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Number of results: 13
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Abstract

Al2O3-Al2TiO5-TiO2 composites can be obtained by the infiltration of molecular titanium precursors into presintered α-Al2O3 (corundum) cylinders. Two titanium tetraalkoxides, and two dialkoxy titanium bis(acetylacetonates) serve as precursors for TiO2 (rutile) and Al2TiO5 (tialite). The precursors were infiltrated as ethanolic solutions. After sintering at 1550, 1600, and 1650°C, the prepared ceramics’ properties were investigated by SEM, in-situ HT-XRD, and conventional XRD. Titanium tetraisopropoxide leads to the highest content of Al2TiO5 in the composite. The more reactive the precursor, considering the Al2O3/precursor interface, the lower and more anisotropic the grain growth, the more homogeneous is the TiO2 contribution and the higher is the content of Al2TiO5. Raising the sintering temperature causes an increase of the crystalline Al2TiO5 con­tent as well as of the grain growth. Moreover, the reactivity of the precursor molecule influences the Ti/(Al + Ti) ratio in the obtained tialite phase.

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Authors and Affiliations

B. Dittert
M. Wiessner
P. Angerer
J.M. Lackner
H. Leichtfried
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Abstract

The work presents a computer simulation realized with the ADINA program concerning nanoindendation test. A shape of nanoindenter was proposed to be similar to the real surgical tools. The theoretical model was used to predict phenomena which would appear in practice. The contribution of the TiN coating thickness to the implant rigid properties was simulated. Three types of extortion conditions could be considered, i.e., short contact with surgery tool (i); long continuous contact with natural tissue (ii); long cyclic contact with natural tissue (iii). In the first part of the work, the authors focused on the first type of extortion (i). The second part of the work is dedicated to the calculations of temperature impact to layer behaviour. Two layer thicknesses are considered i.e., 250 nm and 50 nm. The examined coatings find serious practical applications as a blood-contacting material in medicine. The coatings were subjected to transmission electron microscopy investigations. Columnar mechanism of film growth controlled by kinetic process is stated to operate for the considered range of layer thickness. Plasma temperature is observed to influence the substrate behaviour. Examinations of thinner layers, i.e. under 100nm, revealed higher degree of smoothness and uniformity, which could be related to the operation of the surface diffusion mechanism at the early stage of deposition. The physical explanation of TEM images was based on the finite element calculations of the temperature distribution using the ADINA program .

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Authors and Affiliations

R. Major
P. Lacki
J.M. Lackner
B. Major
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Abstract

Mechanical components and tools in modern industry are facing increasing performance requirements leading to the growing need for advanced materials and thus, for modern frictional systems. In the last decades, the Pulsed Laser Deposition (PLD) has emerged as an unique tool to grow high quality mono- as well as multilayers surfaces in metallic/ceramic systems. Building up a knowledge base of tribological properties of industrially-scaled, room temperature deposited PLD hard coatings are the most important step for the application of these coatings in engineering design. Although single-layer coatings find a range of applications, there are an increasing number of applications where the properties of a single material are not sufficient. One way to surmount this problem is to use a multilayer coating. Application of metallic interlayers improves adhesion of nitride hard layer in multilayer systems, which has been used in PVD processes for many years, however, the PLD technique gives new possibilities to produce system comprising many bilayers at room temperature. Tribological coatings consisted of 2, 4 and 16 bilayers of Cr/CrN and Ti/TiN type were fabricated with the Pulsed Laser Deposition (PLD) technique in the presented work. It is found in transmission electron examinations on thin foils prepared from cross-section that both nitride-based multilayer structures studied are characterized by small columnar crystallite sizes and high defect density, what might rise their hardness but compromise coating adhesion. The intermediate metallic layers contained larger sized and less defective columnar structure compared to the nitride layers, which should improve the coatings toughness. Switching from single layer to multi-layer metal/nitride composition improved resistance to delamination.

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Authors and Affiliations

J.M. Lackner
W. Waldhauser
L. Major
J. Morgiel
M. Kot
B. Major
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Abstract

Titanium nitride (TiN) is regarded as a potential biomaterial for blood-contact applications. TiN thin films were fabricated by pulsed

laser deposition with the Nd:YAG laser on biologically applied polyurethane. Transmission electron microscopy (TEM) study of 250 nm thick films revealed columnar structure. Such films were observed to be brittle, which led to crack formation and secondary nucleation of microcolumn. TEM studies showed a kinetic mechanism of growth (columnar) in films of 250 nm thickness. It was stated that thinner films were much smoother and uniform than the thicker ones, which could be associated with the surface diffusion mechanism to appear. In order to improve the coatings elasticity, the thickness was reduced to 50 nm, which limited the deposition mechanism operation to the early stage. TEM cross-section observation revealed elastic properties of thin films. A biological test showed that TiN surface film produced on polyurethane is characterized by good biocompatibility and decreased surface affinity for cell adhesion. Films of 0.25 and 0.5 1m thick of TiN were selected for theoretical finite element modelling (FEM) using ADINA program. The micro cracks formation predicted in simulation was verified by phenomena observed in microstructure examinations.

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Authors and Affiliations

R. Ebner
J.M. Lackner
W. Waldhauser
R. Major
E. Czarnowska
R. Kustosz
P. Lacki
B. Major
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Abstract

Hybryd PLD method was used for deposition high quality thin Ti, TiN, Ti(C,N) and DLC coatings. The kinetic energy of the evaporated particles was controlled by application of variation of different reactive and non reactive atmospheres during deposition. The purpose was to improve adhesion by building a bridge between the real ceramic coating and the substrate. A new layer composition layout was proposed by application of a buffer, starting layer. Advanced HRTEM investigation based on high resolution transmission electron microscopy was used to reveal structure dependence on specific atmosphere in the reactive chamber. New experimental technique to examine the crystallographic orientation based on X-ray texture tomography was applied to estimate contribution of the atmosphere to crystal orientation. Using Dictyostelium discoideum cells as a model organism for specific and nonspecific adhesion, kinetics of shear flow-induced cell detachment was studied. For a given cell, detachment occurs for critical stress values caused by the applied hydrodynamic pressure above a threshold. Cells are then removed from the substrate with an apparent first-order rate reaction that strongly depends on the stress. The threshold stress depends on cell size and physicochemical properties of the substrate, but it is not affected by depolymerization of the actin and tubulin cytoskeleton.

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Authors and Affiliations

R. Major
F. Bruckert
J.M. Lackner
W. Waldhauser
M. Pietrzyk
B. Major

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