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Abstract

A method for manufacturing of Al-Si alloy (EN AC-44200) matrix composite materials reinforced with MAX type phases in Ti-Al-C systems was developed. The MAX phases were synthesized using the Self-propagating High-Temperature Synthesis (SHS) method in its microwave assisted mode to allow Ti2AlC and Ti3AlC2 to be created in the form of spatial structures with open porosity. Obtained structures were subjected to the squeeze casting infiltration in order to create a composite material. Microstructures of the produced materials were observed by the means of optical and SEM microscopies. The applied infiltration process allows forming of homogeneous materials with a negligible residual porosity. The obtained composite materials possess no visible defects or discontinuities in the structure, which could fundamentally deteriorate their performance and mechanical properties. The produced composites, together with the reference sample of a sole matrix material, were subjected to mechanical properties tests: nanohardness or hardness (HV) and instrumental modulus of longitudinal elasticity (EIT).
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Authors and Affiliations

A. Dmitruk
K. Naplocha
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Abstract

NiTi alloys are successfully used in engineering and medical applications because of their properties, such as shape memory effect, superelasticity or mechanical strength. A composite with Mg matrix, due to its vibration damping properties, can be characterized by low weight and good vibration damping properties. In this study, a combination of two techniques was used for successful fabrication of Mg composite reinforced by NiTi alloy preform. The porous preforms synthesized by Self-propagating High-temperature Synthesis (SHS) from elemental powders were subsequently infiltrated with Mg by squeeze casting. The effects were examined with scanning electron microscope with EDS detector, X-ray diffraction and microindentation. The inspection has shown well-connected matrix and reinforcement; no reaction at the interface and open porosities fully infiltrated by liquid Mg. Moreover, analysis of samples’ fracture has exhibited that crack propagates inside the Mg matrix and there is no detachment of reinforcement.

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Authors and Affiliations

A. Kucharczyk
K. Naplocha
M. Tomanik
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Abstract

Development of open cellular metal foam technology based on investment casting applying the polyurethane pattern is discussed.

Technological process comprises preparing of the ceramic mold applying PUR foam as the pattern, firing of the mold, pouring of the

liquid Zn-Al alloy into the mold and washing out of the ceramic material from cellular casting. Critical parameters such as the temperature

of mold and poured metal, design of gating system affected by metalostatic pressure allowed to produce castings with cellular structure

characterized by the open porosity.

Metal cellular foams with the open porosity embedded in phase change material (PCM) enhance heat transfer and reduce time operations

in energy storage systems. Charging and discharging were performed at the laboratory accumulator by heating and cooling with flowing

water characterized by the temperatures of 97-100oC. Temperature measurements were collected from 7 different thermocouples located

in the accumulator. In relation to the tests with pure paraffin, embedding of the metal Zn-Al cellular foam in paraffin significantly

decreases temperature gradients and melting time of paraffin applied as PCM characterized by the low thermal conductivity. Similarly,

reduction of discharging time by this method improves the efficiency of thermal energy storage system applied in solar power plants or for

the systems of energy efficient buildings.

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Authors and Affiliations

K. Naplocha
A. Koniuszewska
J. Lichota
J.W. Kaczmar
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Abstract

Investment casting combined with the additive manufacturing technology enables production of the thin-walled elements, that are geometrically complex, precise and can be easy commercialized. This paper presents design of aluminium alloy honeycombs, which are characterized with light structure, internal parallel oriented channels and suitable stiffness. Based on 3D printed pattern the mould was prepared from standard ceramic material subjected subsequently to appropriate heat treatment. Into created mould cavity with intricate and susceptible structure molten AC 44200 aluminium alloy was poured under low pressure. Properly designed gating system and selected process parameters enabled to limit the shrinkage voids, porosities and misruns. Compression examination performed in two directions showed different mechanisms of cell deformation. Characteristic plateau region of stress-strain curves allowed to determine absorbed energy per unit volume, which was 485 or 402 J/mm3 depending on load direction. Elaborated technology will be applied for the production of honeycomb based elements designated for energy absorption capability.

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Authors and Affiliations

K. Naplocha
ORCID: ORCID
A. Dmitruk
ORCID: ORCID
P. Mayer
J.W. Kaczmar
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Abstract

Two methods were evaluated in terms of manufacturing of MAX phase preforms characterized with open porosity: microwave-assisted self-propagating high-temperature synthesis (SHS) and spark plasma sintering (SPS). The main purpose of fabrication of such open-porous preforms is that they can be successfully applied as a reinforcement in metal matrix composite (MMC) materials. In order to simulate the most similar conditions to microwave-assisted SHS, the sintering time of SPS was significantly reduced and the pressure was maintained at a minimum value. The chosen approach allows these two methods to be compared in terms of structure homogeneity, complete reactive charge conversion and energy effectivity. Study was performed in Ti-Al-C system, in which the samples were compacted from elemental powders of Ti, Al, C in molar ratio of 2:1:1. Manufactured materials after syntheses were subjected to SEM, XRD and STEM analyses in order to investigate their microstructures and chemical compositions. As was concluded, only microwave-assisted SHS synthesis allows the creation of MAX phases in the studied system. SPS technique led only to the formation of intermetallic secondary phases. The fabrication of MAX phases’ foams by microwave-assisted SHS presents some interesting advantages compared to conventional manufacturing methods. This work presents the characterization of foams obtained by microwave-assisted SHS comparing the results with materials produced by SPS. The analysis of SPS products for different sintering temperatures provided the better insight into the synthesis of MAX phases, supporting the established mechanism. Dissimilarities in the heating mechanisms that lead to the differing synthesis products were also discussed.

