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Abstract

The subject of the work are modern composite materials with increased wear resistance intended for elements of machines operating in difficult conditions in the construction and mining industries. The study determined the effect of zone reinforcement of GX120Mn13 cast steel with macroparticles (Al 2O 3+ZrO 2) on the corrosion resistance and abrasion wear of the composite thus obtained. SEM studies have shown that at interface between two phases, and more precisely on the surface of particles (Al 2O 3+ZrO 2) a durable diffusion layers are formed. During the corrosion tests, no significant differences were found between the obtained parameters defining the corrosion processes of GX120Mn13 cast steel and GX120Mn13 with particles (Al 2O 3+ZrO 2) composite. No intergranular corrosion was observed in the matrix of the composite material, nor traces of pitting corrosion at both phases interface. This is very important in terms of tested material’s service life. Reinforcement of cast steel with particles (Al 2O 3+ZrO 2) resulted in a very significant improvement in the abrasion resistance of the composite – by about 70%. After corrosion tests, both materials were subjected to further operational investigations. These examinations consisted in determining the impact of corrosion processes on the durability of the composite in terms of abrasion. The obtained results indicate that corrosion processes did not significantly deteriorate the wear resistance of both the cast steel and the composite.
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Bibliography

[1] Uetz, H. (1986). Abrasion and Erosion. Munich–Vienna: Carl Hanser Verlag Publ.
[2] Hebda, M., Wachal, A. (1980). Trybology. Warsaw: Scientific and Technical Publ (in Polish).
[3] Kalandyk, B., Zapała, R., Kasińska, J. & Madej, M. (2021). Evaluation of microstructure and tribological propertiesof GX120Mn13 and GX120MnCr18-2 cast steels. Archives of Foundry Engineering. 21(4), 67-76. DOI: 10.24425/afe.2021.138681.
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[6] Kaczmar, J., Janus, A., Samsonowicz, Z. (1998). Influence of technological parameters on the production of selected parts of machines reinforced with ceramic fibers. Report of Institute of Machine and Automation Technology, Wroclaw University of Science and Technology, Series SPR, 35 (in Polish). [7] Kurzawa, A., Kaczmar, J.W. & Janus, A. (2008). Selected mechanical properties of aluminum composite materials reinforced with SiC particles. Archives of Foundry Engineering. 8(2), 99-102.
[8] Kaczmar, J.W. & Kurzawa, A. (2012). The effect of α-alumina particles on the properties of EN AC-44200 Al alloy based composite materials. Journal of Achievements in Materials and Manufacturing Engineering. 55(1), 39-44.
[9] Jach, K., Pietrzak K., Wajler, A., Sidorowicz, A. & Brykała, U. (2013). Application of ceramic preforms to the manufacturing of ceramic – metal composites. Archives of Metallurgy and Materials, 58(4), 1425-1428. DOI: 10.2478/amm-2013-0188.
[10] Gawroński, J., Szajnar, J. & Wróbel, P. (2004). Study on theoretical bases of receiving composite alloy layers on surface of cast steel castings. Journal of Materials Processing Technology. 157, 679-682. DOI: 10.1016/j.jmatprotec.2004.07.153.
[11] Szajnar, J., Walasek, A., & Baron, C. (2013). Tribological and corrosive properties of the parts of machines with surface alloy layer. Archives of Metallurgy and Materials. 58(3), 931-936. DOI: 10.2478/amm-2013-0104.
[12] Hryniewicz, T., Rokosz, K. (2010). Theoretical basis and practical aspects of corrosion. Koszalin: Publ. House of Koszalin University of Technology (in Polish).
[13] Medyński, D. & Chęcmanowski, J. (2022). Corrosion resistance of L120G13 steel castings zone-Reinforced with Al2O3. Materials. 15(12), 4090, 1-14. https://doi.org/10.3390/ma15124090.
[14] Song, Y., Jiang, G., Chen, Y., Zhao, P. & Tian, Y. (2017). Effects of chloride ions on corrosion of ductile iron and carbon steel in soil environments. Scientific Reports. 7, 6865, 1-13. https://doi.org/10.1038/s41598-017-07245-1.

