The results presented in this article are part of the research on fatigue life of various foundry alloys carried out in recent years in the Lukasiewicz Research Network – Institute of Precision Mechanics and AGH University of Science and Technology, Faculty of Foundry Engineering. The article discusses the test results obtained for the EN-GJS-600-3 cast iron in an original modified low-cycle fatigue test (MLCF), which seems to be a beneficial research tool allowing its users to evaluate the mechanical properties of materials with microstructural heterogeneities under both static and dynamic loads. For a comprehensive analysis of the mechanical behaviour with a focus on fatigue life of alloys, an original modified low cycle fatigue method (MLCF) adapted to the actually available test machine was used. The results of metallographic examinations carried out by light microscopy were also presented. From the analysis of the results of the conducted mechanical tests and structural examinations it follows that the MLCF method is fully applicable in a quick and economically justified assessment of the quality of ductile iron after normalizing treatment.
Introduction of polymers into the cement composites improves same of the properties of concretes and mortars. Therefore, the polymer-cement composites are successfully used in construction. The model of microstructure formation in cement composites modified with thermoplastic polymer (pre-mix modifiers) has already been developed and successfully implemented. However, the formation of microstructure in the case of epoxy-cement composites (containing post-mix modifier) demonstrates same peculiarities which should be taken into account when modelling the process. The microstructure of epoxy-cement composites and its formation is discussed in the paper. The model is offered, formulated on the basis of the microscopic observations and results of testing.
The thermochemical treatment applied to improve the surface properties of AZ91 consisted in heating the material in contact with AlSi10Mg powder at 445 oC for 30 min. During heat treatment process the powder was held under pressure to facilitate the diffusion of the alloying elements to the substrate and, accordingly, the formation of a modified layer. Two pressures, 1 MPa and 5 MPa, were tested. The resultant layers, containing hard Mg2Si and Mg17Al12 phases, were examined using an optical microscope and a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer (EDS). The experimental data show that the layer microstructure was dependent on the pressure applied. A thicker, three-zone layer (about 200 μm) was obtained at 1 MPa. At the top, there were Mg2Si phase particles distributed over the Mg17Al12 intermetallic phase matrix. The next zone was a eutectic (Mg17Al12 and a solid solution of Al in Mg) with Mg2Si phase particles embedded in it. Finally, the area closest to the AZ91 substrate was a eutectic not including the Mg2Si phase particles. By contrast, the layer produced at a pressure of 5 MPa had lower thickness of approx. 150 μm and a two-zone structure. Mg2Si phase particles were present in both zones. In the upper zone, Mg2Si phase particles were regularly distributed over the Mg17Al12 intermetallic phase matrix. The lower zone, adjacent to the AZ91, was characterized by a higher volume fraction of Mg2Si phase particles distributed over the matrix composed mainly of Mg17Al12. The alloyed layers enriched with Al and Si had much higher hardness than the AZ91 substrate.
An isolated, deciduous incisor of an archaic whale found in the upper part of the La Meseta Formation (Telm7) is tentatively assigned to the Archaeoceti. The strata from which the tooth was recovered are of Late Eocene (Priabonian) age, and previous reports indicate that they contain the remains of Dorudontinae (Archaeoceti) and Llanocetidae (Mysticeti). The tooth is similar in shape, size and ornamentation to the milk teeth of Zygorhiza. The enamel is mostly prismatic, with prism sheats generally open, except for the outermost layer, which is aprismatic. The Schmelzmuster consists of radial and decussating enamel types. The decussating zone has distinct Hunter-Schreger bands (HSB), usually consisting of 1012 prisms. It is bordered by an external zone built of radial enamel extending for 22% of the enamel thickness and an internal, starting zone, with less developed HSB, occupying 9% of the enamel thickness. The interprismatic matrix is parallel to the prism direction. An archaeocete origin of the tooth is suggested by its enamel features, typical for the group. However, additional study of the Llanocetidae enamel structure is needed for final identification.
A method of using the electric charge in a capacitor was applied for the manufacture of thermocouple micro-joints. The motivation for the study was the need to produce a stable welded connection without affecting the geometry of the substrate, which was a thin sheet of Inconel 625 alloy (UNS designation N06625). Within the framework of the research work, a suitable workstation for micro-joints elaboration was built and welding experiments were performed using different electric charges. Studies carried out within the framework of the present work have shown that joints based on Inconel 625 alloy and platinum have the best application properties in the range of small-scale temperature measurements. They can be used, e.g., for monitoring the temperature distribution on the inner surfaces of electric motor casings. An undeniable advantage is in this case the high thermal resistance of both materials used to produce the joint, i.e. the Inconel 625 alloy and platinum. This allows them to be used at high temperatures under atmospheric conditions.
