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Number of results: 5
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Abstract

Composting of municipal solid waste with a 1 % addition of pulverized metallic iron, iron oxide(III) and iron sulfide(II) has been carried out. The amounts of iron in the bioavailable forms have been assayed in the composts obtained by means of speciation analysis, and the influence of composting on iron mobility has been evaluated. It has been found that pulverized metallic iron introduced into the waste occurs in the compost in the fractions easily accessible to plants, mainly the carbonate fraction. In the waste contaminated with Fe203 iron remains in the residual fraction, and composting does not practically increase its mobility. Over half of the iron from FeS remains in the waste in the residual fraction however, after composting there was an increased iron concentration in the bioavailable carbonate fraction.
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Authors and Affiliations

Jerzy Ciba
Maria Zolotajkin
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Abstract

Water and bottom sediment samples collected from a few fish-breeding ponds/reservoirs were subjected to tests. The aim of this paper was to determine the total content of aluminium and its fractions in the samples tested to estimate the potential risk to fish caused by the toxic forms of aluminium. The monomeric inorganic aluminium in waters was determined using the ion exchange and extraction-colorimetric method with oxychinoline according to Barnes's-Driscoll's procedure. The bottoms were fractionated using a three-step sequential extraction procedure and the microwave mineralisation. The total content of aluminium in waters and extracts was determined using the spectrophotometric method with eriochromocyanine R, and comparatively using the ICP OES technique. The results were subjected to statistical analysis. The level of concentration of labile Al in the waters about 26-34 μg/dm3 and content of exchangeable Al 5-34 mg/g range in bottom sediments are possibly hazardous to aquatic organisms.

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Authors and Affiliations

Joanna Kluczka
Maria Zołotajkin
Jerzy Ciba
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Abstract

The research was carried out on two different industrial wastes deposited on the premises of a chemical plant: used graphite electrode after electrolysis of brine applying the mercury-cathode method and coal catalyst past the usage period after the synthesis of vinyl chloride. The need for utilization of the waste necessitated development of a fast and reliable procedure for mercury determination. We have found procedures for mineralization of coal samples and determination of small concentrations of mercury by the cold vapour of atomic absorption spectrometry (CV AAS) in the available literature. Six procedures for passing mercury from the examined waste into solutions were tested, and mercury was assayed using the titration method of Wickbold and CV AAS. The results were evaluated statistically. It has been found that four ways to mineralize the examined industrial waste samples can be used.
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Authors and Affiliations

Jerzy Ciba
Joanna Kluczka
Maria Zolotajkin
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Abstract

The research of the soil quality was made in Markowice, the district of Racibórz, the town situated in the South of Poland. The soils of Racibórz were expected to be contaminated with heavy metals after the heavy flood in 1997, which devastated great part of Poland, especially the town. The assays covered macroand microcomponents, contents of total calcium, iron, manganese, sulphur, bioavailable magnesium, potassium and phosphorus, contents of heavy metals (lead, cadmium, zinc, chromium, nickel and copper), electrolytic conductivity, pH of soil, and finally organic matter content in soil. The research showed that soils of the district of Racibórz have a natural content of heavy metals, but the soils have the deficiency of macrocornponcnts, such as phosphorus, magnesium and calcium.
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Authors and Affiliations

Ewa Cebula
Jan Cebula
Jerzy Ciba
Bronisław Wyżgolik
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Abstract

The total content of lead in soil from the battery plant site was determined and a speciation analysis of this element was carried out using Rudd's method of sequential extraction. It was found out that lead is present in soil samples mostly in a low mobility organically bound form, which under certain conditions can, however, be absorbed by plants, and in a moderately mobile carbonate form. Lead was extracted from soil using sodium salt of ethylenediaminetetraacetic acid and sodium hydroxide solution and tests were also conducted to separate it from leaching solutions electrochemically. Extraction with Na2 -EDTA solution makes it possible to remove 86% of lead from soil, but the solution shows much lower lead extraction power when used for renewed leaching after having been electrochemically freed of lead. Extraction with NaOH solution gives worse results, namely only 70% of lead can be removed from soil, but the solution after having been electrochemically freed of Pb shows higher Pb leaching power when used for renewed leaching than in the case of Na2 - EDTA solution.
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Authors and Affiliations

Teofil Korolewicz
Marian Turek
ORCID: ORCID
Jerzy Ciba

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