The scope of this work is to investigate the precipitation of two Al-Mg-Si alloys with and without Cu and excess Si by using the differential scanning calorimetry (DSC), transmission electron microscopic (TEM), Vickers hardness measurement and X-ray diffraction. The analysis of the DSC curves found that the excess Si accelerate the precipitation and the alloy contain the excess Si and small addition of copper has higher aging-hardness than that of free alloy (without excess Si and Cu) at the same heat treatment condition. The sufficient holding time for the precipitation of the β'' phase was estimated to be 6 hours for the alloy aged at 100°C and 10 hours for the alloy aged at 180°C. The low Copper containing Al-Mg-Si alloy gives rise to the forming a finer distribution of β (Mg2Si) precipitates which increases the hardness of the alloy. In order to know more about the precipitation reactions, concern the peaks on the DSC curve transmission electron microscopy observation were made on samples annealed at temperatures (250°C, 290°C and 400°C) just above the corresponding peaks of the three phases β'', β' and β respectively.
Archaeometallurgical investigations presented in this work focus on analysing the microstructure as well as mechanical properties of artefacts from the17th in form of findings performed from cast iron as well as copper casts. The presented research results extend the up-to-date knowledge and present the analysis of structural compounds found in the microstructure of the artefacts from the time dating back to the late Middle Ages in the region around Czestochowa, Poland. The tested samples were found in earth in the city centre under the present marketplace. The excavation works were carried out in summer in the year 2009, and have resulted in the excavation of artefacts in form of copper block of the weight of several kg. The excavation action was led by a group of Polish archaeologists collaborating with the local authorities. The performed pre-dating of this element determines the age of the artefacts as the 17th century AD. The excavations that have been taking place since 2007 have widened the knowledge of the former Czestochowa. Historians of this town have suggested, that the found weight and traces of metallurgical activity suggest that the exposed walls were an urban weight. The weight is visible on the 18th century iconography. What was find on the Old Market indicates that there was a lush economic life before the Swedish invasion in this part of Poland. Some buildings lost their functions or were changed, others died in fires, but new places developed. To describe the microstructure, with its structural components, research was done using microscopy techniques, both of the light as well as electron microscopy (SEM), also chemical composition analysis was carried out using the EDS technique, as well as tool for phase analysis were applied in form of X-Ray Diffraction (qualitative analysis), especially for the reason to describe the phases present in the excavated material. This research will help to obtain new information in order to investigate further archaeometallurgical artefacts, extending the knowledge about middle age metallic materials its usage and manufacturing.
Paper presents the results of evaluation of heat resistance and specific heat capacity of MAR-M-200, MAR-M-247 and Rene 80 nickel superalloys. Heat resistance was evaluated using cyclic method. Every cycle included heating in 1100°C for 23 hours and cooling for 1 hour in air. Microstructure of the scale was observed using electron microscope. Specific heat capacity was measured using DSC calorimeter. It was found that under conditions of cyclically changing temperature alloy MAR-M-247 exhibits highest heat resistance. Formed oxide scale is heterophasic mixture of alloying elements, under which an internal oxidation zone was present. MAR-M-200 alloy has higher specific heat capacity compared to MAR-M-247. For tested alloys in the temperature range from 550°C to 800°C precipitation processes (γ′, γ′′) are probably occurring, resulting in a sudden increase in the observed heat capacity.
The aim of these studies was to obtain single phase cubic modification of Li7La3Zr2O12 by mechanical milling and annealing of La(OH)3, Li2CO3 and ZrO2 powder mixture. Fritsch P5 planetary ball mill, Rigaku MiniFlex II X-ray diffractometer, Setaram TG-DSC 1500 analyser and FEI Titan 80-300 transmission electron microscope were used for sample preparation and investigations. The applied milling and annealing parameters allowed to obtain the significant contribution of c-Li7La3Zr2O12 in the sample structure, reaching 90%. Thermal measurements revealed more complex reactions requiring further studies.
With the use of differential scanning calorimetry (DSC), the characteristic temperatures and enthalpy of phase transformations were defined for commercial AlSi9Cu3 cast alloy (EN AC-46000) that is being used for example for pressurized castings for automotive industry. During the heating with the speed of 10oCmin-1 two endothermic effects has been observed. The first appears at the temperature between 495 oC and 534 oC, and the other between 555 oC and 631 oC. With these reactions the phase transformation enthalpy comes up as +6 J g-1 and +327 J g-1 . During the cooling with the same speed, three endothermic reactions were observed at the temperatures between 584 oC and 471 oC. The total enthalpy of the transitions is – 348 J g-1 . Complimentary to the calorimetric research, the structural tests (SEM and EDX) were conducted on light microscope Reichert and on scanning microscope Hitachi S-4200. As it comes out of that, there are dendrites in the structure of α(Al) solution, as well as the eutectic (β) silicon crystals, and two types of eutectic mixture: double eutectic α(Al)+β(Si) and compound eutectic α+Al2Cu+β.
The thermal reclamation process as a utilisation method of spent moulding and core sands is more costly than other reclamation methods, but in the majority of cases it simultaneously provides the best cleaning of mineral matrices from organic binders. Thus, the application of the thermal analysis methods (TG-DSC), by determining the temperature range within which a degradation followed by a destruction of bounded organic binders in moulding sands, can contribute to the optimisation of the thermal reclamation process and to the limiting its realisation costs. The thermal analysis results of furan resin, one of the most often applied binder in foundry practice, are presented in the hereby paper. The influence of the heating rate of the sample - placed in the thermal analyser - on its degradation and destruction process under oxygen-free (argon) and oxygen (air) conditions, were compared. The recorded TG and DSC curves were used for analysing these processes as the temperature as well as the time function. The obtained results were analysed with regard to determining the required temperature of the thermal reclamation of the investigated organic binder. The usefulness of the developed methodology was found out, however under conditions of meeting several essential requirements concerning the repeatability of performed analyses.
Paper presents the results of ATD and DSC analysis of two superalloys used in casting of aircraft engine parts. The main aim of the research was to obtain the solidification parameters, especially Tsol and Tliq, knowledge of which is important for proper selection of casting and heat treatment parameters. Assessment of the metallurgical quality (presence of impurities) of the feed ingots is also a very important step in production of castings. It was found that some of the feed ingots delivered by the superalloy producers are contaminated by oxides located in shrinkage defects. The ATD analysis allows for quite precise interpretation of first stages of solidification at which solid phases with low values of latent heat of solidification are formed from the liquid. Using DSC analysis it is possible to measure precisely the heat values accompanying the phase changes during cooling and heating which, with knowledge of phase composition, permits to calculate the enthalpy of formation of specific phases like γ or γ′.