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Abstrakt

The influence of the processing temperature of polylactide (PLA) on the structure geometry changing (SGC) and its functional properties were analyzed. The PLA samples subjected to testing were manufactured using incremental fused deposition modeling technology (FDM) with processing temperatures ranging from 180°C to 230°C. The topography of the PLA surfaces formed during heat dissipation and generated by the work table was analyzed. The roughness measurements were carried out using the profile method in accordance with PN ISO 3274: 2011. Registered profiles of the surfaces were analyzed numerically in fractal terms using the method of the S(Δx) structure function. The functional properties of the PLA surface were evaluated on the basis of Abbott-Firestone curves, according to PN EN ISO 13565–2: 1999.

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Autorzy i Afiliacje

B. Pszczółkowski
M. Bramowicz
ORCID: ORCID
W. Rejmer
T. Chrostek
C. Senderowski
Pobierz PDF Pobierz RIS Pobierz Bibtex

Abstrakt

Studies on packaging made of polylactide (PLA) subjected to long-term influence of soil environment conditions have been presented in this paper. The scientific objective of this study was to determine changes in selected properties of the PLA packaging after long-term incubation in soil. These changes were investigated by scanning electron microscopy, differential scanning calorimetry, thermogravimetric analysis, and gel permeation chromatography. The structure, thermal properties, and disintegration degree of the packaging after their three-year incubation in soil have been discussed. It was found that the PLA packaging did not disintegrate significantly in the soil environment, and slight changes in their structure and lack of significant changes in thermal properties indicate that the efficiency of their degradation in soil conditions after three years is very low. This was mainly due to inadequate temperatures in the soil. It was also found (based on the results of scanning electron microscopy and gel permeation chromatography) that initiation of the biodegradation process took place and that this process is much faster than in the case of conventional non-biodegradable polymers. The results are confirmation that materials obtained of various biodegradable polymers (not only PLA) should be biodegradable only under strictly defined conditions, allocated to a specific type of polymer, i.e. those in which they are easily and quickly biodegradable
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Bibliografia

