This paper presents an example of practical use of Prony's method for monitoring of power waveform fundamental harmonic fluctuations, which is required for the analysis of window synchronizations in frequency analyses in power monitoring systems. The example presented offers verification of the authors' theoretical considerations published earlier in articles about Prony's method and its opportunities for practical use for real life signals. The investigations shown are based on the least squares Prony's method, which, in connection with digital filtrations, enables estimations of fundamental frequency at the rate of even tens of times per one fundamental harmonic period.