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Authors and Affiliations

Daniel Medyński
1
ORCID: ORCID

  1. Witelon Collegium State University, Poland
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Abstract

Results of a research on influence of chromium, molybdenum and aluminium on structure and selected mechanical properties of Ni-Mn-Cu cast iron in the as-cast and heat-treated conditions are presented. All raw castings showed austenitic matrix with relatively low hardness, making the material machinable. Additions of chromium and molybdenum resulted in higher inclination to hard spots. However, a small addition of aluminium slightly limited this tendency. Heat treatment consisting in soaking the castings at 500 °C for 4 h resulted in partial transformation of austenite to acicular, carbon-supersaturated ferrite, similar to the bainitic ferrite. A degree of this transformation depended not only on the nickel equivalent value (its lower value resulted in higher transformation degree), but also on concentrations of Cr and Mo (transformation degree increased with increasing total concentration of both elements). The castings with the highest hard spots degree showed the highest hardness, while hardness increase, caused by heat treatment, was the largest in the castings with the highest austenite transformation degree. Addition of Cr and Mo resulted in lower thermodynamic stability of austenite, so it appeared a favourable solution. For this reason, the castings containing the highest total amount of Cr and Mo with an addition of 0.4% Al (to reduce hard spots tendency) showed the highest tensile strength.

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Authors and Affiliations

Daniel Medyński
ORCID: ORCID
A. Janus
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Abstract

The paper presents results of research on steel castings GX120Mn13 (L120G13 by PN-89/H-83160), zone-reinforced by elektrocorundum particles (Al2O3), with a grain size from 2 to 3.5 mm. Studies revealed continuity at interface between composite components and formation of a diffusion zone in the surface layer of electrocorundum grains. In the area of this zone, simple manganese segregation and reverse iron and chromium segregation were found. The transfer of these elements from cast steel to electrocorundum grains resulted superficial depletion in aluminum and oxygen in this area. No porosity was observed at the interface between two components of the composite. We found it very beneficial from an exploitation point of view, as confirmed by the study of resistance to abrasive wear.
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Bibliography

[1] Matthews, F.L., Rawlings, R.D. (1999). Composite Materials. Engineering and Science. CRC Press: Boca Raton, FL, USA.
[2] Kocich, R., Kunčická, L., Král, P. & Strunz, P. (2018). Characterization of innovative rotary swaged Cu-Al clad composite wire conductors. Materials Design. 160, 828-835. Materials 2020. 13, 4161, p. 13 of 15.
[3] Kunčická, L., Kocich, R., Dvořák, K. & Macháčková, A. (2019). Rotary swaged laminated Cu-Al composites. Effect of structure on residual stress and mechanical and electric properties. Materials Science Engineering A. 742, 743-750.
[4] Kunčická, L., Kocich, R. (2018) Deformation behaviour of Cu-Al clad composites produced by rotary swaging. IOP Conf. Ser. Mater. Sci. Eng. 369, Kitakyushu City, Japan.
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[10] Kaczmar, J., Janus, A., Samsonowicz, Z. (1997). Influence of technological parameters on production of selected machine parts reinforced with ceramic fibers. Reports of Institute of Machine Technology and Automation of Wrocław University of Science and Technology. SPR No 5.
[11] Kaczmar, J., Janus, A., Kurzawa, A. (2002). Development of basics technology of manufacturing machine and device parts from aluminum composites reinforced with zones of ceramic particles. Reports of Institute of Machine Technology and Automation of Wrocław University of Science and Technology. SPR No 11.
[12] Dmitruk, A.G., Naplocha, K., Żak, A. M., Strojny-Nędza, A., Dieringa, H. & Kainer, K. (2019). Development of pore-free Ti-Si-C MAX/Al-Si composite materials manufactured by squeeze casting infiltration. Journal of Materials Engineering and Performance. 28(10), 6248-6257.
[13] Maj, J., Basista, M., Węglewski, W., Bochenek, K., Strojny-Nędza, A., Naplocha, K., Panzner, T., Tatarková, M., Fiori, F. (2018). Effect of microstructure on mechanical properties and residual stresses in interpenetrating aluminum-alumina composites fabricated by squeeze casting. Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing. 715,154-162.
[14] Szajnar, J., Wróbel, P., Wróbel, T. (2008). Model castings with composite surface layer - application. Archive of Foudry Enginnering. 8(3), 105-110.
[15] Gawroński, J., Szajnar, J., Wróbel, P. (2005). Surface composite layers of cast iron - ceramic particles. Archive of Foundry. 5(17), 107-114.
[16] Marcinkowska, J. (1986). Wear-resistant casting coatings on cast steel. Solidification of Metals and Alloys. 6, 37-42.
[17] Baron, Cz., Gawroński, J. (2006). Abrasive wear resistance of sandwich composites based on iron alloys. Composites. 6(3), 45-49.
[18] Operation and maintenance documentation of test stand T-07.
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Authors and Affiliations

Daniel Medyński
ORCID: ORCID
A.J. Janus
1

  1. Witelon State University of Applied Science in Legnica ul. Sejmowa 5A, 59 – 220 Legnica, Poland

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