Presented study aimed to determine metals distribution on the quartz fiber filters surface coated with particulate matter by using high and low-volume samplers. The distribution pattern was tested using two different sub-sampling schemes. Each sub-sample was mineralized in the nitric acid in a microwave oven. An analysis was performed by means of atomic absorption spectroscopy with electrothermal atomization GF-AAS technique, and the determined elements were: As, Cd, Pb and Ni. A validation of the analytical procedure was carried out using NIES 28 Urban Aerosols standard reference material.

It was assumed that metal is distributed uniformly if its normalized concentrations on a single sub-sample is within ±15% of the mean concentration over the whole filter. The normalized concentrations values exceed this range, indicating a non-homogenous metals distribution. There were no statistically significant differences in metals concentrations between particular sub-samples in the function of its position along the filters diameter.

Thirteen fractions of ambient dust were investigated in Zabrze, a typical urban area in the central part of Upper Silesia (Poland), during a heating season. Fifteen PAH and Cr, Mn, Co, Ni, As, Se, Cd, Pb contents of each fraction were determined. The dust was sampled with use of a cascade impactor and chemically analyzed with an energy dispersive X-ray fluorescence spectrometer (PANalytical Epsilon 5) and a gas chromatograph with a flame ionisation detector (Perkin Elmer Clarus 500). The concentrations of PM1 and the PM1-related PAH and elements were much higher than the ones of the coarse dust (PM2.5-10) and the substances contained in it. The concentrations of total PAH and carcinogenic PAH were very high (the concentrations of PM1-, PM2.5-, and PM10-related BaP were 16.08, 19.19, 19.32 ng m-3, respectively). The municipal emission, resulted mainly from hard coal combustion processes, appeared to be the main factor affecting the air quality in Zabrze in winter.

The: PM2.5/PM10 ratio expresses the anthropogenic share in atmospheric dusl. Very high values or this ratio, i.e. high contribution or PM2.5 to PM10. have occurred recently in atmospheric air within European indusuializcd areas. The paper compiles results of three year pair wise measuring ofconcentrations or PM2.5 and PM2.5-PM10 and compares shares or PMM2.5 in PM10 al three urban background sites in Upper Silesia Poland I towns or Zabrze. Katowice and Częstochowa). At all the three local ions, the PM2.5/PM10 ratio nr daily conccntrations nr dust only occasionally differed considerably from the PM2.5/PM10 ratios for the seasonal and yearly concentrations that, in turn. did not differ from the PM2.5/PM10 ratios al urban sites in Europe.

Polycyclic aromatic hydrocarbons (PAI-ls) are persistent organic pollutants, ubiquitous in the whole environment. They are relatively well known and are still of interest due to their well documented carcinogenic and mutagenie properties. In ambient air of urban regions they mostly occur as adsorbed to particles of suspended dust. The richest in these compounds and therefore most hazardous to humans, fraction of dust is the fraction of the finest particles. The paper presents results of investigations of dust sampled with use of an impactor Dekati PM10 in Zabrze, a site typical of Upper Silesian conditions. While sampling, the impactor segregates sampled particles into four fractions by their aerodynamic diameters. Sixteen PAHs were determined in each fraction chromatographically. PAH content in the fraction of the finest particles, i.e. in PM1, was of particular interest.

The article shows the effect of the supply pressure of fog nozzles on the process of ammonia sorption. In the tests, the nozzles flow characteristics Q=f(p) and the dependence of NH3 concentration as a function of the water stream feeding in time at different supply pressures were determined. For the TF 6 NN, TF 6 V, NF 15, CW 50 nozzles, measurements were carried out at the following supply pressures: 0.1 MPa; 0.2MPa; 0.3MPa; 0.4MPa; 0.5MPa. It was observed that the greatest effect of nozzle feed pressure on ammonia sorption efficiency may be expected at lower pressure values. At higher values, the sorption rate becomes stabilized and even starts to decrease. The decreases in the sorption rate constant observed for higher pressures may be due to a reduction contact time of the droplet and the achievement of the critical mixing rate of ammonia vapors in the air intensively saturated with water streams. This is due to diffusion rate limitations. The measurements show that the use of supply pressures for fog nozzles above 0.4 MPa is not justified. It should be noted that varying the feed pressure of nozzles of various designs can affect their ammonia sorption efficiency differently. The type of nozzle and supply pressure affects the distribution of droplets in space. The angle of dispersion and the shape of the generated jet have a critical influence on the efficiency of the sorption process. Complete filling of the space and a large spray angle assure relatively high sorption efficiency.