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Abstract

The polycyclic musk fragrances AHTN (Tonalide) and HHCB (Galaxolide) are the most common components of cosmetics and detergents. Use of AHTN and HHCB per year (in the USA and in EU) was estimated at 1500 Mg and 3800 Mg, respectively. Because of their persistent character, musk compounds are introduced into environment mostly via urban sewage treatment plant effluents. The aim of the presented research was to assess the receptivity of AHTN and HHCB to the oxidation by means of UV-radiation and in the UV /H2O2 process. The investigations were performed in the treated wastewater and the drinking water. After 8 minutes, in all experiments performed on drinking water, the degradations of AHTN and HHCB in the range of 99% were observed. The removal of HHCB from wastewater by means of UV radiation exceeded up 93% (after 8 minutes of the process), whereas the disappearance degree of this compound in wastewater, after only 3 minutes ofUV/H2O2 process, exceeded 99%. The degradation constant rate for AHTN in drinking water using UV radiation was equal to 0.764 rnin' when the degradation rate ofHHCB was estimated at 0.634 min'. In the wastewater, the coefficient rate ofHHCB degradation by means ofUV/H2O2 was nearly 4.5 times higher (1.580 min') in comparison to the value obtained by direct photolysis of HHCB (0.354 min').
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Authors and Affiliations

Ewa Felis
Alfredo C. Alder
Joanna Surmacz-Górska
Korneliusz Miksch
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Abstract

Prolonged exposure to UV radiation, and ever-increasing life expectancy, mean that an increasing proportion of the population suffers from clouding of the intraocular lens. Nowadays, the performance of intraocular implantation procedures is commonplace. Unfortunately, with the increasing number of operations, the number of postoperative complications is also increasing. One way to avoid complications may be to use an intraocular implant that has been immersed in a solution containing silver nanoparticles. As part of the study, four selected intraocular implants – that are available on the ophthalmic market – were tested. In order to investigate the effect of silver particles on the optical properties of the implants, tests were carried out using a UV-VIS spectrophotometer. Two series of implants were tested: before and after immersion in a silver solution. The implants were immersed for a period of 7 days. It was found that the presence of silver particles does not have a negative impact on the translucency of the implants.
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Authors and Affiliations

K. Jeż
1
ORCID: ORCID
M. Gacek
1
ORCID: ORCID
M. Nabiałek
1
ORCID: ORCID
L. Toth
2
ORCID: ORCID
M. Pike-Biegunski
3

  1. Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Department of Physics, 19 Armii Krajowej Str., 42-200 Częstochowa, Poland
  2. Óbuda University, Bánki Donát Faculty of Mechanical and Safety Engineering, Material Science Department, 1081, Népszínház 8, Budapest, Hungary
  3. Nano Koloid sp. z o. o, Hoża 62/37, 00-682 Warszawa, Poland
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Abstract

Progress in UV treatment applications requires new compact and sensor constructions. In the paper a hybrid (organic-inorganic) rare-earth-based polymeric UV sensor construction is proposed. The efficient luminescence of poly(methyl) methacrylate (PMMA) matrix doped by europium was used for testing the optical sensor (optrode) construction. The europium complex assures effective luminescence in the visible range with well determined multi-peak spectrum emission enabling construction of the optrode. The fabricated UV optical fibre sensor was used for determination of Nd:YAG laser intensity measurements at the third harmonic (355 nm) in the radiation power range 5.0-34.0 mW. The multi-peak luminescence spectrum was used for optimization of the measurement formula. The composition of luminescent peak intensity enables to increase the slope of sensitivity up to −2.8 mW-1. The obtained results and advantages of the optical fibre construction enable to apply it in numerous UV detection systems.

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Authors and Affiliations

Piotr Miluski
Marcin Kochanowicz
Jacek Żmojda
Dominik Dorosz
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Abstract