  1. Adhikari, D., Mukai, M., Kubota, K., Kai, T., Kaneko, N., Araki, K.S. & Kubo, M. (2016). Degradation of Bioplastics in Soil and Their Degradation Effects on Environmental Microorganisms, Journal of Agricultural Chemistry and Environment, 5, pp. 23-34. DOI:10.4236/jacen.2016.51003
  2. Ahmed, J. & Varshney, S.K. (2011). Polylactides – Chemistry, Properties and Green Packaging Technology: A Review, International Journal of Food Properties, 14, pp. 37-58. DOI:10.1080/10942910903125284
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  4. Deroiné, M., Le Duigou, A., Corre, Y.M., Le, Gac, P.Y., Davies, P., César, G. & Bruzaud, S. (2014). Accelerated ageing of polylactide in aqueous environments: Comparative study between distilled water and seawater, Polymer Degradation and Stability, 108, pp. 319-329. DOI:10.1016/j.polymdegradstab.2014.01.020
  5. Dintcheva, N.T., Al-Malaika, S., Morici, E. & Arrigo, R. (2017). Thermo-oxidative stabilization of poly(lactic acid)-based nanocomposites through the incorporation of clay with in-built antioxidant activity, Journal of Applied Polymer Science, 134, pp. 44974-44986. DOI:10.1002/app.44974
  6. Donghee, K., Yoshito, A., Yoshihito, S. & Haruo, N. (2011). Biomass-based composites from poly(lactic acid) and wood flour by vapor-phase assisted surface polymerization, ACS Applied Materials & Interfaces, 3, pp. 385-391. DOI:10.1021/am1009953
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  8. Itavaara, M., Karjomaa, S. & Selin, J.F. (2002). Biodegradation of polylactide in aerobic and anaerobic thermophilic conditions, Chemosphere, 46, pp. 879-885. DOI:10.1016/s0045-6535(01)00163-1
  9. Janczak, K., Dąbrowska, G.B., Raszkowska-Kaczor., A., Kaczor, D., Hrynkiewicz, K. & Richert, A. (2020). Biodegradation of the plastics PLA and PET in cultivated soil with the participation of microorganisms and plants, International Biodeterioration & Biodegradation, 155, 105087. DOI:10.1016/j.ibiod.2020.105087
  10. John, R.P., Nampoothiri, K.M. & Pandey, A. (2007). Fermentative production of lactic acid from biomass: an overview on process developments and future perspectives, Applied Microbiology and Biotechnology, 74, pp. 524-534. DOI:10.1007/s00253-006-0779-6
  11. Kale, G., Auras, R. & Singh, S.P. (2007). Comparison of the degradability of poly (lactide ) packages in composting and ambient exposure conditions, Packaging Technology & Science, 20, pp. 49-70. DOI:10.1002/pts.742
  12. Kamiya, M., Asakawa, S. & Kimura, M. (2007). Molecular Analysis of Fungal Communities of Biodegradable Plastics in Two Japanese Soils, Soil Science and Plant Nutrition, 53, pp. 568-574. DOI:10.1111/j.1747-0765.2007.00169.x
  13. Kim, M.N., Kim, W.G., Weon, H.Y. & Lee, S.H. (2008). Poly(L-Lactide)-Degrading Activity of a Newly Isolated Bacterium, Journal of Applied Polymer Science, 109, pp. 234-239. DOI:10.1002/app.26658
  14. Kim, D.Y. & Rhee, Y.H. (2003). Biodegradation of Microbial and Synthetic Polyesters by Fungi, Applied Microbiology and Biotechonology, 61, pp. 300-308. DOI:10.1007/s00253-002-1205-3
  15. Lee, S.H. & Kim, M.N. (2010). Isolation of Bacteria Degrading Poly(butylenes succinate-co-butylene adipate) and Their lip A Gene, International Biodeterioration and Biodegradation, 64, pp. 184-190. DOI:10.1016/j.ibiod.2010.01.002
  16. Mehlika, K., Ashley, H. & Geoffrey, D.R. (2014). Isolation and characterisation of fungal communities associated with degradation and growth on the surface of poly(lactic) acid (PLA) in soil and compost, International Biodeterioration & Biodegradation, 95, pp. 301-310. DOI:10.1016/j.ibiod.2014.09.006
  17. Nakamura, K., Tomita, T., Abe, N. & Kamio, Y. (2001). Purification and Characterization of an Extracellular Poly(L-Lactic Acid) Depolymerase from a Soil Isolate, Amycolatopsis sp. Strain K104-1, Applied Environmental Microbiology, 67, pp. 345-353. DOI:10.1128/aem.67.1.345-353.2001
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Autorzy i Afiliacje

Rafał Malinowski
1
ORCID: ORCID
Marta Musioł
2
ORCID: ORCID
Krzysztof Moraczewski
3
Volodymyr Krasinskyi
1
ORCID: ORCID
Lauren Szymańska
1
ORCID: ORCID
Krzysztof Bajer
1
ORCID: ORCID

  1. Łukasiewicz Research Network - Institute for Engineering of Polymer Materials and Dyes, Toruń, Poland
  2. Centre of Polymer and Carbon Materials, Polish Academy of Sciences, Zabrze, Poland
  3. Faculty of Materials Engineering, Kazimierz Wielki University, Bydgoszcz, Poland

Abstrakt

In the paper presented are results of a research on effectiveness of absorbing electromagnetic waves at frequency 2.45 GHz by unhardened sodium silicate base sands (SSBS) prepared of high-silica base sand and a PLA (Polylactide) 3D-prited (3DP) mould walls. Measurements of power loss of microwave radiation (P in) expressed by a total of absorbed power (P abs), output power (P out) and reflected power (P ref) were carried-out on a stand of semiautomatic microwave slot line for determining balance of microwave power emitted into selected multimaterial systems. Values of microwave power loss in the rectangular waveguide filled with unhardened moulding sands and prepared by fused deposition modelling (FDM) 5 mm polylactide (PLA) walls with grid infill density from 25% to c.a. 100% served for determining effectiveness of microwave heating. Balance of microwave power loss is of technological importance for microwave manufacture of high-quality casting sand moulds and cores in possibility of use 3D-printed mould tools and core boxes. It was found that apparent density of SSBS placed in a waveguide with PLA walls influences parameters of power output (P out) and power reflected (P ref). The PLA wall position and grid infill density were identified to have a limited effect on effectiveness of absorbing microwaves (P abs).
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Autorzy i Afiliacje

