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Abstract

The paper was focused on the reconstruction of past-environmental conditions dynamics based on the geochemical characteristics of sediments filling kettle-hole located in the western part of the Kashubian Lakeland, North Poland). Stratigraphic variability of lithogeochemical constituents and a set of 13 elements (TOC, N, P, Na, Ca, Mg, K, Al, Fe, Mn, Cu, Ni, Zn) were applied for Holocene reconstruction of certain processes and conditions in the studied kettle-hole. The detailed geochemical analysis allowed us to identify 6 phases in its development: Masz-1 stage covering sedimentation of sedge-moss peat over melting dead ice at the turn of the Preboreal and Boreal periods; Masz-2 stage of the initial phase of lake development with deep-water sedimentation; Late Boreal and Atlantic stage Masz-3 related to sedimentation of lacustrine chalk; Subboreal stage Masz-4 representing the beginning of lake terrestrialization; Subatlantic stage Masz-5 of lowland bog, and Masz-6 stage covering final phase of peatland evolution due to human activity. Principle component analysis highlighted the importance of two major factors controlling the geochemical variability of the studied sediments. These are the varied origin of supplying water reflected in the sedimentation of organic-calcareous sediments (PC1), and oxidative-reduction conditions determined by water level fluctuations (PC2).
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Authors and Affiliations

Adam Wojciechowski
1
Jerzy Jonczak
2

  1. Pomeranian University Institute of Biology and Earth Sciences, Partyzantów 27, 76-200 Słupsk, Poland
  2. Warsaw University of Life Sciences, Department of Soil Science, Nowoursynowska 159, 02-776, Warsaw, Poland
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Abstract

The concentrations of Cu, Mn, Ni and Zn in the soil and litterfall, as well as influx of the elements to the soils with litterfall were studied in a mixed beech-pine-spruce stand in northern Poland during the years 2007–2009. Annual influx of litterfall to the soil amounted from 3.234 to 4.871 t/ha. Beech, pine and spruce litterfall contributed in total litterfall in 50.8−70.1%, 11.4−11.9% and 1.6−24.0% respectively. The following average annual concentrations of heavy metals in total litterfall during the 3-year study period were noticed: 2469.3–3469.2 mg Mn/kg, 153.6–160.8 mg/kg Zn, 8.0–14.3 mg Ni/kg and 5.0–6.8 mg Cu/kg. In general, the concentrations of Mn and Cu were higher in beech litterfall in comparison to pine and spruce. The contents of Zn and Ni in beech, pine and spruce litterfall were comparable. Annual influx of metals to the soil with litterfall was: 10341.6–14422.4 g/ha Mn, 460.3–748.1 g/ha Zn, 37.4–66.6 g/ha Ni and 20.2–31.8 g/ha Cu. The fluxes were higher for Mn, Zn and Ni, and comparable for Cu in relation to those observed in other beech, pine, spruce and mixed stands in northern Europe.
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Authors and Affiliations

Agnieszka Parzych
Jerzy Jonczak
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Abstract

The paper presents the results of study on heavy metals in needles of Pinus sylvestris in selected pine forests in Słowiński National Park. It was evidenced that heavy metal contents (Zn, Cu, Mn and Fe) in needles of Pinus sylvestris varied depending on the metal, the age of the needles and the humidity of a forest complex. Variation coefficients of such metals remained at the level of: 13-30% (Zn), 3-6% (Cu), 13-34% (Mn) and 12-30% (Fe) depending on the age of the needles. In the case of Zn, Mn and Fe higher concentrations of researched metal were found in the 2-year-old needles than in 1 year old needles, and in the case of Cu in 1 year old needles than in 2-year-old needles. The increase of zinc concentration found in 1-year-old needles after rainfall sums was (Bw, r = 0.67, p < 0.05, n = 24) and (Bśw, r = 0.39, p < 0.05, n = 24) in 2-year-old needles. The content of the above mentioned metals in needles of dry coniferous forests (Bs), fresh coniferous forests (Bśw) and humid coniferous forests (Bw) of the ground cover constitute the following decreasing series: Mn(323.8) > Fe(103.4) > Zn(65.5) > Cu(5.9).

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Authors and Affiliations

Agnieszka Parzych
Jerzy Jonczak

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