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Abstract

Kinetic studies of esterification reaction of maleic anhydride with butan-1-ol, 2-methylpropan-1-ol and butan-2-ol were carried out in a semibatch reactor, in the presence of four acidic catalysts: sulfuric acid, phosphotungstic acid, ion exchange resin Dowex 50WX8 and tetrabutyl zirconate. Phosphotungstic acid proved to be the most active catalyst. The temperature range was 383–413 K, the initial molar ratio of alcohol to acid ranged 2.2-5:1. The kinetic parameters were given. The kinetics appeared to be that of the second order with respect both to the acid and to the alcohol. The reaction carried out in the presence of tetrabutyl zirconate was very slow and depended only on acid concentration. The effect of temperature on the reaction rate follows the Arrhenius equation well.
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Authors and Affiliations

Maria Bartoszewicz
1
Maria Kulawska
2
Wiesław Organek
2

  1. Łukasiewicz Research Network – Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland
  2. Polish Academy of Sciences, Institute of Chemical Engineering, Bałtycka 5, 44-100 Gliwice, Poland
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Abstract

In the paper the results of experimental investigations concerning flat slabs made from reinforced lightweight concrete with sintered fly ash aggregate CERTYD were presented. In the research program 6 models made in a natural scale were included. The main variable parameter was slab longitudinal reinforcement ratio. The aim of investigation was the experimental verification of efficiency of double-headed studs as punching shear reinforcement. In the existing technical approvals such kind of reinforcement was allowed only in normal concrete slabs. It was demonstrated that double-headed studs can be an effective transverse reinforcement of lightweight aggregate concrete slabs. The use of double-headed studs resulted in increase in the ultimate load from 19% to 44%, depending on the slab reinforcement ratio which ranged from 0.5% to 1.2%. The comparative analysis showed that the Eurocode 2 provisions were conservative in relation to the experimental results, which were on average 42% higher than the theoretical ones however with a very low 7% coefficient of variation.

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Authors and Affiliations

M. Gołdyn
Ł. Krawczyk
W. Ryżyński
T. Urban
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Abstract

The author examines Ways of Russian Theology in Georges Florovsky works in the light of contemporary trends in epistomology and a modern understanding of intelligibility. In the 20th century attemt were undertaken to develop a project of theology that would address the current intellectual demands and at the same time be in the service of faith in Jesus Christ, the Son of God and Saviour. The currently prevailing concept of teology as an ongoing interpretation of the event of Jesus as Christ and Word of God revealed in history, recognizes an interdependece between the fundamental Christian experience (Tradition) and the historical experience of “here and now”

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Authors and Affiliations

Dymitr Romanowski

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