Progress in UV treatment applications requires new compact and sensor constructions. In the paper a hybrid (organic-inorganic) rare-earth-based polymeric UV sensor construction is proposed. The efficient luminescence of poly(methyl) methacrylate (PMMA) matrix doped by europium was used for testing the optical sensor (optrode) construction. The europium complex assures effective luminescence in the visible range with well determined multi-peak spectrum emission enabling construction of the optrode. The fabricated UV optical fibre sensor was used for determination of Nd:YAG laser intensity measurements at the third harmonic (355 nm) in the radiation power range 5.0-34.0 mW. The multi-peak luminescence spectrum was used for optimization of the measurement formula. The composition of luminescent peak intensity enables to increase the slope of sensitivity up to −2.8 mW-1. The obtained results and advantages of the optical fibre construction enable to apply it in numerous UV detection systems.
The influence of ambient solar UV-A or UV-B radiation on growth responses was investigated in three varieties of cotton (Gossypium hirsutum L.) after exclusion of solar UV-A/B radiation: JK-35, IH-63 and Khandwa-2. Cotton plants were grown from seeds in UV-exclusion chambers lined with selective UV filters to exclude either UV-B (280-315 nm) or UV-A/B (280-400 nm) from the solar spectrum under field conditions. Excluding UV-B and UV-A/B significantly increased plant height, leaf area and dry weight accumulation in all three varieties of cotton. The varieties differed considerably in their sensitivity to ambient UV-A/B. Khandwa-2 was most sensitive and JK-35 least sensitive to ambient solar UV. We monitored the activity of the antioxidant enzymes superoxide dismutase (SOD), ascorbic acid peroxidase (APX), glutathione reductase (GR) and guaiacol peroxidase (GPX), as well as the level of the antioxidant ascorbic acid (ASA), in primary leaves of the most UV-sensitive variety (Khandwa-2). The level of UV-B-absorbing substances was significantly decreased by exclusion of solar UV-B and UV-A/B. Exclusion of solar UV decreased the activity of all the antioxidant enzymes monitored and the level of ascorbic acid versus control plants (+UV-A/B) grown under filters transparent to solar UV. Reduction of the antioxidant defense after UV exclusion indicates that ambient solar UV exerts significant stress and induces some reactive oxygen species to accumulate, which in turn retards the growth and development of cotton plants. Ambient solar UV stresses cotton plants, shifting their metabolism towards defense against solar UV. Exclusion of solar UV eliminates the need for that defense and leads to enhancement of primary metabolism.
The shipment of cut flowers from Colombia and Ecuador to the United States, the biggest importer of this product in the world, has doubled in the last 20 years. One of the main constraints in cut roses production is the gray mold disease caused by the fungus Botrytis cinerea, which can destroy the flowers, in the crop, during storage and/or shipping. Since the resistance of the fungus to conventional fungicides has been increasing, as well as the health effects in rose growers, alternative approaches for controlling the disease are needed. The effect of UV-C light on the gray mold development in cut roses was studied. Irradiation with 2,160; 1,080 and 540 J ⋅ m–2 UV-C, every 24 h for 5 days in a humid chamber, did not harm the roses. Instead, as seen by image analysis, a highly significant reduction of the area of the lesions by the disease and of the fungus germination was obtained at 1,080 J ⋅ m–2. The addition of a 4-h dark period to the irradiation did not improve the effect of UV-C on the disease. The results of this work potentiate the use of UV-C light in the agro-industry as a low-cost and non-invasive alternative method to control diseases. They also reflect the application of optical approaches as image analysis in the evaluation of important agricultural features.
The objective of the paper is to use life cycle assessment to compare environmental impact of different technologies used in the process of water disinfection. Two scenarios are developed for water disinfection life cycle at ZUW Raba water treatment plant: (1) historical, in which gaseous chlorine is used as a disinfectant and (2) actual, in which UV radiation and electrolytically generated sodium hypochlorite are used for that purpose. Primary data is supplemented with ecoinvent 3 database records. Environmental impact is assessed by IMPACT2002+ method and its midpoint and endpoint indicators that are calculated with the use of SimaPro 8.4 software. The focus of the assessment is on selected life cycle phases: disinfection process itself and the water distribution process that follows. The assessment uses the data on flows and emissions streams as observed in the Raba plant. As the results of primal analysis show, a change of disinfectant results in quantitative changes in THMs and free chlorine in water supplied to the water supply network. The results of analysis confirm the higher potential of THMs formation and higher environmental impact of the combined method of UV/NaClO disinfection in distribution phase and in whole life cycle, mainly due to the increase of human toxicity factors. However, during the disinfection phase, gaseous chlorine use is more harmful for environment. But the final conclusion states that water quality indicators are not significant in the context of LCA, while both disinfection and distribution phases are concerned.