Metallic bearing alloys have different types, most of which are tin (Babbitt) or bronze based. Bronze bearings are used at heavy duty conditions. The goal of this research is an investigation on the effect of cooling rate and pouring temperature (two important factors in casting production) on the Brinell hardness and pin-on-disc wear resistance (two important properties in bearing applications) of bronze SAE660. The melt had prepared by induction furnace. Then, it had poured in sand mold in four different casting conditions, including pouring temperatures of 950 oC and 1200 oC, and cooling with water and air. Finally, the microstructure, hardness and wear resistance of the SAE660 had investigated. The results indicated that if the maximum hardness, along with the minimum weight loss due to wear (or maximum wear resistance) is required; the contents of intermetallic compounds, lead phase and the solid solution phase should be more. In this way, the samples which are cooled in air and poured at 950 oC have the high hardness and the lowest weight loss.
This paper presents the results of studies of high-alloyed white cast iron modified with lanthanum, titanium, and aluminium-strontium. The samples were taken from four melts of high-vanadium cast iron with constant carbon and vanadium content and near-eutectic microstructure into which the tested inoculants were introduced in an amount of 1 wt% respective of the charge weight. The study included a metallographic examinations, mechanical testing, as well as hardness and impact resistance measurements taken on the obtained alloys. Studies have shown that different additives affect both the microstructure and mechanical properties of high-vanadium cast iron.
The multiple direct remelting of composites based on the A359 alloy reinforced with 20% of Al2O3 particles was performed. The results of both gravity casting and squeeze casting were examined in terms of the obtained microstructure and mechanical characteristics. In microstructure examinations, the combinatorial method based on phase quanta theory was used. In mechanical tests, the modified low cycle fatigue method (MLCF) was applied. The effects obtained after both gravity casting and squeeze casting were compared. It was noted that both characteristics were gradually deteriorating up to the tenth remelting. The main cause was the occurrence of shrinkage porosity after the gravity casting. Much better results were obtained applying the squeeze casting process. The results of microstructure examinations and fatigue tests enabled drawing the conclusion that the A359 alloy reinforced with Al2O3 particles can confer a much better fatigue life behavior to the resulting composite than the A359 alloy without the reinforcement. At the same time, comparing these results with the results of the previous own research carried out on the composites based also on the A359 alloy but reinforced in the whole volume with SiC particles, it has been concluded that both types of the composites can be subjected to multiple remelting without any significant deterioration of the structural and mechanical characteristics. The concepts and advantages of using the combinatorial and MLCF methods in materials research were also presented
Ultrasonic pulse echo technique was used to study cupric oxide (CuO) thin films. CuO thin films were prepared using sol gel technique. They were doped with Lithium (Li) (1%, 2% and 4%). Thin films’ thickness (d) and band gap energy (Eg) were measured. In addition, elastic moduli (longitudinal (L), shear (G), bulk (K) and Young’s (E)) and Poisson’s ratio (v) were determined to estimate the microstructure properties of the prepared films. The study ameliorated the used transducers to overcome their dead zone and beam scattering; wedges were developed. The results showed the effectiveness of these wedges. They enhanced transducers’ sensitivity by changing the dead zone, beam diameter, beam directivity and waves’ transmission. Also, the study noted that Li doping caused the improvement of CuO thin films to be more useful in solar cell fabrication. Li-CuO thin films had narrower band gap. Thus, they acquired a high quantum yield for the excited carriers; also they gained more efficiency to absorb solar light.
This research work is focused on examining the turning behavior of Incoloy 800H superalloy by varying important cutting parameters. Incoloy 800H is an Iron- Nickel-Chromium based superalloy; it can withstand high temperature (810°C), high oxidization and corrosion resistance. But, it is difficult to turn in conventional machines and hence the present work was carried out and investigated. Experiments were conducted based on the standard L27 orthogonal array using uncoated tungsten inserts. The cutting force components, namely, feed force (Fx), thrust force (Fy) and cutting force (Fz); surface roughness (Ra) and specific cutting pressure (SCPR) were measured as responses and optimized using Taguchi-Grey approach. The main effects plots and analysis of mean (ANOM) were performed to check the effect of turning parameters and their significance on responses of cutting forces in all the direction (FX, FY, FZ), the surface roughness (Ra) and specific cutting pressure (SCPR). The tool wear and machined surfaces were also investigated using white light interferometer and SEM.
