In this work a concept of energetic efficiency of mixing is presented and discussed; a classical definition of mixing efficiency is modified to include effects of the Schmidt number and the Reynolds number. Generalization to turbulent flows is presented as well. It is shown how the energetic efficiency of mixing as well as efficiencies of drop breakage and mass transfer in twophase liquid-liquid systems can be identified using mathematical models and test chemical reactions. New expressions for analyzing efficiency problem are applied to identify the energetic efficiency of mixing in a stirred tank, a rotor stator mixer and a microreactor. Published experimental data and new results obtained using new systems of test reactions are applied. It has been shown that the efficiency of mixing is small in popular types of reactors and mixers and thus there is some space for improvement.
The Rzeszów thrust-top basin was formed on the active Skole thrust sheet of the Outer Carpathian fold-andthrust belt and filled with Miocene syntectonic sediments. New seismic 3D, well and field data were used to define the relationship between sedimentation and tectonic activity and to establish the synkinematic context of the Rzeszów basin-fill architecture. The basin evolution was controlled by the activity of the Carpathian frontal thrust and hinterland thrusts developed in the forelimbs of folds in the Skole thrust sheet, bounding the basin from the north and south, respectively. The activity of the frontal thrust resulted in hinterland-directed depocentre migration and tilting of the syntectonic stratigraphic sequence. Balanced cross-sections have indicated that during the last compressive stage of deformation, the syntectonic deposits filling the basin were shortened by c. 5%, which resulted in the formation of folds and contractional faults. The architecture of the syntectonic deposits and the development of contractional structures reflect the activity of thrusts bounding the basin during compressive deformation of the Carpathian orogenic belt.
A theoretical approach was applied to investigate the impact of nonlinear standing waves underneath a horizontal deck. A solution was achieved by applying a boundary element method. The model was applied to predict impact pressure underneath a deck. The results show that the wave impact is a very complex momentary process. The influence of initial boundary conditions, wave parameters and deck clearance on impact pressure are analysed. The analysis shows that purely sinusoidal waves of very small amplitude may cause an impact pressure several orders of magnitude higher than a pressure arising from typical applications of a linear wave theory. The analysis shows that all these non-intuitive outcomes arise from the complexity of a wave impact process and its enormous sensitivity to initial conditions what indicates serious difficulties in a reliable prediction of a wave impact for complex wave fields or other structures. Laboratory experiments were conducted to validate theoretical results.
The genus Scutellaria L., Lamiaceae family, Scutellarioideae sub-family is known as the most important medicinal plant in the world. This research aimed to investigate the flavonoid content of seven Scutellaria species from the center, southwest, and west of Iran. Via thin layer and column chromatography, the flavonoid was extracted from leaves and then purified. To screen the flavonoid compositions, a chromatographic method was applied by liquid chromatography mass spectrometry on a triple quadrupole mass spectrometer (LC/TQMS/MS). Fingerprint analysis was implemented so as to characterize a total of 73 chemical compounds, from which 71 compounds were flavonoids belonging to different classes. Flavone with 37 derivatives possessed major values. The most abundant flavonoid compounds were observed in S. multicaulis (23 compounds) and S. patonii (22 compounds). Flavonoid composition, including apigenin, kaempferol, quercetin, and hydroxyl- flavones represented remarkable derivatives. A total of 45 flavonoids, one tannin and one anthraquinone compound, were observed to be primarily separated and identified for Scutellaria species. Moreover, six categorized chemical groups were identified in this genus and proposed as chemical barcodes. The specific chemical groups strongly provided the boundaries of Scutellaria species, the pharmacological value enhancement, breeding programs, and comprehensive documents of the species. According to the results, LC/TQMS/MS was proven a dominant method regarding genus Scutellaria.