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Abstract

“Mineral deposit model”, “deposit modelling” are the terms commonly used, although imprecise. This is often identified as the application of computerized methods to the elaboration and presentation of geological information, in particular for the mining design. Deposit modelling is the mode of presentation of deposit features, which in the meaning of the authors of such presentation, describes the deposit features between the points of observations as best as possible. Deposit modelling has a long history (XVI-XVII centuries), however such a term was not used. Varied methods of cartographic presentation of deposits and their features were proposed. The progress in the presentation of the deposit in space using isolines maps has led to the separation of methods of deposits geometrisation. Over time, a simple mathematical statistics method was used to describe the deposit parameters, followed by geostatistical methods. Some of them were however not commonly used as too troublesome. The computer based approach to the presentation of geological data has an unquestionable value but is accompanied by the possibility of inappropriate formalized and erroneous interpretations and a presentation as to whether the basic rules of geological knowledge were neglected. Deposits modeling is a conceptual task and cannot be fully automated.

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Authors and Affiliations

Edyta Sermet
Jerzy Górecki
Marek Nieć
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Abstract

This work determined the solid-water distribution coefficient Kd, the Freundlich constant KF and the organic carbon normalized coefficient K0c of ibuprofen in natural, aquifer sediments. They are characterized as silt sediments with different clay and sand fraction contents varied in specific surface areas. Content of organic carbon and pH are on the same level. For determining sorption coefficients values of ibuprofen in sediments, its concentration was measured in the aqueous and calculated in the solid phase. Batch tests were conducted following OECD Guideline 106. The resulting Kd values ranged between 1.14 and 2.29 L/kg, ~ between 0.25 and 5.48 and Koc between 1.22 and 2.53 for ibuprofen in sediments SI and S2, respectively. These experiments proved that the presence of clay minerals beside organic carbon and pH might be relevant in sorption of ibuprofen in sediments. A comparison of experimentally determined Koc with modelled Koc calculated on the base of octanol-water partitioning coefficient K0w shows that the prediction of sorption behaviour cannot be based only on Kow· This is probably due to the fact that these approaches well describe hydrophobic interactions, but fail to predict sorption of polar and ionic compounds.
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Authors and Affiliations

Katarzyna Styszko
Katarzyna Sosonowska
Piotr Wojtanowicz
Janusz Gołaś
Jerzy Górecki
Mariusz Macherzyński
ORCID: ORCID
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Abstract

In the study we have focused on the distribution of several metals (Cr, As, Pb) and anions (Cr, NO3-) and their partition between pore (interstitial) waters and sediments sampled at three stations at the Dobczyce Reservoir which supplies the drinking water to inhabitants from the city of Kraków and its agglomeration. The results show considerable increase in concentrations of Pb and As in pore water samples, when compared to the bottom waters. Meaningful alternations in concentration were observed in case of pore water samples (Pb, As) and sediments (Cr, Pb, As), coming from three stations and their lateral sections. The possible relations between this phenomenon and the sediment characteristic as well as the Fe and Ca content, has been studied. Some comments on the seasonal variations of anion contents in water and pore water samples, are also provided. It was found that nitrates and sulphates show considerable variations.
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Authors and Affiliations

Mariusz Macherzyński
ORCID: ORCID
Witold Reczyński
J. Sanecki
Jerzy Górecki
Janusz Gołaś

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