M. Stachowicz
1
ORCID: ORCID

  1. Wroclaw University of Technology, Poland

Abstrakt

In sand casting, Fused Deposition Modeling (FDM) printing by using Poly Lactic Acid (PLA) filament is one of the innovative foundry technologies being adopted to substitute traditional pattern making. Several literatures have reported the influence of process parameters such as raster angle and print speed on some mechanical properties of FDM-printed, PLA-prototypes used in other applications. This study investigated the effects of interior fill, top solid layer, and layer height on the compressive strength of rapid patterns for sand casting application. Different values of the process parameters were used to print the pre-defined samples of the PLA-specimens and a compression test was performed on them. The coupled effects of the process parameters on compressive strength were investigated and the optimum values were determined. Interior fill of 36%, layer height of 0.21 mm and top solid layer of 4 were found to produce a FDM-printed, PLApattern that sustained a compaction pressure of 0.61 MPa. A simulation analysis with ANSYS® to compare failure modes of both experiment and model shows a similarity of buckling failure that occurred close to the base of each specimen.
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Autorzy i Afiliacje

P.I. Anakhu
C.C. Bolu
A.A. Abioye
G. Onyiagha
H. Boyo
K. Jolayemi
J. Azeta
Pobierz PDF Pobierz RIS Pobierz Bibtex

Abstrakt

The article presents the results of the research related to the decomposition of polylactic acid (PLA)/halloysite nanotube (HNTs) biocomposites into a simple organic form. After manufacturing the nanocomposites, the evaluation of the composting process simulation was conducted using the biodegradation method. First, the selected properties of PLA/HNTs biocomposites, such as density, water absorption, and impact strength were tested. Next, the impact of the composting process on the behavior of PLA/HNTs composites was investigated from 30 to 90 days. Finally, the loss of mass of the composites, hardness, and the structural changes of biocomposites under the composting conditions before and after the composting were evaluated using SEM microscopy. The results showed that the PLA modified by HNT particles has biodegradation-friendly properties and therein is fully suitable for organic recycling. Due to this, in the coming years, it may contribute to the replacement of non-biodegradability polymers, i.e. polyolefins and polyesters, and reduction of plastic packaging wastes.
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Bibliografia

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Autorzy i Afiliacje

Dorota Czarnecka-Komorowska
1
ORCID: ORCID
Katarzyna Bryll
2
ORCID: ORCID
Ewelina Kostecka
2
ORCID: ORCID
Małgorzata Tomasik
3
ORCID: ORCID
Elżbieta Piesowicz
4
ORCID: ORCID
Katarzyna Gawdzińska
2
ORCID: ORCID

  1. Institute of Materials Technology, Polymer Processing Division; Poznan University of Technology, 60-965 Poznan, Poland
  2. Department of Machines Construction and Materials, Maritime University of Szczecin, 71-650 Szczecin, Poland
  3. Department of Interdisciplinary Dentistry, Pomeranian Medical University, 70-111 Szczecin, Poland
  4. Institute of Material Science and Engineering, West Pomeranian University of Szczecin, 70-310 Szczecin, Poland

Abstrakt

The transition to circular economy requires diversifying material sources, improving secondary raw materials management, including recycling, and finally finding sustainable alternative materials. Both recycled and bio-based plastics are often regarded as promising

alternatives to conventional fossil-based plastics. Their broad application instead of fossilbased plastics is, however, frequently the subject of criticism because of offering limited

environmental benefits. The study presents a comparative life cycle assessment (LCA) of

fossil-based polyethylene terephthalate (PET) versus its recycled and bio-based counterparts. The system boundary covers the plastics manufacturing and end-of-life plastic management stages (cradle-to-cradle/grave variant). Based on the data and assumptions set

out in the research, recycled PET (rPET) demonstrates the best environmental profile out

of the evaluated plastics in all impact categories. The study contributes to circular economy in plastics by providing transparent and consistent knowledge on their environmental

portfolio.

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Autorzy i Afiliacje

Magdalena Rybaczewska-Błażejowska
Angel Mena-Nieto

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