The presented in the paper investigations were aimed at the determination of the reclaimed material (obtained in the dry mechanical reclamation process) addition influence on properties of moulding sands with hydrated sodium silicate modified by colloidal suspension of zinc oxide nanoparticles in propanol. Nanoparticles originated from the thermal decomposition of alkaline zinc carbonate, were used. The results of the reclamation of the spent moulding sand with hydrated sodium silicate performed in the AT-2 testing reclaimer are presented in the paper. Both, spent sands from the Floster S technology and from the technology with the modified water-glass were subjected to the reclamation processes. The following determinations of the reclaimed material were performed: pH reaction, acid demand, ignition loss and Na2O content. The obtained reclaim was used as a matrix component of moulding sands with water-glass in the Floster S technology, in which it constituted 60% and 50% of the sand matrix. The strength properties of the prepared moulding sands were determined (bending strength Rg u , tensile strength Rm u ) after samples storing times: 1h, 2h, 4h and 24 hours.
In this study, a preliminary evaluation was made of the applicability ofthe signalsof the cutting forces, vibration and acoustic emission in diagnosis of the hardness and microstructure of ausferritic ductile iron and tool edge wear rate during its machining. Tests were performed on pearlitic-ferritic ductile iron and on three types of ausferritic ductile iron obtained by austempering at 400, 370 and 320⁰C for 180 minutes. Signals of the cutting forces (F), vibration (V) and acoustic emission (AE) were registered while milling each type of the cast iron with a milling cutter at different degrees of wear. Based on individual signals from all the sensors, numerous measures were determined such as e.g. the average or maximum signal value. It was found that different measures from all the sensors tested depended on the microstructure and hardness of the examined material, and on the tool condition. Knowing hardness of the material and the cutting tool edge condition, it is possible to determine the structure of the material .Simultaneous diagnosis of microstructure, hardness, and the tool condition is probably feasible, but it would require the application of a diagnostic strategy based on the integration of numerous measures, e.g. using neural networks.
The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3- 3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear.The work proposes an application of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material. The paper presents the results of examination of the kinetics of σ phase precipitation at a temperature of 800°C and at times ranging from 30 to 180 minutes. Changes in the morphology of precipitates of the σ phase were determined using the value of shape factor R. Resistance to erosion-corrosion wear of duplex cast steel was correlated with the kinetics of sigma phase precipitating.
The article presents an analysis of the applicability of the Replicast CS process as an alternative to the investment casting process, considered in terms of the dimensional accuracy of castings. Ceramic shell moulds were based on the Ekosil binder and a wide range of ceramic materials, such as crystalline quartz, fused silica, aluminosilicates and zirconium silicate. The linear dimensions were measured with a Zeiss UMC 550 machine that allowed reducing to minimum the measurement uncertainty.
The work presents the test result of the influence of cooling rate on the microstructure of AZ91 alloy, Vickers micro-hardness and Brinell hardness. Studies cooling and crystallization of AZ91 alloy was cast into the ceramic shells pre-heated to 180 ° C and then air-cooled at ambient temperature or intensively super cooled in the liquid coolant. The TDA method was applied to record and characterize the thermal effect resulting from the phase transformations occurring during the crystallization of AZ91 alloy. The kinetics and dynamics of the thermal processes of crystallization of AZ91 alloy in the ceramic shells were determined. Metallographic tests were performed with the use of an optical microscope. A comparison of these test results with the thermal effect recorded by way of the TDA method was made. Influence of cooling rate of AZ91 on HV0, 01 micro-hardness and Brinell hardness alloy was examined.
Porosity is one of the major defects in aluminum castings, which results is a decrease of a mechanical properties. Porosity in aluminum alloys is caused by solidification shrinkage and gas segregation. The final amount of porosity in aluminium castings is mostly influenced by several factors, as amount of hydrogen in molten aluminium alloy, cooling rate, melt temperature, mold material, or solidification interval. This article deals with effect of chemical composition on porosity in Al-Si aluminum alloys. For experiment was used Pure aluminum and four alloys: AlSi6Cu4, AlSi7Mg0, 3, AlSi9Cu1, AlSi10MgCu1.
This paper presents the effect of the temperature and hold time in the holding furnace of 226 silumin on the characteristic quantities of TDA curves. The temperature of phase transformations and the cooling rate were tested.It has been shown that increasing both the hold time and the temperature in the holdingfurnace cause the decreasethe end ofα+Al9Fe3Si2+β and α+Al2Cu+βternary eutectics crystallizationtemperature in the tested silumin. This is due to the fact an increase in amounts of impurities as a result of reacting theliquid alloy with the gases contained in the air.It has been shown, however, that examined technological factors ofthe metal preparation do not cause systematic changes in the cooling rate.
