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Abstract

The article presents crystallization process of silicon molybdenum ductile cast iron (SiMo). The alloy with 5% silicon content and with

variable amounts of Mo in a range of 0-1% was chosen for the research. The carbon content in the analysed alloys did not exceed 3,1%.

The studies of crystallization process were based on thermal – derivative analysis (TDA). Chemical composition of all examined samples

was analysed with the use of LECO spectrometer. Additionally, the carbon and the sulphur content was determined basing on carbon and

sulphur LECO analyser. For metallographic examination, the scanning electron microscopy (SEM) with EDS analyser was used. Disclosed

phases have been also tested with the use of X-ray diffraction. The results allowed the description of crystallization processes of silicon

molybdenum ductile cast iron using thermal – derivative analysis (TDA). Conducted studies did not allow for the clear identification of all

complex phases containing molybdenum, occurring at the grain boundaries. Therefore, the further stages of the research could include the

use of a transmission electron microscope to specify the description of complex compounds present in the alloy.

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Authors and Affiliations

M. Stawarz
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Abstract

The article presents results of studies of silicon – molybdenum cast iron (4.42% Si, 2.59% Mo and 2.48% C wt.-%) crystallization process. Metallographic analysis was carried out using SEM-scanning electron microscopy with the EDS system. In order to determine the phase composition, X-ray diffraction studies were performed. Thermo-Calc, a computer simulation program, was used to simulate the crystallization process. . The obtained data allowed to describe the effect of some elements on the crystallization process. The silicon phase of MnSi could not be identified during metallographic studies. Also, computer simulation of the crystallization process did not answer the question at which point the silicon phase of MnSi crystallizes in the tested alloy. Therefore, not all results obtained were linked to the registered crystallization process (TDA process). The EDS analysis revealed an unusual distribution of molybdenum in the microstructure of the sample, where it is clearly visible that the area enriched with this element is also the separation of spheroidal graphite. The possibility of occurrence of Mo-rich micro-areas found in graphite is considered. The case is debatable and difficult to resolve at this stage. Perhaps, at such a high concentration of molybdenum (2.59% Mo) in the alloy, conditions are created for simultaneously crystallization of graphite and molybdenum phases.
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Authors and Affiliations

M. Stawarz
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Abstract

The paper presents an analysis of a selected grade of high silicon cast iron intended for work in corrosive and abrasive conditions. The text describes its microstructure taking into account the process of crystallization, TDA analysis, EDS, XRD and the chemical composition analysis. In order to determine the phase composition, X-ray diffraction tests were carried out. The tests were executed on a Panalytical X'Pert PRO X-ray diffractometer with filtration of radiation from a lamp with copper anode and PIXcel 3D detector on the deflected beam axis. Completed tests allowed to describe the microstructure with detailed consideration of intermetallic phases present in the alloy. Results of the analysis of the examined alloy clearly show that we deal with intermetallic phases of Fe3Si, Fe5Si3 types, as well as silicon ferrite and crystals of silicon. In the examined alloy, we observed the phenomenon of segregation of carbon, which, as a result of this process, enriches the surface of silicon crystals, not creating a compound with it. Moreover, the paper demonstrates capability for crystallization of spheroidal graphite in the examined alloy despite lack of elements that contribute to balling in the charge materials.

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Authors and Affiliations

M. Stawarz
ORCID: ORCID
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Abstract

Silicon – molybdenum cast iron commonly called SiMo due to its unique properties has becoming more and more interesting engineering material. The history and development of this alloy is relatively long but, due to the significant difficulties during the manufacturing process resulting in the lower final quality than expected, it has not been applied to often in practice. The biggest challenge is its brittleness as a result of the carbides precipitations. During last few years, thanks to the many important researches made and the general foundry technology development, the interest in SiMo iron has been rapidly growing, especially for the castings for heavy duty applications like corrosion, high temperature and wear abrasion resistant parts. In the article the heat treatment attempts to improve the microstructure of SiMo castings has been presented. The goal was to destroy or at least to refine and uniformly distribute the carbides precipitations to improve mechanical properties of the exhaust manifold castings for the cars. The experiments were carried out for the alloy contains approx. 4% Si, 1% Mo and 3.2%C. The range of the research included: hardness measuring, standard mechanical properties and microstructure for as-cast state and after that the subsequent heat treatment process with another properties check. The result of the heat treatment was the elimination of pearlite from the metal matrix. Moreover, the changes of the carbide molybdenum – rich phase morphology were observed. The dispersion of the carbides precipitations in the carbides area was observed. The experiments proved the possibility to control the microstructure and the mechanical properties of the SiMo castings by means of heat treatment but only to some extent.

