In this paper the effect of soldering technique and thermal shock test were investigated on SAC 305 solder joints, produced by two different solder method. The solder joints were subjected to different cycle numbers up to 5000 thermal shock tests with two different thermal profiles of –30/+110°C and –40/+125°C. Microstructural properties of the tested joints were examined with the focus on intermetallic layer thickness and crack formation/propagation. Thickness of the scallop shaped Cu6Sn5 intermetallic layer was increased with increasing cycle number for both THRS and multiwave joints, but the thickening was more effective for the THRS joints. Cracks typically formed at the solder alloy/ PTH barrel and the solder alloy/pin interfaces and propagated along grain boundaries and precipitations of intermetallic compound.
We studied the embryology of Withania somnifera (L.) Dunal by light microscopy in order to reveal specific embryological features of the genus, and compared the results with embryological data on other members of the family Solanaceae. The key embryological characters of W. somnifera include dicotyledonous-type anther wall formation, simultaneous cytokinesis in pollen mother cells, binucleate tapetal cells, 2-celled mature pollen, anatropous, tenuinucellate and unitegmic ovules, polygonum-type embryo sac formation, the presence of an endothelium, and cellular endosperm formation. We give the first report of the dicotyledonous mode of anther wall formation (previously described as basic type) for the species. Comparative study suggests that anther wall formation, number of nuclei in tapetal cells, number of cells in mature pollen, mode of embryo sac formation and endosperm development are the most variable embryological features in Solanaceae. Some of these embryological features of W. somnifera should be of value for comparative study of related species and their phylogenetic relationships within the family.
Due to its unique features, the metal foam is considered as one of the newest acoustic absorbents. It is a navel approach determining the structural properties of sound absorbent to predict its acoustical behavior. Unfortunately, direct measurements of these parameters are often difficult. Currently, there have been acoustic models showing the relationship between absorbent morphology and sound absorption coefficient (SAC). By optimizing the effective parameters on the SAC, the maximum SAC at each frequency can be obtained. In this study, using the Benchmarking method, the model presented by Lu was validated in MATLAB coding software. Then, the local search algorithm (LSA) method was used to optimize the metal foam morphology parameters. The optimized parameters had three factors, including porosity, pore size, and metal foam pore opening size. The optimization was applied to a broad band of frequency ranging from 500 to 8000 Hz. The predicted values were in accordance with benchmark data resulted from Lu model. The optimal range of the parameters including porosity of 50 to 95%, pore size of 0.09 to 4.55 mm, and pore opening size of 0.06 to 0.4 mm were applied to obtain the highest SAC for the frequency range of 500 to 800 Hz. The optimal amount of pore opening size was 0.1 mm in most frequencies to have the highest SAC. It was concluded that the proposed method of the LSA could optimize the parameters affecting the SAC according to the Lu model. The presented method can be a reliable guide for optimizing microstructure parameters of metal foam to increase the SAC at any frequency and can be used to make optimized metal foam.
Thermodynamic principles for the dissolution of gases in ionic liquids (ILs) and the COSMO-SAC model are presented. Extensive experimental data of Henry’s law constants for CO2, N2 and O2 in ionic liquids at temperatures of 280-363 K are compared with numerical predictions to evaluate the accuracy of the COSMO-SAC model. It is found that Henry’s law constants for CO2 are predicted with an average relative deviation of 13%. Both numerical predictions and experimental data reveal that the solubility of carbon dioxide in ILs increases with an increase in the molar mass of ionic liquids, and is visibly more affected by the anion than by the cation. The calculations also show that the highest solubilities are obtained for [Tf2N]ˉ. Thus, the model can be regarded as a useful tool for the screening of ILs that offer the most favourable CO2 solubilities. The predictions of the COSMOSAC model for N2 and O2 in ILs differ from the pertinent experimental data. In its present form the COSMO-SAC model is not suitable for the estimation of N2 and O2 solubilities in ionic liquids.