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Abstract

The organo-inorganic commercial binder Albertine F/1 (Hüttenes-Albertus) constituting the starch-aluminosilicate mixture was directed to structural studies. The paper presents a detailed structural analysis of the binder before and after exposure to physical curing agents (microwaves, high temperature) based on the results of infrared spectroscopy studies (FTIR). An analysis of structural changes taking place in the binder system with the quartz matrix was also carried out. Based on the course of the obtained IR spectra, it was found that during the exposure on physical agents there are structural changes within the hydroxyl groups in the polymeric starch chains and silanol groups derived from aluminosilicate as well as in the quartz matrix (SiO2). The curing of the molding sand takes place due to the evaporation of the solvent water and the formation of intramolecular and intermolecular cross-linking hydrogen bonds. Type and amount of hydrogen bonds presence in cured molding sand have an impact on selected properties of molding sand. Results indicates that for molding sand with Albertine F/1 during conventional heating a more extensive network of hydrogen bonds is created.
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Authors and Affiliations

S. Żymankowska-Kumon
B. Grabowska
A. Bobrowski
K. Kaczmarska
S. Cukrowicz
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Abstract

Microwave curing of bamboo fiber increases the physical and mechanical qualities of cement concrete, according to previous studies. However, there are limited research on their endurance when used as an additive in concrete manufacturing to increase strength. The impact of bamboo fiber and Styrene Butadiene Rubber (SBR) on the mechanical and microstructure of the resulting concrete is investigated in this study. With the inclusion of bamboo fiber ranging from 0–1.5%, a mix ratio of 1:1.5:3 was used. To make the samples, 10% SBR by weight of cement was dissolved in the mixing water. The batching was done by weight, with a water cement ratio of 0.6. Compressive strength, water absorption, swelling, modulus of elasticity, and modulus of rupture were all studied as mechanical properties. Various characterization tests such as SEM, EDS, FTIR, XRD, and TGA were performed on the microstructure, crystalline nature, and mineral composition of certain samples. According to the FTIR study’s findings, peak levels were detected in the O–H stretching, C–H fiber and CH2 functional groups, carbonyl group, C–O and C–C functional groups. As the temperature climbed, TGA measurements showed a drop in weight. The XRD test revealed peak levels of 6.611, 4.255, and 3.855 for sanidine, quartz, and calcite, respectively. After 28 days, the inclusion of bamboo fibers as an additive in concrete shows some promising outcomes in compressive strength, with samples containing 1% and 1.5% bamboo fiber cured at 80°C having a higher compressive strength value.
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Authors and Affiliations

Ajayi Joseph Adeniyi
1
ORCID: ORCID
James Gana
1
ORCID: ORCID
Ariyo Adanikin
ORCID: ORCID
Kola Ogedengbe
1
ORCID: ORCID
Abundance Idowu
1
ORCID: ORCID

  1. Landmark University, School of Engineering, Department of Civil Engineering, Omu-Aran, Kwara State, Nigeria

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