The application of micro components in various fields such as biomedical, medical, automobile, electronics, automobile and aviation significantly improved. To manufacture the micro components, different techniques exist in the non-traditional machining process. In those techniques, electrochemical micromachining (ECMM) exhibits a unique machining nature, such as no tool wear, non-contact machining process, residual stress, and heat-affected zone. Hence, in this study, micro holes were fabricated on the copper work material. The sodium nitrate (NaNO₃) electrolyte is considered for the experiments. During the experiments, magnetic fields strength along with UV rays are applied to the electrolyte. The L₁₈ orthogonal array (OA) experimental design is planned with electrolyte concentration (EC), machining voltage (MV), duty cycle (DC) and electrolyte temperature (ET). The optimization techniques such as similarity to ideal solution (TOPSIS), VlseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR) and grey relational analysis (GRA) were employed to find the optimal parameter combinations. The entropy weight method is used to assess the weight of responses such as MR and OC. The optimal combination using TOPSIS, VIKOR and GRA methods shows the same results for the experimental runs 8, 9 and 7, and the best optimal parameter combination is 28 g/l EC, 11 V MV, 85 % DC and 37°C ET. Based on the analysis of variance (ANOVA) results, electrolyte concentration plays a significant role by contributing 86 % to machining performance. The second and least contributions are DC (3.86 %) and ET (1.74 %) respectively on the performance. Furthermore, scanning electron microscope (SEM) images analyses are carried out to understand the effect of magnetic field and heated electrolyte on the work material.
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Bibliography

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Authors and Affiliations

K.G. Saravanan
R. Thanigaivelan
M. Soundarrajan
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Abstract

The influence of ambient solar UV-A or UV-B radiation on growth responses was investigated in three varieties of cotton (Gossypium hirsutum L.) after exclusion of solar UV-A/B radiation: JK-35, IH-63 and Khandwa-2. Cotton plants were grown from seeds in UV-exclusion chambers lined with selective UV filters to exclude either UV-B (280-315 nm) or UV-A/B (280-400 nm) from the solar spectrum under field conditions. Excluding UV-B and UV-A/B significantly increased plant height, leaf area and dry weight accumulation in all three varieties of cotton. The varieties differed considerably in their sensitivity to ambient UV-A/B. Khandwa-2 was most sensitive and JK-35 least sensitive to ambient solar UV. We monitored the activity of the antioxidant enzymes superoxide dismutase (SOD), ascorbic acid peroxidase (APX), glutathione reductase (GR) and guaiacol peroxidase (GPX), as well as the level of the antioxidant ascorbic acid (ASA), in primary leaves of the most UV-sensitive variety (Khandwa-2). The level of UV-B-absorbing substances was significantly decreased by exclusion of solar UV-B and UV-A/B. Exclusion of solar UV decreased the activity of all the antioxidant enzymes monitored and the level of ascorbic acid versus control plants (+UV-A/B) grown under filters transparent to solar UV. Reduction of the antioxidant defense after UV exclusion indicates that ambient solar UV exerts significant stress and induces some reactive oxygen species to accumulate, which in turn retards the growth and development of cotton plants. Ambient solar UV stresses cotton plants, shifting their metabolism towards defense against solar UV. Exclusion of solar UV eliminates the need for that defense and leads to enhancement of primary metabolism.

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Authors and Affiliations

Sunita Kataria
Priti Dehariya
K.N. Guruprasad
G.P. Pandey
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Abstract

Solar blind UV cameras are not theoretically supposed to be sensitive to solar light. However, there is practically always some sensitivity to solar light. This limited solar sensitivity can sometimes make it impossible to detect the weak emission of a corona target located on the solar background. Therefore, solar sensitivity is one of the crucial performance parameters of solar blind UV cameras. However, despite its importance, the problem of determining solar sensitivity of solar blind UV cameras has not been analysed and solved in the specialized literature, so far. This paper presents the concept (definition, measurement method, test equipment, interpretation of results) of measuring solar sensitivity of solar blind UV cameras.
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Authors and Affiliations

Krzysztof Chrzanowski
1 2
ORCID: ORCID
Bolesław Safiej
2

  1. Military University of Technology, Institute of Optoelectronics, 2 gen. Kaliskiego St., 00-908 Warsaw, Poland
  2. INFRAMET, Bugaj 29a, Koczargi Nowe, 05-082 Stare Babice, Poland
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Abstract

The shipment of cut flowers from Colombia and Ecuador to the United States, the biggest importer of this product in the world, has doubled in the last 20 years. One of the main constraints in cut roses production is the gray mold disease caused by the fungus Botrytis cinerea, which can destroy the flowers, in the crop, during storage and/or shipping. Since the resistance of the fungus to conventional fungicides has been increasing, as well as the health effects in rose growers, alternative approaches for controlling the disease are needed. The effect of UV-C light on the gray mold development in cut roses was studied. Irradiation with 2,160; 1,080 and 540 J ⋅ m–2 UV-C, every 24 h for 5 days in a humid chamber, did not harm the roses. Instead, as seen by image analysis, a highly significant reduction of the area of the lesions by the disease and of the fungus germination was obtained at 1,080 J ⋅ m–2. The addition of a 4-h dark period to the irradiation did not improve the effect of UV-C on the disease. The results of this work potentiate the use of UV-C light in the agro-industry as a low-cost and non-invasive alternative method to control diseases. They also reflect the application of optical approaches as image analysis in the evaluation of important agricultural features.

