The work presents the results of the investigations of the effect of the nitrogen (N2) refining time „τraf” and the gas output on the course of
the crystallization process, the microstructure and the gassing degree of silumin 226 used for pressure casting. The refinement of the
examined silumin was performed with the use of a device with a rotating head. The crystallization process was examined by way of
thermal analysis and derivative analysis TDA. The performed examinations showed that the prolongation of the N2 refining time causes
a significant rise of the temperature of the crystallization end of the silumin, „tL”, as well as a decrease of its gassing degree, „Z”. An
increase of the nitrogen output initially causes an increase of the temperature „tL” and a drop of the gassing degree „Z”, which reach their
maximal values with the output of 20 dm3
/min. Further increase of the output causes a decrease of the value „tL” and an increase of „Z”.
The examined technological factors of the refining process did not cause any significant changes in the microstructure of silumin 226.
This paper presents the effect of the temperature and hold time in the holding furnace of 226 silumin on the characteristic quantities of
TDA curves. The temperature of phase transformations and the cooling rate were tested.It has been shown that increasing both the hold
time and the temperature in the holdingfurnace cause the decreasethe end ofα+Al9Fe3Si2+β and α+Al2Cu+βternary eutectics
crystallizationtemperature in the tested silumin. This is due to the fact an increase in amounts of impurities as a result of reacting theliquid
alloy with the gases contained in the air.It has been shown, however, that examined technological factors ofthe metal preparation do not
cause systematic changes in the cooling rate.
The paper presents the results of studies of the effect of chromium concentration on the solidification process, microstructure and selected
properties of cast iron with vermicular graphite. The vermicular graphite cast iron was obtained by an Inmold process. Studies covered the
cast iron containing chromium in a concentration at which graphite is still able to preserve its vermicular form. The effect of chromium on
the temperature of eutectic crystallization and on the temperature of the start and end of austenite transformation was discussed. The conditions
under which, at a predetermined chromium concentration, the vermicular graphite cast iron of a pearlitic matrix is obtained were
presented, and the limit concentration of chromium was calculated starting from which partial solidification of the cast iron in a metastable
system takes place. The effect of chromium on the hardness of cast iron, microhardness of individual phases and surface fraction of carbides
was disclosed.
In this paper crystallization studies of low-alloyed construction cast steel were presented for different additions of chromium, nickel and
molybdenum modified with vanadium and titanium. Studies were conducted using developed TDA stand, which additionally enabled
evaluation of cooling rate influence on crystallization process of investigated alloys.
The article presents the investigations of 7xxx aluminium alloys performed by the method of thermal and derivational analysis. The studies made it possible to identify the effect of the changes in the Cu concentration, the total Zn and Mg weight concentrations and the Zn/Mg weight concentration ratio on their crystallization process: the cooling as well as the kinetics and dynamics of the thermal process of cooling and crystallization. Metallographic studies were performed on the microstructure of the examined alloys and their HB hardness was measured. The evaluation of the changes was presented in reference to the model alloys EN AW-7003 and EN AW-7010, whose microstructure under the conditions of thermodynamic equilibrium are described by the phase diagrams: Al-Zn-Mg and Al-Zn-Mg-Cu. The performed investigations confirmed that the hardness HB of the examined alloys is mainly determined by the reinforcement of the matrix αAl by the introduced alloy additions and the presence of phases Θ(Al2Cu) and S(Al2CuMg) rich in copper, as well as η(MgZn2), in the examined alloys' microstructure. The increase of the amount of intermetallic phases precipitated in the microstructure of the examined alloys is caused, beside Cu, by the characteristic change of Zn wt. concentration and Mg. It was proposed that the process of one-stage thermal treatment of the examined alloys be introduced at a temperature of up to tJ-20 °C, which will prevent the exceedance of the solidus temperature.
The work presents the test result of the influence of cooling rate on the microstructure of AZ91 alloy, Vickers micro-hardness and Brinell
hardness. Studies cooling and crystallization of AZ91 alloy was cast into the ceramic shells pre-heated to 180 ° C and then air-cooled at
ambient temperature or intensively super cooled in the liquid coolant. The TDA method was applied to record and characterize the thermal
effect resulting from the phase transformations occurring during the crystallization of AZ91 alloy. The kinetics and dynamics of the
thermal processes of crystallization of AZ91 alloy in the ceramic shells were determined. Metallographic tests were performed with the
use of an optical microscope. A comparison of these test results with the thermal effect recorded by way of the TDA method was made.
Influence of cooling rate of AZ91 on HV0, 01 micro-hardness and Brinell hardness alloy was examined.
The work presents the results of the examinations of silumin 226 as well as a silumin produced on its basis containing a W and Mo addition
introduced in the amount of 0.1; 0.2; 0.3 and 0.4% of both elements simultaneously. Investigations of the crystallization process of the
silumins by the TDA method were conducted. Also, a microscopic analysis of their microstructure was performed and their basic mechanical
properties were determined. Microstructure tests were made on casts produced in an TDA sampler as well as by the pressure method.
The investigations exhibited a change in the course of crystallization of the silumin containing 0.3 and 0.4% W and Mo with respect to
silumin 226 and the silumin with the addition of 0.1 and 0.2%. The presence of additional phases which did not occur in the case of lower
addition contents was established in the silumin containing 0.3-0.4% W and Mo, regardless of the applied casting technology. The tests
showed the possibility of increasing the tensile strength Rm, the proof stress Rp0,2 and the unit elongation A of the silumin as a result of a
simultaneous introduction of the W and Mo addition. The highest values of Rm, Rp0,2 and A were obtained in the silumins with the additions
of these elements within the range of 0.1-0.2% each.
The paper presents the results of hypoeutectic silumin 226 grade and silumin produced on its basis through the addition of V and Mo.
Vanadium and molybdenum were added as the preliminary alloy AlV10 and AlMo8 in an amount providing the concentration of 0.1; 0.2;
0.3 and 0.4% V and Mo. TDA curves of tested silumins were presented; regardless of the chemical composition there were similar thermal
effects. Pressure castings microstructure research revealed the presence in silumins with the addition of V and Mo phases do not occur in
silumin without these additives. These phases have a morphology similar to the walled, and their size increases with increasing
concentration of V and Mo. The size of the precipitates of these phases silumin containing 0.1% V and Mo does not exceed 10 microns,
while 0.4% of the content of these elements increases to about 80 microns. Tests of basic mechanical properties of silumins were carried
out. It has been shown that the highest values of tensile strength Rm = 295 MPa and elongation A = 4.2% have silumin containing
approximately 0.1% V and Mo. Increasing concentrations of these elements causes a gradual lowering of the Rm and A values.
The article presents the investigation results of the crystallization (performed by means of the TDA method) and the microstructure of complex aluminium bronzes with the content of 6% Al, 4% Fe and 4% Ni, as well as Si additions in the scope of 1–2% and Cr additions in the scope of 0.1–0.3%, which have not been simultaneously applied before. For the examined bronze, the following tests were performed: hardness HB, impact strength (KU2). For bronze CuAl6Fe4Ni4Si2Cr0.3, characterizing in the highest hardness, wear tests were conducted with dry friction and the dry friction coefficient. The investigations carried out by means of the X-ray phase analysis demonstrated the following phases in the microstructure of this bronze: αCu, γ2 and complex intermetallic phases based on iron silicide type Fe3Si (M3Si M={Fe,Cr,…}). Compared to the normalized aluminium bronzes (μ=0.18–0.23), the examined bronze characterizes in relatively low wear and lower friction coefficient during dry friction (μ=0.147±0.016).