The use of biomass in the energy industry is the consequence of ongoing efforts to replace Energy from fossil fuels with energy from renewable sources. However, due to the diversity of the biomass, its use as a solid fuel generates waste with diverse and unstable chemical composition. Waste from biomass combustion is a raw material with a very diverse composition, even in the case of using only one type of biomass. The content of individual elements in fly ash from the combustion of biomass ranges from zero to tens of percent. This makes it difficult to determine the optimal recovery methods. The ashes from the combustion of biomass are most commonly used in the production of building materials and agriculture. This article presents the elemental composition of the most commonly used biomass fuels. The results of the analysis of elemental composition of fly ashes from the combustion of forest and agricultural biomass in fluidized bed boilers used in the commercial power industry were presented. These ashes are characterized by a high content of calcium (12.3–19.4%), silicon (1.2–8.3%), potassium (0.05–1.46%), chlorine (1.1–6.1%), and iron (0.8–6.5%). The discussed ashes contained no sodium. Aluminum was found only in one of the five ashes. Manganese, chromium, copper, nickel, lead, zinc, sulfur, bismuth, titanium and zirconium were found in all of the examined ashes. The analysis of elemental composition may allow for a preliminary assessment of the recovery potential of a given ash.
Humification plays an important role in stabilization of organic matter in soils of the cryolithic zone. In this context, the degree of organic matter stabilization has been assessed, using instrumental methods, for permafrost peat soils of the eastern European Arctic, based on selected plots from within the Komi Republic (Russian Federation). Humic substances (HSs) isolated from the mire permafrost peats of the forest-tundra subzone of the European Arctic have been characterized in terms of molecular composition. This was accomplished using elemental and amino acid fragments (AAFs) composition. Solid-state 13C nuclear magnetic resonance (13C NMR) spectroscopy was utilized to identify the structure of HSs. Changes in the molar x(H) : x(C) ratio, ratio of aromatic to paraffin fragments and ratio of hydroxy AAFs to heterocyclic AAFs along the peat profiles have been revealed. They are due to the activation of cryogenic processes in the upper part of the seasonally thawing layer, the natural selection of condensed humic molecules, the botanical composition and degree of degradation of peat, which reflect the climatic features of the area in the Holocene. Humic acids and fulvic acids of the peat soils showed the prevalence of compounds with a low degree of condensation and a low portion of aromatic fragments. The aromaticity degree showed the trend to increase within the depth. Changes of quantitative and qualitative parameters of specific organic compounds occur at the permafrost boundary of peatlands, which can serve as an indicator of recent climate changes in environments from the high latitudes. The presented data can be useful in the evaluation of soil organic matter stabilization degree in the active layer and below the permafrost table.
In this study, free and forced vibration responses of carbon nanotube reinforced uniform and tapered composite beams are investigated. The governing differential equations of motion of a carbon nanotube (CNT) reinforced uniform and tapered composite beams are presented in finite element formulation. The validity of the developed formulation is demonstrated by comparing the natural frequencies evaluated using present FEM with those of available in literature. Various parametric studies are also performed to investigate the effect of aspect ratio, percentage of CNT content, ply orientation, and boundary conditions on natural frequencies and mode shapes of a CNT reinforced composite beam. It was observed that the addition of carbon nanotube in fiber reinforced polymer composite (FRP) beam enhances the stiffness of the structure which consequently increases the natural frequencies and alters the mode shapes.
Humic acids, isolated from selected soils of Grønfjorden area (Spitsbergen) were investigated in terms of molecular composition and resistance of decomposition. The degree of soils organic matter stabilization has been assessed with the use of modern instrumental methods (nuclear magnetic resonance spectroscopy (CP/MAS 13C-NMR). Analysis of the humic acids showed that aromatic compounds prevail in the organic matter formed in cryoconites, located on the glaciers surfaces. The predominance of aliphatic fragments is revealed in the soils in tidal zone that form on the coastal terrace. This could be caused by sedimentation of fresh organic matter exhibiting low decomposition stage due to the harsh climate and processes of hydrogenation in the humic acids, destruction of the C-C bonds and formation of chains with a high hydrogen content. These processes result in formation of aliphatic fragments in the humic acids. In general, soils of the studied region characterizes by low stabilized soil organic matter which is indicated by low aromaticity of the HAs.
The paper presents the results of experimental-numerical tests of firing at aluminum composite materials. The test materials were manufactured by pressure infiltration of porous ceramic preforms made of -Al2O3 particles in the amount of 30% and 40% by volume. The EN AW-7075 alloy was chosen as the material matrix, and the steel 7.62×39 mm (M 43) FMJ (Full Metal Jacket) intermediate ammunition was selected for firing. In the result of the experiment, the samples were perforated with a clear difference in the muzzle diameter. The projectile with fragments caused damage to up to three reference plates placed behind the samples (witness plates) in composites with 40% of particles by volume. The mechanics of crack propagation during ballistic impacts of the projectile was characterized based on microstructure studies. Then, using numerical analysis of impact load, the examination of composite materials puncture in the ABAQUS environment was carried out. The Finite Element Method (FEM) was employed for the discretization of geometric models using Hex elements. The Johnson-Cook constitutive model describing the relationship between stress and strain in metal-ceramic composites was applied for the analyses. Numerical models were then subjected to numerical verification using smoothed particle hydrodynamics (SPH). Based on the obtained results, it was found that the hybrid FEM/SPH method correlates significantly with the experimental results.