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Authors and Affiliations

B. Cygan
M. Stawarz
J. Jezierski
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Abstract

The article presents results of pitting corrosion studies of selected silicon cast irons. The range of studies included low, medium and high

silicon cast iron. The amount of alloying addition (Si) in examined cast irons was between 5 to 25 %. Experimental melts of silicon cast

irons [1-3] were conducted in Department of Foundry of Silesian University of Technology in Gliwice and pitting corrosion resistance

tests were performed in Faculty of Biomedical Engineering in Department of Biomaterials and Medical Devices Engineering of Silesian

University of Technology in Zabrze. In tests of corrosion resistance the potentiostat VoltaLab PGP201 was used. Results obtained in those

research complement the knowledge about the corrosion resistance of iron alloys with carbon containing Si alloying addition above 17 %

[4-6]. Obtained results were supplemented with metallographic examinations using scanning electron microscopy. The analysis of

chemical composition for cast irons using Leco spectrometer was done and the content of alloying element (silicon) was also determined

using the gravimetric method in the laboratory of the Institute of Welding in Gliwice. The compounds of microstructure were identify by

X-ray diffraction.

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Authors and Affiliations

A. Kajzer
M. Stawarz
M. Dojka
W. Kajzer
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Abstract

The paper presents results of tests carried out on ausferrite carbide matrix alloyed ductile cast iron. The ausferrite was obtained via addition of Cu and Mo alloying elements. This eliminated heat treatment from the alloy production cycle. The article presents results of tests of the quality of the obtained material. Emphasis was put on metallographic analysis using light and scanning microscopy. Works also included chemical composition tests and EDS analysis. Strength tests were executed in an accredited laboratory. It is possible to create a raw ausferrite carbide matrix without subjecting an alloy to heat treatment. However, it turned out that quality parameters of cast iron were insufficient. The obtained material hardness was 515 HB, while Rm strength and A5 ductility were very low. The low tensile strength of the analyzed alloy resulted from the presence of degenerate graphite secretion (of flake or vermicular shape) in the cast iron. The tests also demonstrated that the alloy was prone to shrinkage-related porosity, which further weakened the material. Alloys made of alloyed ductile iron of ausferrite matrix micro-structure are very attractive due to elimination of the heat treatment process. However, their production process and chemical composition must be optimized.
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Bibliography

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Authors and Affiliations

M. Stawarz
1
ORCID: ORCID
M. Lenert
1
K. Piasecki
1
ORCID: ORCID

  1. Department of Foundry Engineering, Silesian University of Technology, Towarowa 7 St., 44-100 Gliwice, Poland
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Abstract

The paper presents the research results of horizontal continuous casting of ingots of aluminium alloy containing 2% wt. silicon (AlSi2).

Together with the casting velocity (velocity of ingot movement) we considered the influence of electromagnetic stirring in the area of the

continuous casting mould on refinement of the ingot’s primary structure and their selected mechanical properties, i.e. tensile strength, yield

strength, hardness and elongation. The effect of primary structure refinement and mechanical properties obtained by electromagnetic

stirring was compared with refinement obtained by using traditional inoculation, which consists in introducing additives, i.e. Ti, B and Sr,

to the metal bath. On the basis of the obtained results we confirmed that inoculation done by electromagnetic stirring in the range of the

continuous casting mould guarantees improved mechanical properties and also decreases the negative influence of casting velocity, thus

increasing the structure of AlSi2 continuous ingots.

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Authors and Affiliations

J. Szajnar
M. Stawarz
D. Bartocha
T. Wróbel
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Abstract

In paper is presented results of studies concerning ingot of Al with a purity of 99.5% cast with use of stand of horizontal continuous

casting. Mainly together with casting velocity was considered influence of electromagnetic stirrer, which was placed in continuous casting

mould on refinement of ingots structure and theirs usability to plastic deformation. Effect of structure refinement and usability to plastic

deformation obtained by influence of electromagnetic stirring was compared with refinement obtained by use of traditional inoculation,

which consists in introducing of additives i.e. Ti and B to metal bath. On the basis of obtained results was affirmed that inoculation

realized by electromagnetic stirring in range of continuous casting mould guarantees improvement in structure refinement and usability to

rolling of pure Al continuous ingots.

