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Abstract

Studies on biocompatibility of AISI 316LVM steel indicate the need to eliminate the nickel from the surface and replace it with other elements of improved biocompatibility. Therefore, in the presented work selected physicochemical and mechanical properties of the diffusive nitrocarburized layer formed by plasma potential by means of an active screen made of the Fe-Cr-Ni were studied. In the paper we present results of microstructure and phase composition of the layers, roughness, and surface wettability, potentiodynamic pitting corrosion resistance, penetration of ions into the solution as well as mechanical properties. The studies were conducted for the samples of both mechanically polished and nitrocarburized surfaces, after sterilization, and exposure to the Ringer’s solution. Deposition of the nitrocarburized layer increased the contact angle, surface roughness, surface hardness, and corrosion resistance with respect to the polished surfaces. The nitrocarburized layer is a barrier against the ions release into the solution and sterilization and exposure to Ringer solution. The obtained results showed beneficial increase of both mechanical and electrochemical properties of the deposited layer, and thus the applicability of the proposed method of surface treatment of the 316LVM steel for short-term implants after sterylization.

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Authors and Affiliations

A. Kajzer
K. Rabij
M. Basiaga
K. Nowińska
M. Kaczmarek
T. Borowski
T. Wierzchoń
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Abstract

Nitrogen-doped DLC (diamond-like carbon) coatings were produced on 316L nitrided austenitic steel in direct current and pulsed glow discharge conditions. The chemical composition, surface topography, hardness and corrosion resistance of the obtained carbon coatings were examined. The coatings varied in surface morphology, roughness and hardness. Direct current glow discharge made it possible to produce a coating characterized by lower hardness, greater thickness and higher nitrogen content. The coating featured improved corrosion resistance and adhesion compared to coatings produced in the pulsed process.

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Authors and Affiliations

T. Borowski
ORCID: ORCID
M. Spychalski
ORCID: ORCID
K. Rożniatowski
ORCID: ORCID
K. Kulikowski
ORCID: ORCID
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Abstract

AISI 316L steel was subjected to nitrocarburizing under glow discharge conditions, which was followed by DLC (diamond-like carbon) coatings deposition using the same device. The coatings were applied under conditions of direct current and pulsed glow discharge. In order to determine the influence of the produced nitrocarbon austenite layer and the type of discharge on the microstructure and mechanical properties of the coatings, the following features were analysed: surface roughness, coating thickness, structure, chemical composition, adhesion and resistance to frictional wear. For comparison purposes, DLC coatings were also deposited on steel without a nitrocarburised layer. The obtained results indicate a significant influence of the type of glow discharge on the roughness, hardness, nitrogen content and of the nitrocarburised layer on the resistance to wear by friction and adhesion of the produced coatings.
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Authors and Affiliations

T. Borowski
1
ORCID: ORCID
K. Kulikowski
1
ORCID: ORCID
M. Spychalski
1
ORCID: ORCID
K. Rożniatowski
1
ORCID: ORCID
B. Rajchel
2
B. Adamczyk-Cieślak
1
ORCID: ORCID
T. Wierzchoń
1
ORCID: ORCID

  1. Warsaw University of Technology, Faculty of Materials Science and Engineering, 141 Wołoska Str., 02-507 Warszawa, Poland
  2. Polish Academy of Sciences, Institute of Nuclear Physics, Poland

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