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Authors and Affiliations

Katherine Vega
Samuel Ochoa
Luis F. Patiño
Jorge A. Herrera-Ramírez
Jorge A. Gómez
Jairo C. Quijano
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Abstract

The objective of the paper is to use life cycle assessment to compare environmental impact of different technologies used in the process of water disinfection. Two scenarios are developed for water disinfection life cycle at ZUW Raba water treatment plant: (1) historical, in which gaseous chlorine is used as a disinfectant and (2) actual, in which UV radiation and electrolytically generated sodium hypochlorite are used for that purpose. Primary data is supplemented with ecoinvent 3 database records. Environmental impact is assessed by IMPACT2002+ method and its midpoint and endpoint indicators that are calculated with the use of SimaPro 8.4 software. The focus of the assessment is on selected life cycle phases: disinfection process itself and the water distribution process that follows. The assessment uses the data on flows and emissions streams as observed in the Raba plant. As the results of primal analysis show, a change of disinfectant results in quantitative changes in THMs and free chlorine in water supplied to the water supply network. The results of analysis confirm the higher potential of THMs formation and higher environmental impact of the combined method of UV/NaClO disinfection in distribution phase and in whole life cycle, mainly due to the increase of human toxicity factors. However, during the disinfection phase, gaseous chlorine use is more harmful for environment. But the final conclusion states that water quality indicators are not significant in the context of LCA, while both disinfection and distribution phases are concerned.

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Authors and Affiliations

Artur Jachimowski
Tomasz Nitkiewicz
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Abstract

The paper presents the results of the analysis of physical phenomena associated with the degradation processes of the surface layer of polymeric materials. During the interaction disturbance of ultraviolet radiation, atoms are knocked out of the polymer chains, thus breaking the macromolecules, which leads to the disturbance in the structural stability of the materials. The standardised test samples obtained using the injection moulding method were subjected to the degradation process in natural and accelerated conditions in the UV Test device. The degradation process in laboratory conditions was carried out during 750 hours with the use of lamps with a wavelength of 313 nanometers and an irradiation level of 0.76 W/m 2, which corresponds to a period of 2 years in natural conditions. Using of thermogravimetric TGA and differential scanning calorimetry DSC analysis, the influence of energy applied from lamps and the energy reaching the earth’s surface on the change of melting enthalpy ∆ Hm, quantitative index of the crystalline phase and the temperature of phase changes were determined.
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Authors and Affiliations

A. Kalwik
1
ORCID: ORCID
P. Postawa
1
ORCID: ORCID

  1. Czestochowa University of Technology, Faculty of Mechanical Engineering and Computer Science, Depa rtment of Technology and Automation, 19C Armii Krajowej Av., 42- 201 Czestochowa, Poland
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Abstract

Antarctica features one of the most ancient, largest glacier reserves and the most pristine environment left on the earth. However, in last few decade disturbances due to industrialization and release of greenhouse gases have led to serious consequences such as melting of polar ice sheets, changing atmospheric chemistry and ozone depletion. Here, we use high-throughput sequencing to understand the impact of subtle changes in environmental parameters on bacterial communities. We observed dominance of Cyanobacteria (41.93%) followed by Bacteroidetes (14.8%), Acidobacteria (13.35%), Proteobacteria (9.67%), Actinobacteria (7.79%), Firmicutes (3.46%) among all the samples collected every alternate day for 20 days. Additionally, metagenomic imputations revealed higher abundance of gene families associated with DNA repair and carotenoid biosynthesis enabling bacterial communities to resist and function under the high UV radiations. We further observed bacterial communities are dependent on the single carbon metabolism as a strategy for nutrient uptake in such nutrient deprived conditions.
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Bibliography