This paper deals with influence of chrome addition and heat treatment on segregation of iron based phases in the secondary alloy AlSi7Mg0.3 microstructure by chrome and heat treatment. Iron is the most common and harmful impurity in aluminum casting alloys and has long been associated with an increase of casting defects. In generally, iron is associated with the formation of Fe-rich intermetallic phases. It is impossible to remove iron from melt by standard operations, but it is possible to eliminate its negative influence by addition some other elements that affect the segregation of intermetallics in less harmful type or by heat treatment. Realization of experiments and results of analysis show new view on solubility of iron based phases during melt preparation with higher iron content and influence of chrome as iron corrector of iron based phases.
The article describes the optimization of the melting brass. Brasses, as one of the most popular alloys of copper, deserve special attention in the context of the processes of melting, which in turn would provide not only products of better quality, but also reduce the cost of their production or refining. For this purpose, several studies carried out deriatographic (DTA) and thermogravimetric (TG) using derivatograph. The results were confronted with the program SLAG - PROP used to evaluate the physicochemical properties of the coatings extraction. Based on the survey and analysis of the program can identify the most favorable physico - chemical properties, which should be carried out treatments. This allows for slag mixtures referred configurations oxide matrix containing specific stimulators of the reaction. Conducted empirical studies indicate a convergence of the areas proposed by the application. It should also be noted that the program also indicates additional areas in which to carry out these processes would get even better, to optimize the melting process, the results.
The problem considered in the paper is motivated by production planning in a foundry equipped with the furnace and casting line, which provides a variety of castings in various grades of cast iron/steel for a large number of customers. The quantity of molten metal does not exceed the capacity of the furnace, the load is a particular type of metal from which the products are made. The goal is to create the order of the melted metal loads to prevent delays in delivery of goods to customers. This problem is generally considered as a lot-sizing and scheduling problem. The paper describes a mathematical programming model that formally defines the optimization problem and its relaxed version that is based on the conception of rolling-horizon planning
Air abrasion process is used for cleaning casting surface of prosthetic components, and to prepare the surface of these elements for the application of veneering items. Its side effect, however, is that abrasive particles are embedded in the treated surface, which can be up to 30% of the surface and it constitutes the side effect of this procedure. Such a significant participation of foreign material can not be indifferent to the properties of the surface. Embedded particles can be the place of stress concentration causing cracking of ceramics, and may deteriorate corrosion resistance by forming corrosive microlinks. In the latter cases, it would be advisable to remove elements embedded into the surface. The simplest method is chemical etching or electrochemical one. Nevertheless, these procedures should not significantly change the parameters of the surface. Among many possible reagents only a few fulfills all the above conditions. In addition, processing should not impair corrosion resistance of titanium, which is one of the most important factors determining its use as a prosthetic restoration in the mouth. The study presented results of corrosion resistance of titanium used to make prosthetic components by means of casting method, which were subjected to chemical processing designed to remove the embedded abrasive particles. The aim of the study was to investigate whether etching with selected reagents affects the corrosion resistance of titanium castings. For etching the following reagents were used: 30% HNO3 + 3% HF + H2O, HNO3+ HF+ glycerol (1:2:3), 4% HF in H2O2, 4% HF in H2O, with a control sandblasted sample, not subjected to etching. Tests demonstrated that the etching affected corrosion properties of test samples, in each case the reduction of the corrosion potential occurred - possibly due to the removal of particles of Al2O3 from the surface and activation of the surface. None of the samples underwent pitting corrosion as a result of polarization to 9 V. Values of the polarization resistance, and potentiodynamic characteristics indicated that the best corrosion resistance exhibited the samples after etching in a mixture of 4% solution of HF in H2O2. They showed very good passivation of the surface.
Presented are results of a research on usability of an innovative reclamation process of microwave-hardened moulding sands containing water-glass, combined with activation of binder. After each subsequent stage of reclamation, quality of the reclaimed material was determined on the grounds of measurements of permeability and results of screen analysis. The reclaimed material was next used again to prepare new moulding sand. The sandmix based on high-silica sand prepared with water-glass grade 145, was subject to the following cyclical treatment operations: mixing components, consolidation, microwave hardening, cooling, heating the mould up to 800 °C, cooling to ambient temperature, mechanical reclamation dry and wet. It was found that the used-up and reclaimed sandmix containing water-glass is susceptible to the applied activation process of thermally reacted film of binder and, in addition, it maintains good quality and technological properties of high-silica base. Observations of surfaces of reclaimed high-silica grains with activated film of reacted inorganic binder were carried-out using a scanning microscope. Thanks to properly selected reclamation parameters, the high-silica base can be reused even five times, thus reducing demand for fresh aggregate and inorganic binder.
