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Abstrakt

Due to their potential to lower CO2 emissions linked with the cement and concrete industries, geopolymer binders are a desirable alternative for Portland cement binders. However, if they are to become a viable alternative to conventional Portland cement materials, their resilience in harsh conditions has to be further investigated. This paper presented mechanical and short-term durability properties of metakaolin based geopolymer concrete at sulphuric acid (H2SO4) solutions exposed with the concentrations of 2%, 3%, 4% and 5% for 14 days. (0%) or unexposed sample also prepared as referral and comparison. The geopolymer concretes were synthesized using an alkali activation of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3). The main objective of the study was to examine the durability and deterioration mechanism parameters like different acid percentages, changes in weight, compressive strength, density and water absorption. Morphology analysis also performed in this study. The results indicated that metakaolin geopolymer experienced some strength deterioration with increasing sulphuric concentration solutions which are from 32.58 MPa, 20.67 MPa and 4.25 MPa at unexposed (0%), 2% and 5% sulphuric acid immersion respectively. Furthermore, change in weight or mass loss and water absorption after the chemical attack resulted directly proportional to sulphuric acid concentration due to increment of crack on the sample. Among that, the metakaolin geopolymer submerged in 2% acid gives the optimum results in terms of durability, mechanical and physical qualities.
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Autorzy i Afiliacje

W.M.W. Ibrahim
1 2
ORCID: ORCID
M. Ibrahim
2 3
ORCID: ORCID
M.Z.A. Azis
1
ORCID: ORCID
M.M. Al B. Abdullah
2 3
ORCID: ORCID
A.S. Sauffi
2 3
ORCID: ORCID
A. Romisuhani
1 2
ORCID: ORCID
S.H. Adnan
4
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering Technology, 02600, Arau, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  3. Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  4. Universiti Tun Hussein Onn, Faculty of Engineering Technology, Pagoh, Johor, Malaysia

Abstrakt

The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.
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Autorzy i Afiliacje

M. Ibrahim
1 2
ORCID: ORCID
W.M.W. Ibrahim
2 3
ORCID: ORCID
M.M. Al B. Abdullah
1 2
ORCID: ORCID
L.H. Mahamud
1
ORCID: ORCID
M.N.N. Tajuddin
1
ORCID: ORCID
Nur Faezah Yahya
ORCID: ORCID

  1. Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, Malaysia
  2. Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, Malaysia
  3. Universiti Malaysia Perlis (UniMAP), Faculty of Mechanical Engineering Technology, 02600, Arau, Perlis, Malaysia

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