Currently is the biggest problem of metallurgical companies the increase of fossil fuel prices and strict environmental regulations. As a result of this, companies must look for alternatives that would reduce the amount of fossil fuels and reduce emissions. Wood sawdust has huge energy potential, which can be used in the process of agglomerate production. This type of energy is locally available, has some similar properties as fossil fuels and is economically advantageous. For these reasons, experimental study using laboratory agglomeration pan was realized to study the possibility of agglomerate production with a mixed fuel. Experimental results show the viability of mixed fuel use in the agglomeration process, but also show significant possibility for improvement. The maximum acceptable substitution ratio, which corresponds to qualitatively suitable agglomerate is 20% of pine sawdust. Based on the realized experiments and the obtained results we have acceded to the intensification of the agglomeration process with an objective to increase the amount of added substitution fuel while maintaining the required quality of agglomerate.
Mechanical properties and residual stresses of friction stir welded and autogenous tungsten inert gas welded structural steel butt welds have been studied. Friction stir welding (FSW) of structural steel butt joints has been carried out by in-house prepared tungsten carbide tool with 20 mm/ min welding speed and 931 rpm tool rotation. Tungsten inert gas (TIG) welding of the butt joints was carried out with welding current, arc voltage and the welding speed of 140 amp, 12 V and 90 mm/min respectively. Residual stress measurement in the butt welds has been carried out in weld fusion zone and heat affected zone (HAZ) by using blind hole drilling method. The magnitude of longitudinal residual stress along the weld line of TIG welded joints were observed to be higher than friction stir welded joint. In both TIG and FSW joints, the nature of longitudinal stress in the base metal was observed to be compressive whereas in HAZ was observed to be tensile. It can be stated that butt welds produced with FSW process had residual stress much lower than the autogenous TIG welds.
In this article the structural and mechanical properties of grain refinement of Cu-Sn alloys with tin content of 10%, 15% and 20% using the KOBO method have been presented. The direct extrusion by KOBO (name from the combination of the first two letters of the names of its inventors – A. Korbel and W. Bochniak) method employs, during the course of the whole process, a phenomenon of permanent change of strain travel, realized by a periodical, two-sided, plastic metal torsion. Moreover the aim of this work was to study corrosion resistance. The microstructure investigations were performed using an optical microscope Olimpus GX71, a scanning electron microscope (SEM) and a scanning transmission electron microscope (STEM). The mechanical properties were determined with INSTRON 4505/5500 machine. Corrosion tests were performed using «Autolab» set – potentiostat/galvanostat from EcoChemie B.V. with GPES software ver. 4.9. The obtained results showed possibility of KOBO deformation of Cu-Sn casting alloys. KOBO processing contributed to the refinement of grains and improved mechanical properties of the alloys. The addition of tin significantly improved the hardness. Meanwhile, with the increase of tin content the tensile strength and yield strength of alloys decrease gradually. Ductility is controlled by eutectoid composition and especially δ phase, because they initiate nucleation of void at the particle/matrix interface. No significant differences in the corrosion resistance between cast and KOBO processed materials were found.
This study manufactured a SiC coating layer using the vacuum kinetic spray process and investigated its microstructure and wear properties. SiC powder feedstock with a angular shape and average particle size of 37.4 μm was used to manufacture an SiC coating layer at room temperature in two different process conditions (with different degrees of vacuum). The thickness of the manufactured coating layers were approximately 82.4 μm and 129.4 μm, forming a very thick coating layers. The SiC coating layers consisted of α-SiC and β-SiC phases, which are identical to the feedstock. Cross-sectional observation confirmed that the SiC coating layer formed a dense structure. In order to investigate the wear properties, ball crater tests were performed. The wear test results confirmed that the SiC coating layer with the best wear resistance achieved approximately 4.16 times greater wear resistance compared to the Zr alloy. This study observed the wear surface of the vacuum kinetic sprayed SiC coating layer and identified its wear mechanism. In addition, the potential applications of the SiC coating layer manufactured using the new process were also discussed.
Hybryd PLD method was used for deposition high quality thin Ti, TiN, Ti(C,N) and DLC coatings. The kinetic energy of the evaporated particles was controlled by application of variation of di#11;erent reactive and non reactive atmospheres during deposition. The purpose was to improve adhesion by building a bridge between the real ceramic coating and the substrate. A new layer composition layout was proposed by application of a bu#11;er, starting layer. Advanced HRTEM investigation based on high resolution transmission electron microscopy was used to reveal structure dependence on specific atmosphere in the reactive chamber. New experimental technique to examine the crystallographic orientation based on X-ray texture tomography was applied to estimate contribution of the atmosphere to crystal orientation. Using Dictyostelium discoideum cells as a model organism for specific and nonspecific adhesion, kinetics of shear flow-induced cell detachment was studied. For a given cell, detachment occurs for critical stress values caused by the applied hydrodynamic pressure above a threshold. Cells are then removed from the substrate with an apparent first-order rate reaction that strongly depends on the stress. The threshold stress depends on cell size and physicochemical properties of the substrate, but it is not a#11;ected by depolymerization of the actin and tubulin cytoskeleton.