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Authors and Affiliations

Kunal Jani
1
Anoop Mahajan
2
Swapnil Kajale
1
Aditee Ashar
1
Avinash Sharma
1

  1. National Centre for Cell Science, Pune, India
  2. Indian Institute of Tropical Meteorology, Ministry of Earth Sciences, Dr. Homi Bhabha road, Pune 411008, India
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Abstract

Antarctic plants experience UV−B stress and for their survival they have been showing various adaptive strategies. The first line of defence is to screen UV−B radiation before it reaches the cell, then to minimize damage within the cells through other protective strategies, and finally to repair damage once it has occurred. A fifteen days experiment was designed to study lichen: Dermatocarpon sp. and Acarospora gwynnii under natural UV and below UV filter frames in the Indian Antarctic Station Maitri region of Schirmacher Oasis, East Antarctica. Changes in UV absorbing compounds, total phenolics, total carotenoids and chlorophyll content were studied. The change in total phenolics and total carotenoid content was significant in both Dermatocarpon sp. and A. gwynnii indicating that the increase in UV absorbing compounds, total phenolics and total carotenoid content act as a protective mechanism against the deleterious effect of UV−B radiations, whereas the change in chlorophyll content was not significant in both lichen species.
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Authors and Affiliations

Sanghdeep Gautam
Jaswant Singh
Aditya Bhushan Pant
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Abstract

Many of the drugs used arc not completely metabolized in the human body and with urine and faces arc introduced into the sewage system. Finally, due to their incomplete removal during the conventional wastewater treatment process (CWTP), they can be released into the receiving water. One of the medicaments frequently detected in surface water is diclolcnac. The present study addresses the problem of diclofcnac removal in various aquatic samples using advanced oxidation processes (AOPs). The experiments were performed in distilled water and in biologically treated wastewater. The following AO Ps were applied: Fenlon 's reagent, UVand UV/H2O2-processes. The concentration of diclolcnac in distilled water corresponded to the concentration of this drug in human urine (ca. 20 mg-dm'). The real wastewater samples contained diclofcnac concentrations ranging from 630 to 790 ng-dm-'. The photodcgradation of diclolcnac was carried out in the photorcactor with a medium pressure Hg-vapor lamp (400 W). In the Fcnton's reaction different molar ratiosof H2O2/Fc'' were used. The diclotcnac mineralization (TOC removal) strictly depended on the amount of 1-1,0, applied in the Fcnton's reaction. Diclofcnac was rapidly degraded by direct photolysis (UV) and in UV/H2O2,-process both in distilled water and in wastewater samples. The results proved that the advanced oxidation processes arc cflcctive in diclofcnac removal from aquatic samples. The pseudo first order rate constants It)!' diclolcnac photodcgradation were determined.
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Authors and Affiliations

Ewa Felis
Jarosław Wiszniowski
Korneliusz Miksch
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Abstract

The possibility of removing organic compounds from wastewater originating from the photochemical production of printed circuit boards by use of waste acidification and disposal of precipitated photopolymer in the first stage and the UV-Fenton method in a second stage has been presented. To optimize the process of advanced oxidation, the RSM (Response Surface Methodology) for three independent factors was applied, i.e. pH, the concentration of Fe(II) and H2O2 concentration. The use of optimized values of individual parameters in the process of wastewater treatment caused a decrease in the concentration of the organic compounds denoted as COD by approx. 87% in the first stage and approx. 98% after application of both processes. Precipitation and the decomposition of organic compounds was associated with a decrease of wastewater COD to below 100 mg O2/L whereas the initial value was 5550 mg O2/L. Decomposition of organic compounds and verification of the developed model of photopolymers removal was also carried out with use of alternative H2O2 sources i.e. CaO2, MgO2, and Na2CO3·1,5H2O2.

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Authors and Affiliations

Barbara Białecka
Maciej Thomas
Dariusz Zdebik
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Abstract

The spectroscopic FT-IR and FT-Raman methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic

acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) applied as a binder for moulding sands (as a novel group binders BioCo). The

cross-linking was performed by physical agent, applying the UV-radiation. The results of structural studies (IR, Raman) confirm the

overlapping of the process of cross-linking polymer composition PAA/CMS-Na in UV radiation. Taking into account the ingredients and

structure of the polymeric composition can also refer to a curing process in a binder - mineral matrix mixture. In the system of bindermineral

matrix under the influence of ultraviolet radiation is also observed effect of binding. However, the bonding process does not occur

in the entire volume of the investigated system, but only on the surface, which gives some possibilities for application in the use of UV

curing surface of cores, and also to cure sand moulds in 3D printing technology

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Authors and Affiliations

B. Grabowska
A. Bobrowski
K. Kaczmarska
Ż. Kurleto-Kozioł
Ł. Szymański
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Abstract

