Search results

Filters

  • Journals
  • Authors
  • Keywords
  • Date
  • Type

Search results

Number of results: 3
items per page: 25 50 75
Sort by:
Download PDF Download RIS Download Bibtex

Abstract

This work determined the solid-water distribution coefficient Kd, the Freundlich constant KF and the organic carbon normalized coefficient K0c of ibuprofen in natural, aquifer sediments. They are characterized as silt sediments with different clay and sand fraction contents varied in specific surface areas. Content of organic carbon and pH are on the same level. For determining sorption coefficients values of ibuprofen in sediments, its concentration was measured in the aqueous and calculated in the solid phase. Batch tests were conducted following OECD Guideline 106. The resulting Kd values ranged between 1.14 and 2.29 L/kg, ~ between 0.25 and 5.48 and Koc between 1.22 and 2.53 for ibuprofen in sediments SI and S2, respectively. These experiments proved that the presence of clay minerals beside organic carbon and pH might be relevant in sorption of ibuprofen in sediments. A comparison of experimentally determined Koc with modelled Koc calculated on the base of octanol-water partitioning coefficient K0w shows that the prediction of sorption behaviour cannot be based only on Kow· This is probably due to the fact that these approaches well describe hydrophobic interactions, but fail to predict sorption of polar and ionic compounds.
Go to article

Authors and Affiliations

Katarzyna Styszko
Katarzyna Sosonowska
Piotr Wojtanowicz
Janusz Gołaś
Jerzy Górecki
Mariusz Macherzyński
ORCID: ORCID
Download PDF Download RIS Download Bibtex

Abstract

In the study we have focused on the distribution of several metals (Cr, As, Pb) and anions (Cr, NO3-) and their partition between pore (interstitial) waters and sediments sampled at three stations at the Dobczyce Reservoir which supplies the drinking water to inhabitants from the city of Kraków and its agglomeration. The results show considerable increase in concentrations of Pb and As in pore water samples, when compared to the bottom waters. Meaningful alternations in concentration were observed in case of pore water samples (Pb, As) and sediments (Cr, Pb, As), coming from three stations and their lateral sections. The possible relations between this phenomenon and the sediment characteristic as well as the Fe and Ca content, has been studied. Some comments on the seasonal variations of anion contents in water and pore water samples, are also provided. It was found that nitrates and sulphates show considerable variations.
Go to article

Authors and Affiliations

Mariusz Macherzyński
ORCID: ORCID
Witold Reczyński
J. Sanecki
Jerzy Górecki
Janusz Gołaś

This page uses 'cookies'. Learn more