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Authors and Affiliations

A. Dmitruk
ORCID: ORCID
M. Lagos
K. Naplocha
ORCID: ORCID
P. Egizabal
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Abstract

Microwave Assisted Self-propagating High-temperature Synthesis (MASHS) was used to prepare open-porous MAX phase preforms in Ti-Al-C and Ti-Si-C systems, which were further used as reinforcements for Al-Si matrix composite materials. The pretreatment of substrates was investigated to obtain open-porous cellular structures. Squeeze casting infiltration was chosen to be implemented as a method of composites manufacturing. Process parameters were adjusted in order to avoid oxidation during infiltration and to ensure the proper filling. Obtained materials were reproducible, well saturated and dense, without significant residual porosity or undesired interactions between the constituents. Based on this and the previous work of the authors, the reinforcement effect was characterized and compared for both systems. For the Al-Si+Ti-Al-C composite, an approx. 4-fold increase in hardness and instrumental Young's modulus was observed in relation to the matrix material. Compared to the matrix, Al-Si+Ti-Si-C composite improved more than 5-fold in hardness and almost 6-fold in Young's modulus. Wear resistance (established for different loads: 0.1, 0.2 and 0.5 MPa) for Al-Si+Ti-Al-C was two times higher than for the sole matrix, while for Al-Si+Ti-Si-C the improvement was up to 32%. Both composite materials exhibited approximately two times lower thermal expansion coefficients than the matrix, resulting in enhanced dimensional stability.
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Bibliography

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Authors and Affiliations

A. Dmitruk
1
ORCID: ORCID
K. Naplocha
1
ORCID: ORCID
A. Żak
2
A. Strojny-Nędza
3

  1. Wrocław University of Science and Technology, Faculty of Mechanical Engineering, Department of Lightweight Elements Engineering, Foundry and Automation, Poland
  2. Wrocław University of Science and Technology, Faculty of Chemistry, Institute of Advanced Materials, Poland
  3. Łukasiewicz Institute of Microelectronics and Photonics, Poland
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Abstract

Bending strength, thermal and electric conductivity and microstructure examinations of Cu based composite materials reinforced with Saffil alumina fibres are presented. Materials were produced by squeeze casting method applying the designed device and specially elaborated production parameters. Applying infiltration pressure of 90MPa and suitable temperature parameters provided manufacturing of copper based composite materials strengthened with Saffil alumina fibres characterized by the low rest porosity and good fibre-matrix interface. Three point bending tests at temperatures of 25, 100 and 300ºC were performed on specimens reinforced with 10, 15 and 20% of Saffil fibres. Introduced reinforcement effected on the relatively high bending strengths at elevated temperatures. In relation to unreinforced Cu casting strength of composite material Cu – 15vol.% Saffil fibres increase by about 25%, whereas at the highest applied test temperature of 300o C the improvement was almost 100%. Fibres by strengthening of the copper matrix and by transferring loads from the matrix reduce its plastic deformation and hinder the micro-crack developed during bending tests. Decreasing of thermal and electrical conductivity of Cu after incorporating fibres in the matrix are relatively small and these properties can be acceptable for electric and thermal applications.
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Authors and Affiliations

J.W. Kaczmar
K. Naplocha
K. Granat
A. Kurzawa
E. Grodzka
B. Samociuk
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Abstract

The process of investment casting of AZ91 magnesium alloy open-cell porosity foams was analysed. A basic investment casting technique was modified to enable the manufacturing of magnesium foams of chosen porosities in a safe and effective way. Various casting parameters (mould temperature, metal pouring temperature, pressure during metal pouring and solidifying) were calculated and analysed to assure complete mould filling and to minimize surface reactions with mould material. The foams manufactured with this method have been tested for their mechanical strength and collapsing behaviour. The AZ91 foams acquired in this research turned out to have very high open porosity level (>80%) and performed with Young’s modulus of ~30 MPa on average. Their collapsing mechanism has turned out to be mostly brittle. Magnesium alloy foams of such morphology may find their application in fields requiring lightweight materials of high strength to density ratio or of high energy absorption properties, as well as in biomedical implants due to magnesium’s high biocompatibility and its mechanical properties similar to bone tissue.
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Authors and Affiliations

H. Kapłon
1
ORCID: ORCID
A. Dmitruk
1
ORCID: ORCID
K. Naplocha
1
ORCID: ORCID

  1. Wroclaw University of Science and Technology, Poland
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Abstract

A method for the open-cell aluminum foams manufacturing by investment casting was presented. Among mechanical properties, compressive behaviour was investigated. The thermal performance of the fabricated foams used as heat transfer enhancers in the heat accumulator based on phase change material (paraffin) was studied during charging-discharging working cycles in terms of temperature distribution. The influence of the foam on the thermal conductivity of the system was examined, revealing a two-fold increase in comparison to the pure PCM. The proposed castings were subjected to cyclic stresses during PCM’s subsequent contraction and expansion, while any casting defects present in the structure may deteriorate their durability. The manufactured heat transfers enhancers were found suitable for up to several dozen of cycles. The applied solution helped to facilitate the heat transfer resulting in more homogeneous temperature distribution and reduction of the charging period’s duration.
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Authors and Affiliations

A. Dmitruk
1
ORCID: ORCID
H. Kapłon
1
ORCID: ORCID
K. Naplocha
1
ORCID: ORCID

  1. Department of Lightweight Elements Engineering, Foundry and Automation, Faculty of Mechanical Engineering, Wrocław University of Science and Technology, Poland

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