine load exerts a particularly pronounced influence on the mass admixture of hydrogen. The proportion of mass addition of hydrogen in relation to the pressure of supply (ranging from 4–12 MPa) adheres to a geometric progression (within the range of 0.04–0.1%). The application of this technology allows for a reduction in the specific fuel consumption of the engine by 2–5%, contingent upon the type of fuel system in use, and concurrently permits an augmentation in engine power by up to 5%. The resultant economic benefits are estimated at 1.5–4.2% of the total fuel expenses. This technology is applicable across marine, automotive, tractor, and stationary diesel engines. Its implementation necessitates no intricate modifications to the engine design, and its utilization demands no specialized skills. It is worth noting that, in addition to hydrogen, other combustible gases can be employed.

Computational intelligence (CI) can adopt/optimize important principles in the workflow of 3D printing. This article aims to examine to what extent the current possibilities for using CI in the development of 3D printing and reverse engineering are being used, and where there are still reserves in this area. Methodology: A literature review is followed by own research on CI-based solutions. Results: Two ANNs solving the most common problems are presented. Conclusions: CI can effectively support 3D printing and reverse engineering especially during the transition to Industry 4.0. Wider implementation of CI solutions can accelerate and integrate the development of innovative technologies based on 3D scanning, 3D printing, and reverse engineering. Analyzing data, gathering experience, and transforming it into knowledge can be done faster and more efficiently, but requires a conscious application and proper targeting.

This study investigated the improvement in the electrical conductivity and mechanical properties obtained by adjusting the amount of the Sr addition to the Al-Zn-Mg-Mn alloy. The addition of Sr formed an intermetallic compounds, and the volume fraction of the intermetallic compounds increased with increasing Sr content. As the amount of Sr added increased from 0 to 1.0 wt%, the electrical conductivity of the extruded alloy decreased to 48.9, 45.2 and 42.5% IACS. As the addition amount of Sr increased, the average grain size of the rolled alloy decreased to 55.5, 53.1 and 42.3 μm. And, the ultimate tensile strength increased to 195, 212 and 216 MPa.

Article presents results of laser overlaying welding of metal powder Inconel 625. Laser metal deposition by laser engineered net shaping (LENS) is modern manufacturing process for low scale production series. High alloy materials such as Inconel 625 nickel based super alloy have high thermal resistant and good mechanical properties, nevertheless it's hard to machining. Plastic forming of high alloy materials such as Inconel 625 are difficult. Due to high strength characteristic performing components made from Inconel alloy are complex, selective melting of metallic powder using laser beam are alternative method for Inconel tooling. Paper present research of additive deposition of spatial structure made from Inconel 625 metallic powder with CO2 laser and integrated powder feeder. Microstructure analysis as well as strength characteristic in normal condition and at elevated temperature was performed. Possibility of using LENS technology for manufacturing components dedicated for work in high temperature conditions are presented.

In this study, we propose a cooling structure manufactured using a specialized three-dimensional (3D) printing design method. A cooling performance test system with complex geometry that used a thermoelectric module was manufactured using metal 3D printing. A test model was constructed by applying additive manufacturing simulation and computational fluid analysis techniques, and the correlation between each element and cooling efficiency was examined. In this study, the evaluation was conducted using a thermoelectric module base cooling efficiency measurement system. The contents were compared and analyzed by predicting the manufacturing possibility and cooling efficiency, through additive manufacturing simulation and computational fluid analysis techniques, respectively.

Along with the increase in popularity of the sewage sludge thermal treatment methods in Poland

resulting from the implementation of European Union law, a management problem with ash, which is produced

as a result of this process, appeared. The paper analyses the chemical composition and physical properties of fl y

ash from thermal treatment of municipal sewage sludge in terms of its use in concrete technologies in relation to

EN 450-1 Fly ash for concrete. Defi nition, specifi cations and conformity criteria (2012) and EN 197-1 Cement.

Composition, specifi cations and conformity criteria for common cements (2011) standards. The tested material did

not meet the requirements related to use of fl y ash for concrete production (chemical composition, low activity

index, high water demand and fi neness), and as main and minor components for cement production. On the basis

of the carried out research and analyses, it was found that the hardening slurry technology creates the greatest

possibilities related to the management of fl y ash from thermal treatment of municipal sewage sludge.

Steel and cast-iron products, due to their low price and beneficial properties, are the most widely used among metals; their consumption has become an indicator of the economic development of countries. The characteristics of iron raw materials, in relation to current metallurgical requirements, are presented in the present this article. The globalization of the trade and development of steelmaking technologies have caused significant changes in the quality of raw materials in the last half-century forcing improvements in processing technologies. In many countries, standard concentrates (at least 60% Fe) are almost twice as rich as those processed in the mid-20th century. Methods of quality assessment have been improved and quality standards tightened.

The quality requirements for the most important raw materials ‒ iron ores and concentrates, steel scrap, major alloy metals, coking coal, and coke, as well as gas and other energy media ‒ are reviewed in the present paper. Particular attention is paid to the quality testing methodology. The quality of many raw materials is evaluated multi-parametrically: both chemical and physical characteristics are important. Lower-quality parameters in raw materials equate to significantly lower prices obtained by suppliers in the market.

The markets for these raw materials are diversified and governed by separate sets of newly introduced rules. Price benchmarks (e.g. for standard Australian metallurgical coal) or indices (for iron concentrates) apply. Some raw materials are quoted within the framework of the commodity market system (certain alloying components and steel scrap). The abandonment of the long-established system of multi-annual contracts has led to wide fluctuations in prices, which have reached a scale similar to that of other metals.