Distribution of the exhaust gas temperature within the furnace of a grate boiler greatly depends on its operating parameters such as output. It has a considerably different character than temperature distributions in other types of boilers (with pulverised or fluidised bed), as it varies considerably across the chamber. Results presented in this paper have been obtained through research of a grate-fired hot water boiler with a nominal rating of some 30 MW. Measurements have been taken by introducing temperature sensors into prearranged openings placed in the boiler side walls. Investigation has been carried out for different output levels. Tests involved thermocouples in ceramic coating and aspirated thermocouples. The latter were used to eliminate influence of radiative heat transfer on measured results. Values obtained with both methods have been cross-checked.