Rutile-TiO2 nanorod thin films were formed on Ti disks via alkali treatment in NaOH solutions followed by heat treatment at 700°C. Ag nanoparticles were loaded on nanorods using a photo-reduction method to improve the photocatalytic properties of the prepared specimen. The surface characterization and the photo-electrochemical properties of the Ag-loaded TiO2 nanorods were investigated using a field-emission scanning electron microscope (FE-SEM), X-ray photoelectron spectroscopy (XPS), UV-Vis spectroscopy and electrochemical impedance spectroscopy (EIS). The TiO2 nanorods obtained after the heat treatment were 80 to 180 nm thick and 1 μm long. The thickness of the nanorods increased with the NaOH concentration. The UV-Vis spectra exhibit a shift in the absorption edge of the Ag-loaded TiO2 to the visible light range and further narrowing of the bandgap. The decrease in the size of the capacitive loops in the EIS spectra showed that the Ag loading effectively improved the photocatalytic activity of the TiO2 nanorods.
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Authors and Affiliations

Kwangmin Lee
1
ORCID: ORCID
Daeheung Yoo
1 2
Ahmad Zakiyuddin
3
ORCID: ORCID

  1. Chonnam National University, School of Materials Science and Engineering, Gwangju 61186, Republic of Korea
  2. Quality Tech. Dept. Chosun Refractories Co., Ltd, Republic of Korea
  3. Universitas Indonesia, Department of Metallurgical and Materials Engineering, Depok 16425 Indonesia
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Abstract

In experiments with short-pulse lasers the measurement control of the energy of the laser pulse is of crucial importance. Generally it is difficult to measure the amplitude of the pulses of short-pulse lasers using electronic devices, their response time being longer than the duration of the laser pulses. The electric response of the detector is still too fast to be directly digitized therefore a peak-hold unit can be used to allow data processing for the computer. In this paper we present a device which measures the energy of UV short (fs) pulses shot-byshot, digitizes and sends the data to the PC across an USB interface. The circuit is based on an analog peak detect and hold unit and the use of fiber optical coupling between the PC and the device provides a significant improvement to eliminate potential ground loops and to reduce conductive and radiated noise as well. The full development is open source and has been made available to download from our web page (http://www.noise.inf.u-szeged.hu/Instruments/PeakHold/).

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Authors and Affiliations

A. Barna
I.B. Földes
Z. Gingl
R. Mingesz
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Abstract

Due to the difficulty of detecting traces of organic acid mixture in an aqueous sample and the complexity of resolving UV-Vis spectra effectively, a combinatory method based on a self-made radical electric focusing solid phase extraction (REFSPE) device, UV-Vis detection and partial least squares (PLS) calculation is proposed here. In this study, REFSPE was used to enhance the extraction process of analytes between the aqueous phase and the membrane phase to enrich the trace of mixed organic acid efficiently. Then, the analytes, which were eluted from the adsorption film by ethanol with the assistance of an ultrasonic cleaning machine, were detected with UV-Vis spectrophotometry. After that, the PLS method was introduced to solve the problem of overlapping peaks in UV-Vis spectra of mixed substances and to quantify each compound. The linearly dependent coefficients between the predicted value of the model and the actual concentration of the sample were all higher than 0.99. The limit values of detection for benzoic acid, phthalic acid and p-toluene sulfonic acid were found at 9.9 µg/L, 12.2 µg/L and 13.8 µg/L with the relative recovery values between 84.8% and 117.9%. The RSD (n = 20) values of each component are 1.17%, 1.11% and 0.86%, respectively. Therefore, the proposed combined method can determine traces of complex materials in an aqueous sample efficiently and has wonderful potential applications.
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Authors and Affiliations

Guo Yugao
Liu Xia
Liu Jianyi
Bian Xihui
Zhang Qingyin
Pan Jie
Wan Dong
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Abstract

