The spectroscopic FT-IR and FT-Raman methods allowed to identify the cross-linking process of the aqueous composition of poly(acrylic

acid)/sodium salt of carboxymethyl starch (PAA/CMS-Na) applied as a binder for moulding sands (as a novel group binders BioCo). The

cross-linking was performed by physical agent, applying the UV-radiation. The results of structural studies (IR, Raman) confirm the

overlapping of the process of cross-linking polymer composition PAA/CMS-Na in UV radiation. Taking into account the ingredients and

structure of the polymeric composition can also refer to a curing process in a binder - mineral matrix mixture. In the system of bindermineral

matrix under the influence of ultraviolet radiation is also observed effect of binding. However, the bonding process does not occur

in the entire volume of the investigated system, but only on the surface, which gives some possibilities for application in the use of UV

curing surface of cores, and also to cure sand moulds in 3D printing technology