The possibility of removing organic compounds from wastewater originating from the photochemical production of printed circuit boards by use of waste acidification and disposal of precipitated photopolymer in the first stage and the UV-Fenton method in a second stage has been presented. To optimize the process of advanced oxidation, the RSM (Response Surface Methodology) for three independent factors was applied, i.e. pH, the concentration of Fe(II) and H2O2 concentration. The use of optimized values of individual parameters in the process of wastewater treatment caused a decrease in the concentration of the organic compounds denoted as COD by approx. 87% in the first stage and approx. 98% after application of both processes. Precipitation and the decomposition of organic compounds was associated with a decrease of wastewater COD to below 100 mg O2/L whereas the initial value was 5550 mg O2/L. Decomposition of organic compounds and verification of the developed model of photopolymers removal was also carried out with use of alternative H2O2 sources i.e. CaO2, MgO2, and Na2CO3·1,5H2O2.
The spectroscopic FT-IR and FT-Raman methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic
acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) applied as a binder for moulding sands (as a novel group binders BioCo). The
cross-linking was performed by physical agent, applying the UV-radiation. The results of structural studies (IR, Raman) confirm the
overlapping of the process of cross-linking polymer composition PAA/CMS-Na in UV radiation. Taking into account the ingredients and
structure of the polymeric composition can also refer to a curing process in a binder - mineral matrix mixture. In the system of bindermineral
matrix under the influence of ultraviolet radiation is also observed effect of binding. However, the bonding process does not occur
in the entire volume of the investigated system, but only on the surface, which gives some possibilities for application in the use of UV
curing surface of cores, and also to cure sand moulds in 3D printing technology
In experiments with short-pulse lasers the measurement control of the energy of the laser pulse is of crucial importance. Generally it is difficult to measure the amplitude of the pulses of short-pulse lasers using electronic devices, their response time being longer than the duration of the laser pulses. The electric response of the detector is still too fast to be directly digitized therefore a peak-hold unit can be used to allow data processing for the computer. In this paper we present a device which measures the energy of UV short (fs) pulses shot-byshot, digitizes and sends the data to the PC across an USB interface. The circuit is based on an analog peak detect and hold unit and the use of fiber optical coupling between the PC and the device provides a significant improvement to eliminate potential ground loops and to reduce conductive and radiated noise as well. The full development is open source and has been made available to download from our web page (http://www.noise.inf.u-szeged.hu/Instruments/PeakHold/).
The increasing demands for miniaturization and better functionality of electronic components and devices have a significant effect on the requirements facing the printed circuit board (PCB) industry. PCB manufactures are driving for producing high density interconnect (HDI) boards at significantly reduced cost and reduced implementation time. The interconnection complexity of the PCB is still growing and today calls for 50/50 μm or 25/25 μm technology are real. Existing technologies are unable to offer acceptable solution. Recently the Laser Direct Imaging (LDI) technology is considered as an answer for these challenges. LDI is a process of imaging electric circuits directly on PCB without the use of a phototool or mask. Our laboratory system for Laser Direct Imaging is designed for tracks and spaces on PCB with minimum width distance of 50/50 μm. In comparison with conventional photolithography method, this technology is much better for 50/50 μm track and spaces. In our research we used photoresist with resolution 50 μm, but in case of using laser photoresists with better resolution (e.g. 25 μm) it will be possible to image tracks in super-fine-line technology (25/25 μm). The comparison between two technology of creating mosaic pattern tracks on PCB proved that laser imaging is promising technology in high density interconnects patterns, which are widely use in multilayered PCB and similar applications.
This study examined the effects of UV-B radiation and allelochemical stress induced by ferulic acid (FA) on the activity of phenylalanine ammonia lyase (PAL; EC 4.3.1.5) at metabolic and molecular levels in two cucumber genotypes differing in tolerance to cold and disease, in order to determine any interaction between stress effects and genotype response. Stresses were applied simultaneously, sequentially, and singly. In both genotypes, several days of UV radiation retarded growth up to 36%. The effect of FA was not significant. The response to a particular stress, including the effect on PAL activation, was enhanced by simultaneous application of the two stresses. PAL transcription was not correlated with the increase of PAL activity. Exposure to UV-B, FA, and combined UV-B and FA was detrimental to both genotypes but to different extents. The response was not correlated with the genotype of cold and disease sensitivity. PAL activity and its transcription seem to be involved in UV and allelochemical stress, but not related to the plants' tolerance of these stresses.
Transparent Al doped ZnO nanocrystalline films with a crystallite size less than 19 nm are obtained by spray pyrolysis. Band gap increases monotonically from 3.16 to 3.31 eV with increasing aluminum dopant up to 1.56 at.% facilitating increasing width of a transmission window in addition to the band gap tuning of 4.74% which compares favorably well with literature. UV emission with continuously increasing intensity is obtained which reflects on the good crystalline quality of the films. Also the defect emissions are suppressed remarkably as the dopant Al concentration increases in ZnO. The band gap tuning by quite small increment in dopant amount makes the present films, much attractive for the fabrication of light emitting devices with a much sought-for benefit of large area fabrication. FESEM shows the surface is granular with grain size lying in the range of 20–35 nm and EDX confirms the presence of Al in the doped samples.