In this paper the effects of titanium addition in an amount up to 0.13 wt.% have been investigated to determine their effect on the microstructure and mechanical properties of Thin Wall Vermicular Graphite Iron Castings (TWVGI). The study was performed for thinwalled iron castings with 3-5 mm wall thickness and for the reference casting with 13 mm. Microstructural changes were evaluated by analyzing quantitative data sets obtained by image analyzer and also using scanning electron microscope (SEM). Metallographic examinations show that in thin-walled castings there is a significant impact of titanium addition to vermicular graphite formation. Thinwalled castings with vermicular graphite have a homogeneous structure, free of chills, and good mechanical properties. It may predispose them as a potential use as substitutes for aluminum alloy castings in diverse applications.
The results of studies presented in this article are an example of the research activity of the authors related to lead-free alloys. The studies covered binary SnZn90 and SnZn95 lead-free alloys, including their microstructure and complex mechanical characteristics. The microstructure was examined by both light microscopy (LM) and scanning electron microscopy (SEM). The identification of alloy chemical composition in micro-areas was performed by SEM/EDS method. As regards light microscopy, the assessment was of both qualitative and quantitative character. The determination of the geometrical parameters of microstructure was based on an original combinatorial method using phase quantum theory. Comprehensive characterization of mechanical behavior with a focus on fatigue life of alloys was performed by means of the original modified low cycle fatigue method (MLCF) adapted to the actually available test machine. The article discusses the fatigue life of binary SnZn90 and SnZn95 alloys in terms of their microstructure. Additionally, the benefits resulting from the use of the combinatorial method in microstructure examinations and MLCF test in the quick estimation of several mechanical parameters have been underlined.
Trials of cast steel filtration using two types of newly-developed foam filters in which carbon was the phase binding ceramic particles have been conducted. In one of the filters the source of carbon was flake graphite and coal-tar pitch, while in the other one graphite was replaced by a cheaper carbon precursor. The newly-developed filters are fired at 1000o C, i.e. at a much lower temperature than the currently applied ZrO2-based filters. During filtration trials the filters were subjected to the attack of a flowing metal stream having a temperature of 1650°C for 30 seconds. Characteristic of the filters’ properties before and after the filtration trial were done. It was found, that the surface reaction of the filter walls with molten metal, which resulted in local changes of the microstructure and phase composition, did not affect on expected filter lifetime and filtration did not cause secondary contamination of cast steel.
Using methods of physical material studies (scanning electron microscopy and micro X-ray spectral analysis), a study was carried out with focus on alteration of structure and phase composition in surface layers of Al-Si alloy (silumin АК10М2N) treated in electroexplosive alloying with a multiphase plasma jet formed in the process of aluminum foil explosion and carrying particles of Y2O3 weighted powder portion. It was revealed that a porous surface layer with non-homogeneously distributed alloying elements (silicon, yttrium) in it is formed in any conditions of electroexplosive alloying of silumin. Thickness of the modified layer is different, varying 50 to 160 µm, depending on the zone to be examined. The modified surface consists basically of Al, Si and Y. Yttrium in the modified layer is thought to be an indirect evidence of better physical and mechanical properties of the surface layer in comparison with the base material.
The present paper is a presentation of results of a study on morphology, chemical composition, material properties (HVIT, HIT, EIT), and nanoindentation elastic and plastic work for carbide precipitates in chromium cast iron containing 24% Cr. It has been found that the carbides differ in chemical composition, as well as in morphology and values characterizing their material properties. The carbides containing the most chromium which had the shape of thick and long needles were characterized with highest values of the analyzed material properties.
In Poland, researchers have a very strong interest in archaeometallurgy, which, as presented in classical works, focuses on dating artefacts from the prehistoric and early medieval periods in the form of cast iron and copper castings. This study, extending the current knowledge, presents the results of a microstructure investigation into the findings from the Modern era dating back to the late Middle Ages. The investigated material was an object in the form of a heavy solid copper block weighing several kilograms that was excavated by a team of Polish archaeologists working under the direction of Ms Iwona Młodkowska-Przepiórowska during works on the marketplace in the city of Czestochowa during the summer of 2009. Pre-dating of the material indicates the period of the seventeenth century AD. The solid copper block was delivered in the form of a part shaped like a bell, named later in this work as a “kettlebell”. To determine the microstructure, the structural components, chemical composition, and homogeneity, as well as additives and impurities, investigations were carried out using light microscopy, scanning electron microscopy including analysis of the chemical composition performed in micro-areas, and qualitative X-ray phase analysis in order to investigate the phase composition. Interpretation of the analytical results of the material’s microstructure will also help modify and/or develop new methodological assumptions to investigate further archaeometallurgical exhibits, throwing new light on and expanding the area of knowledge of the use and processing of seventeenth-century metallic materials.