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Abstract

Much zinc residue is produced during the traditional processes involved in zinc hydrometallurgy in the leaching stage: its composition is complex and valuable metals are difficult to recover therefrom. If not handled properly, it can lead to a waste of resources and environmental pollution. To solve this problem, zinc leach residue specimens were treated using the carbothermal reduction method (CTR) that is easy to operate and has a high energy utilisation rate. The methods, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and scanning transmission electron microscopy (STEM) were used for analytical characterisation. Based on this, this research investigated a structure-function relationship between microstructures and microwave-absorbing properties of ZnO smoke from CTR-treated zinc leach residue. The results demonstrate that microstructures and macro-properties of ZnO smoke obtained at different temperatures differ greatly. Under conditions including a calcination temperature of 1250°C, holding time of 60 min, and addition of 50% and 10% of powdered coal and CaO separately, the ZnO content in the obtained smoke is 99.14%, with regular micron-sized ZnO particles therein. For these particles, the minimum reflection loss (RLmin) reached –25.56 dB at a frequency of 15.84 GHz with a matching thickness of 5 mm. Moreover, frequency bandwidth corresponding to RL < –10 dB can reach 2.0 GHz. ZnO smoke obtained using this method is found to have excellent microwave-absorbing performance, which provides a new idea for high-value applications of zinc-rich residue.
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Authors and Affiliations

Zhiwei Ma
1
ORCID: ORCID
Sheng Wang
1
ORCID: ORCID
Xueyan Du
1
ORCID: ORCID
Ji Zhang
1
ORCID: ORCID
Ruifeng Zhao
1
ORCID: ORCID
Shengquan Zhang
1
ORCID: ORCID

  1. Lanzhou University of Technology, State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou 730050, China
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Abstract

Paper presents results of laser welding of dissimilar joints. Flange pipe joints of austenitic TP347-HFG and low carbon S235JR steels were performed. Possibility of laser girth welding of dissimilar joints was presented. Welding of dissimilar materials are complex phenomena, chemical composition of chromium and nickel base austenitic steel with carbon amount of 0.07%, comparing to low carbon steel with trace amount of chromium, nickel and with 0.17% of carbon are different, and affect on welding result. Amount of carbon and chromium have great effect on steel phase transformation and crystallization process, which affect on material hardenability and strength characteristic. In conventional GMA welding methods solidification process of different metals is controlled by use of a selected filler material, for creating buffer zone. The main advantages of laser welding over other methods is process without an additional material, nevertheless some application may require its use. Laser welding with additional material combines advantages of both methods. To carry out weld with high strength characteristic, without welding defects, selecting chemical composition of filler wire are required. Welding parameters was obtained using numerical simulation based on Finite Element Method (FEM). Joint properties was investigated using hardness test. Metallographic analysis of obtained weld was carried out using optical microscopy and energy dispersive spectroscopy (EDS) analysis.

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Authors and Affiliations

H. Danielewski
A. Skrzypczyk
K. Mulczyk
A. Zrak

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