This paper presents a study of the effect of the modification and cooling rate on the grain count α(Al) in the Al-5Cu alloy. Research was performed on castings with walls thickness between 3 mm and 25 mm. Cooling curves were recorded to determine the cooling rate and the degree of undercooling at the beginning of solidification. It has been shown that cooling rate increases exponentially as the wall thickness of casting decreases. Moreover it has been demonstrated that the cooling rate of castings changes within a wide range (21ºC/s - 1ºC/s) when the wall thickness changes from 3 up to 25 mm. Metallographic examinations revealed primary grains (primary α(Al) grains). The paper show that the relationship between the grain count and the degree of undercooling (for non-modified and modified alloys) can be represented by the equation N = Nv = np·exp(-b/ΔTα), based on the Weibull's distribution of the size of nucleation sites.
This research presents comprehensive assessment of the precision castings quality made in the Replicast CS process. The evaluation was made based on quality of the surface layer, shape errors and the accuracy of the linear dimensions. Studies were carried out on the modern equipment, among other things a Zeiss Calypso measuring machine and profilometer were used. Obtained results allowed comparing lost wax process models and Replicast CS process.
In the paper presented are results of a research on influence of electrical and physico-chemical properties of materials being parts of multicomponent and multimaterial systems used in foundry practice on efficiency and effectiveness of microwave heating. Effectiveness of the process was evaluated on the grounds of analysis of interaction between selected parameters of permittivity and loss factor, as well as collective index of energy absorbed, reflected and transmitted by these materials. In the examinations used was a stand of waveguide resonance cavity for determining electrical properties and a stand of microwave slot line for determining balance of microwave power emitted into selected materials. The examinations have brought closer the possibility of forecasting the behaviour of multimaterial systems like e.g. model, moulding sand or moulding box in microwave field on the grounds of various electrical and physico-chemical properties. On the grounds of analysis of the results, possible was selecting a group of materials designed for building foundry instrumentation to be effectively used in electromagnetic field.
Bentonite is clay rock, which is created by decomposition of vulcanic glass. It is formed from mixture of clay minerals of smectite group, mainly montmorillonite, beidellite and nontronite. Its typical characteristics is, that when in contact with water, it intensively swells. First who used this term was W.C. Knight in 1887. The rock had been named after town Fort Benton in American state Montana. For its interesting technological properties and whiteness has wide technological use. Bentonite is selectively mined and according to its final use separately modified, which results in high quality product with specific parameters. In the beginning of 21st century belong bentonite moulding mixtures in foundry to always perspective. Mainly increased ratio of ductile cast iron castings production cannot be ensured without the need of quality bentonite. Great area of scope remains to further research of moulding materials, which return also to bentonite producers.
The present article deals with the possibility of using the reverse engineering method for the production of prototype molds by Patternless process technology. Article describes method how to obtain virtual model by using a 3D scanner. Article also explains principle of the Patternless process technology, which is based on the milling mold cavity using CNC machining equipment. The aim of the research is the use of advanced technologies that speed up and facilitate the process of production prototype mold. The practical result of the presented experiment is bronze casting, which serves as a foot rest bracket on historic bike.
Contribution gives an overview of knowledge about the method of centrifugal casting with orientate on Tekcast system. Company Tekcast Industries has developed a device for centrifugal casting, extending the area of production of castings or prototyping of metal or plastic. Materials suitable for the centrifugal casting with flexible operating parameters may include non-ferrous metal alloy based on zinc or aluminum or non-metallic materials such as polyester resins, polyurethane resins, epoxy resins, waxes and the like. The casting process is particularly suitable for a wide range of commercial castings and decorative objects.
The article describes the problem of selection of heat treatment parameters to obtain the required mechanical properties in heat- treated bronzes. A methodology for the construction of a classification model based on rough set theory is presented. A model of this type allows the construction of inference rules also in the case when our knowledge of the existing phenomena is incomplete, and this is situation commonly encountered when new materials enter the market. In the case of new test materials, such as the grade of bronze described in this article, we still lack full knowledge and the choice of heat treatment parameters is based on a fragmentary knowledge resulting from experimental studies. The measurement results can be useful in building of a model, this model, however, cannot be deterministic, but can only approximate the stochastic nature of phenomena. The use of rough set theory allows for efficient inference also in areas that are not yet fully explored.
