Zinc oxide is considered an outstanding photocatalyst candidate, but its low photo-corrosion resistance is a problem to be solved. In the ZnO-ZnS core-shell structure, ZnS acts as a protective layer for the ZnO core, and thus, it can enhance stability and long-term performance. The ZnO-ZnS core-shell structure is synthesized into various nanoscale morphologies with high specific surface areas to improve photocatalytic efficiency. However, they are easily agglomerated and are hard to separate from reaction media. In this study, micro-sized bumpy spheres of ZnO-ZnS core-shell structure were prepared via facile chemical transformation of as-prepared ZnO. After sulfurization of the ZnO template, it was confirmed through SEM, TEM, EDS, and XPS analysis that a uniform ZnS shell layer was formed without significant change in the initial ZnO morphology. The ZnO-ZnS core-shell microsphere has shown superior efficiency and stability in the photocatalytic degradation of Rhodamine B compared with pristine ZnO microspheres

ZnS-based mechanoluminescent film has been widely used in the fields of stress visualization and stress sensing, due to its high brightness and repeatable stable luminescent characteristics. To evaluate the flexibleelastic deformation performance of ZnS-based mechanoluminescent film, both visual inspection and digital image correlation (DIC) are, respectively, employed for measuring the ZnS-based mechanoluminescent film. ZnS:Cu ²⁺ mechanoluminescent powders are first mixed with polydimethylsiloxane (PDMS) matrix to produce ZnS:Cu ²⁺–PDMS mechanoluminescent film. Then, two measurement experiments are, respectively, conducted to investigate the mechanical response and the flexible-elastic deformation performance of the prepared ZnS:Cu2+–PDMS mechanoluminescent film. On one hand, the mechanical response performance of the ZnS:Cu ²⁺–PDMS mechanoluminescent film is validated by visual monitoring of composite concrete fracture processes. On the other hand, the prepared ZnS:Cu ²⁺–PDMS mechanoluminescent film is also measured by DIC to obtain its full-field deformations and strains information. The flexible-elastic deformation performance of the ZnS:Cu ²⁺–PDMS mechanoluminescent film is well demonstrated by the DIC measured results.