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Authors and Affiliations

J. Szajnar
D. Bartocha
T. Wróbel
M. Stawarz
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Abstract

In paper is presented idea of construction and influence of selected parts of stand of horizontal continuous casting on quality of pure Al and AlSi2

alloy ingots. The main parts of the made stand belong to induction furnace, which is also tundish, water cooled continuous casting mould, system

of recooling, system of continuous ingot drawing and cutting. Mainly was considered influence of electromagnetic stirrer, which was placed

in continuous casting mould on refinement of ingots structure. Effect of structure refinement obtained by influence of electromagnetic stirring was

compared with refinement obtained by use of traditional inoculation, which consists in introducing of additives i.e. Ti and B to metal bath. The

results of studies show possibility of effective refinement of Al and AlSi2 alloy primary structure, only with use of horizontal electromagnetic field

and without necessity of application of inoculants. This method of inoculation is important, because inoculants decrease the degree of purity

and electrical conductivity of pure aluminum and moreover are reason of point cracks formation during rolling of ingots.

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Authors and Affiliations

J. Szajnar
D. Bartocha
T. Wróbel
M. Stawarz
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Abstract

Nowadays, the best castings’ manufacturers have to meet very demanding requirements and specifications applicable to mechanical properties and other characteristics. To fulfill those requirements, more and more sophisticated methods are being used to analyze the internal quality of castings. In many cases, the commonly used Non-Destructive Methods, like X-ray or ultrasonic testing, are not enough to ensure precise and unequivocal evaluation. Especially, when the properties of the casting only slightly fail the specification and the reasons for such failures are very subtle, thus difficult to find without the modern techniques. The paper presents some aspects of such an approach with the use of Scanning Electron Microscopy (SEM) to analyze internal defects that can critically decrease the performance of castings. The paper presents the so-called bifilm defects in ductile and chromium cast iron, near-surface corrosion caused by sulfur, micro-shrinkage located under the risers, lustrous carbon precipitates, and other microstructure features. The method used to find them, the results of their analysis, and the possible causes of the defects are presented. The conclusions prove the SEM is now a powerful tool not only for scientists but it is more and more often present in the R&D departments of the foundries.
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Authors and Affiliations

J. Jezierski
1
ORCID: ORCID
M. Dojka
1
M. Stawarz
1
ORCID: ORCID
R. Dojka
2

  1. Department of Foundry Engineering, Silesian University of Technology, 7 Towarowa, 44-100 Gliwice, Poland
  2. ODLEWNIA RAFAMET Sp. z o.o., 1 Staszica, 47-420 Kuźnia Raciborska, Poland
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Abstract

The article discusses benefits associated with the use of silicon carbide in the process of melting gray cast iron and ductile cast iron in induction electric furnaces. It presents the analysis of the impact of various charge materials and the addition of a variable amount of SiC and FeSi to the fixed charge when melting cast iron of grades GJS 400-15 and GJS 500-7 on mechanical properties and microstructure. Moreover, the article includes an analysis of the efficiency of carburization and the increase in the content of silicon during the application of SiC. The article also presents the results of the study of primary modification using silicon carbide at the minimum temperature of Temin eutectic and Tsol solidus. Based on analysis of the literature, conducted research, and calculations, it was found that the addition of silicon carbide has a beneficial impact on the properties of melted cast iron. The addition of SiC in the charge increases the content of C and Si without increasing the amount of contaminations. The addition of SiC at reduced pig iron presence in the charge decreases production costs, while the use of SiC as an inoculant increases both Temin and Tsol, which is beneficial from the point of view of cast iron nucleation.
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Authors and Affiliations

K. Janerka
1
ORCID: ORCID
Ł. Kostrzewski
2
ORCID: ORCID
M. Stawarz
1
ORCID: ORCID
J. Jezierski
1
ORCID: ORCID
J. Szajnar
1
ORCID: ORCID

  1. Silesian University of Technology, Department of Foundry Engineering, 7 Towarowa Str., 44-100 Gliwice, Poland
  2. Leszczyńska Fabryka Pomp, 15 Fabryczna Str., 64-100 Leszno, Poland

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