The aim of this work is the development of Cu-Al2O3 composites of copper Cu-ETP matrix composite materials reinforced by 20 and 30 vol.% Al2O3 particles and study of some chosen physical properties. Squeeze casting technique of porous compacts with liquid copper was applied at the pressure of 110 MPa. Introduction of alumina particles into copper matrix affected on the significant increase of hardness and in the case of Cu-30 vol. % of alumina particles to 128 HBW. Electrical resistivity was strongly affected by the ceramic alumina particles and addition of 20 vol. % of particles caused diminishing of electrical conductivity to 20 S/m (34.5% IACS). Thermal conductivity tests were performed applying two methods and it was ascertained that this parameter strongly depends on the ceramic particles content, diminishing it to 100 Wm-1K-1 for the composite material containing 30 vol.% of ceramic particles comparing to 400 Wm-1K-1 for the unreinforced copper. Microstructural analysis was carried out using SEM microscopy and indicates that Al2O3 particles are homogeneously distributed in the copper matrix. EDS analysis shows remains of silicon on the surface of ceramic particles after binding agent used during preparation of ceramic preforms.
Development of salt cores prepared by high-pressure squeezing and shooting with inorganic binders has shown a high potential of the given technology even for high-pressure casting of castings. Strength, surface quality of achieved castings, and solubility in water become a decisive criterion. The shape and quality of grain surface particularly of NaCl – cooking salts that can be well applied without anticaking additives has shown to be an important criterion. Thus the salt cores technology can cover increasingly growing demands for casting complexity especially for the automobile industry.
The work determined the influence of aluminium in the amount from about 0.6% to about 8% on graphitization of cast iron with relatively high silicon content (3.4%-3.9%) and low manganese content (about 0.1%). The cast iron was spheroidized with cerium mixture and graphitized with ferrosilicon. It was found that the degree of graphitization increases with an increase in aluminium content in cast iron up to 2.8%, then decreases. Nodular and vermicular graphite precipitates were found after the applied treatment in cast iron containing aluminium in the amount from about 1.9% to about 8%. The Fe3AlCx carbides, increasing brittleness and deteriorating the machinability of cast iron, were not found in cast iron containing up to about 6.8% Al. These carbides were revealed only in cast iron containing about 8% Al.
The results presented in this paper are a continuation of the previously published studies. The results of hest treatment of ductile iron with content 3,66%Si and 3,80% Si were produced. The experimental castings were subjected to austempering process for time 30, 60 and 90 minutes at temperature 300o C. The mechanical properties of heat treated specimens were studied using tensile testing and hardness measurement, while microstructures were evaluated with conventional metallographic observations. It was again stated that austempering of high silicone ferritic matrix ductile iron allowed producing ADI-type cast iron with mechanical properties comparable with standard ADI.
The work presents experiment results from the area of copper casting technology and chosen examples of alloyed copper. At present, copper casting technology is applied in many branches of industrial manufacturing, especially in the sector of construction, communications, arms and power engineering. Alloyed copper, containing slight additions of different elements and having special physio-chemical properties, is used in a special range of applications. Copper technology and alloyed copper analyses have been presented, these materials being used for cast manufacturing for power engineering. The quality of casts has been assessed, based on their microstructure analysis, chemical content and the cast properties. During the research, special deoxidizing and modifying agents were applied for copper and chosen examples of alloyed copper; also exemplary samples were tested with the help of metallographic analysis, electrical conductivity and gaseous impurities research.
In the aluminium alloy family, Al-Zn materials with non-standard chemical composition containing Mg and Cu are a new group of alloys, mainly owing to their high strength properties. Proper choice of alloying elements, and of the method of molten metal treatment and casting enable further shaping of the properties. One of the modern methods to produce materials with submicron structure is a method of Rapid Solidification. The ribbon cast in a melt spinning device is an intermediate product for further plastic working. Using the technique of Rapid Solidification it is not possible to directly produce a solid structural material of the required shape and length. Therefore, the ribbon of an ultrafine grain or nanometric structure must be subjected to the operations of fragmentation, compaction, consolidation and hot extrusion. In this article the authors focussed their attention on the technological aspect of the above mentioned process and described successive stages of the fabrication of an AlZn9Mg2.5Cu1.8 alloy of ultrafine grain structure designated for further plastic working, which enables making extruded rods or elements shaped by the die forging technology. Studies described in the article were performed under variable parameters determined experimentally in the course of the alloy manufacturing process, including casting by RS and subsequent fragmentation.