The paper presents a study of the performance of some selected UV detectors. Unlike many similar works, the obtained data refer to commercial photodiodes (not only to detector materials). The main task of the research was to determine the influence of the operating temperature and annealing on the detector spectral responsiveness. A comparison of the results obtained for the photodiodes made of GaN and SiC was also performed. Although both kinds of detectors can work at high temperatures for a long time, some modification of their properties was observed. However, for GaN and SiC photodiodes, this modification has a substantially different nature. It is very important for some applications, e.g. fire alarms and a military equipment.
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Authors and Affiliations

Joanna Ćwirko
Robert Ćwirko
Janusz Mikołajczyk
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Abstract

An active beam-pointing stabilization system has been developed for a high-power KrF laser system to eliminate the long-term drift of the directional change of the beam in order to have a stable focusing to a high intensity. The control of the beam direction was achieved by a motor-driven mirror activated by an electric signal obtained by monitoring the position of the focus of the output beam. Instead of large sized UV-sensitive position sensitive detectors a simple arrangement with scatter plates and photodiodes are used to measure the directionality of the beam. After the beam stabilization the long-term residual deviation of the laser shots is ~14 μrad, which is comparable to the shot-to-shot variation of the beam (~12 μrad). This deviation is small enough to keep the focal spot size in a micrometer range when tightly focusing the beam using off-axis parabolic mirrors.
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Authors and Affiliations

A. Barna
I. B. Földes
J. Bohus
S. Szatmári
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Abstract

The increasing demands for miniaturization and better functionality of electronic components and devices have a significant effect on the requirements facing the printed circuit board (PCB) industry. PCB manufactures are driving for producing high density interconnect (HDI) boards at significantly reduced cost and reduced implementation time. The interconnection complexity of the PCB is still growing and today calls for 50/50 μm or 25/25 μm technology are real. Existing technologies are unable to offer acceptable solution. Recently the Laser Direct Imaging (LDI) technology is considered as an answer for these challenges. LDI is a process of imaging electric circuits directly on PCB without the use of a phototool or mask. Our laboratory system for Laser Direct Imaging is designed for tracks and spaces on PCB with minimum width distance of 50/50 μm. In comparison with conventional photolithography method, this technology is much better for 50/50 μm track and spaces. In our research we used photoresist with resolution 50 μm, but in case of using laser photoresists with better resolution (e.g. 25 μm) it will be possible to image tracks in super-fine-line technology (25/25 μm). The comparison between two technology of creating mosaic pattern tracks on PCB proved that laser imaging is promising technology in high density interconnects patterns, which are widely use in multilayered PCB and similar applications.

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Authors and Affiliations

R. Barbucha
M. Kocik
J. Mizeraczyk
G. Kozioł
J. Borecki
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Abstract

This study examined the effects of UV-B radiation and allelochemical stress induced by ferulic acid (FA) on the activity of phenylalanine ammonia lyase (PAL; EC 4.3.1.5) at metabolic and molecular levels in two cucumber genotypes differing in tolerance to cold and disease, in order to determine any interaction between stress effects and genotype response. Stresses were applied simultaneously, sequentially, and singly. In both genotypes, several days of UV radiation retarded growth up to 36%. The effect of FA was not significant. The response to a particular stress, including the effect on PAL activation, was enhanced by simultaneous application of the two stresses. PAL transcription was not correlated with the increase of PAL activity. Exposure to UV-B, FA, and combined UV-B and FA was detrimental to both genotypes but to different extents. The response was not correlated with the genotype of cold and disease sensitivity. PAL activity and its transcription seem to be involved in UV and allelochemical stress, but not related to the plants' tolerance of these stresses.

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Authors and Affiliations

Anna Jóźwiak-Żurek
Monika Kozłowska
Katarzyna Nuc
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Abstract

Transparent Al doped ZnO nanocrystalline films with a crystallite size less than 19 nm are obtained by spray pyrolysis. Band gap increases monotonically from 3.16 to 3.31 eV with increasing aluminum dopant up to 1.56 at.% facilitating increasing width of a transmission window in addition to the band gap tuning of 4.74% which compares favorably well with literature. UV emission with continuously increasing intensity is obtained which reflects on the good crystalline quality of the films. Also the defect emissions are suppressed remarkably as the dopant Al concentration increases in ZnO. The band gap tuning by quite small increment in dopant amount makes the present films, much attractive for the fabrication of light emitting devices with a much sought-for benefit of large area fabrication. FESEM shows the surface is granular with grain size lying in the range of 20–35 nm and EDX confirms the presence of Al in the doped samples.

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Authors and Affiliations

N. Kumar
A. Srivastava

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