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Abstract

For ages, concrete has been used to construct underwater structures. Concrete laying underwater is a very complex procedure important to the success or failure of underwater projects. This paper elucidates the influence of alkali activator ratios on geopolymers for underwater concreting; focusing on the geopolymer concrete synthesized from fly ash and kaolin activated using sodium hydroxide and sodium silicate solutions. The geopolymer mixtures were designed to incorporate multiple alkali activator ratios to evaluate their effects on the resulting geopolymers’ properties. The fresh concrete was molded into 50 mm cubes in seawater using the tremie method and tested for its engineering properties at 7 and 28 days (curing). The control geopolymer and underwater geopolymers’ mechanical properties, such as compressive strength, water absorption density, and setting time were also determined. The differences between the control geopolymer and underwater geopolymer were determined using phase analysis and functional group analysis. The results show that the geopolymer samples were optimally strengthened at a 2.5 alkali activator ratio, and the mechanical properties of the control geopolymer exceeded that of the underwater geopolymer. However, the underwater geopolymer was determined to be suitable for use as underwater concreting material as it retains 70% strength of the control geopolymer.
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Authors and Affiliations

Fakhryna Hannanee Ahmad Zaidi
1
ORCID: ORCID
Romisuhani Ahmad
1 2
ORCID: ORCID
Mohd Mustafa Al Bakri Abdullah
3 2
ORCID: ORCID
Wan Mastura Wan Ibrahim
1 2
ORCID: ORCID
Ikmal Hakem Aziz
3 2
ORCID: ORCID
Subaer Junaidi
4
ORCID: ORCID
Salmabanu Luhar
5 2
ORCID: ORCID

  1. Universiti Malaysia Perlis, Faculty of Engineering Technology, Sungai Chuchuh, 02100 Padang Besar, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Geopolymer & Green Technology, Centre of Excellence (CEGeoGTech), Perlis, Malaysia
  3. Universiti Malaysia Perlis, Faculty of Chemical Engineering Technology, Taman Muhibbah, 02600 Jejawi, Arau, Perlis, Malaysia
  4. Universitas Negeri Makassar, Geopolymer & Green Material Group, Physics Department, FMIPA, Indonesia
  5. Frederick Research Center, P.O Box 24729, 1303 Nicosia, Cyprus
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Abstract

Fe-based PM alloy powder of Fe-2.5Ni-0.5Mo-2Cu-0.4C was pressed by high velocity compaction combined with die wall lubrication, and the effect of die wall lubrication on high velocity compaction behavior and sintering properties of the Fe-based PM alloy were studied. The results indicate that the impact force, green density, sintered density of samples increase with the augment of the impact velocity and die wall lubrication. Compared with that without die wall lubrication, the green density and sintered density of the sample with die wall lubrication are about 0.07-0.12 g/cm3 and 0.08~0.11 g/cm3 higher at the same impact velocity, respectively, while the ejection force of the die wall lubricated sample is much smaller, and reduced about 26%~36%. The green compact with die wall lubrication has much fewer porosity than that without die wall lubrication, and more mechanical bonding and cold welding regions are observed. The sintered samples mainly consists of gray pearlite and white ferrite, and more pearlite is observed in the sintered sample with die wall lubrication.

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Authors and Affiliations

Zili Liu
Dong Li
Xiqin Liu
Haohao Li
Xin Huang
Zhihao Tang
Yuwen Zou

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