The aim of the study was to evaluate the degree of pollution of bottom sediments from small water reservoirs with heavy metals on the basis of geochemical criteria: the enrichment factor and the geo-accumulation index. The investigations concerned sediment from eight small water reservoirs located in the Kielce Highland. Selected heavy metals, including cadmium, chromium, copper, lead and zinc, were determined using inductively coupled plasma-atomic emission spectrometry method. Additionally, particle size distribution and the content of organic matter expressed as loss of ignition were designated. The concentration of heavy metals in sediments was characterized by a great variety. The sediments of Morawica and Rejów show very high and extremely high enrichment in Cr, Zn, Pb and Cd. The values of EF>20 indicate also an extremely high enrichment in Cd of sediments in Mostki. In addition, over 50% of the samples of sediment from Suchedniów, Kaniów, Mostki and Jaśle reservoirs (the value of EF for Cr exceeded 5) indicate a moderately high enrichment of this element. Results of the analysis of the I_geo values indicate that the tested sediments are characterized by moderately high (2<I_geo<3) or high (3<I_geo<4) pollution. The differences in individual enrichment factor and geoaccumulation index values may result in the nature of heavy metals, their pollution loads, as well as speciation forms of trace elements occurrence in sediment-water complex. These findings indicate that the integration of geochemical methods is necessary for an appropriate ecological risk assessment of heavy metals in bottom sediments.

Drawing on the stressor–emotion model, the study examines the mechanisms of counterproductive work behavior (CWB) development: specifically (1) the direct effect of job stressor (bullying at work); (2) the moderation effect of the Dark Triad (DT) and job control (JC); and (3) the moderated moderation effect (DT x JC) on the job stressor–CWB link. Data were collected among 763 white- and blue-collar workers. The hypotheses were tested by means of the PROCESS method. As expected in the hypotheses, high job stressor was directly related to high CWB, and DT moderated (increased) the link. JC also moderated the job stressor–CWB link, but the moderation effect was in a direction opposite to expectations. High job control participants were more likely to report CWB when they reported a high level of the stressors. The moderated moderation effect was supported. JC increases the moderation effect of DT on the job stressor–CWB link. The highest level of CWB was observed when DT and JC were high. The findings provide further insight into processes leading to the development of CWB.